The Spatial Distribution Characteristics of Heavy Metals in River Sediments and Suspended Matter in Small Tributaries of the Abandoned Wanshan Mercury Mines, Guizhou Province

Jing-yi CAI; Ke-yan TAN; Guo-hui LU; Xiao-cai YIN; Yu ZHENG; Peng-wei SHAO; Jing WANG; Yong-liang YANG

doi:10.15898/j.cnki.11-2131/td.201811150123

Rock and Mineral Analysis > 2019 > 38(3): 305-315. > DOI: 10.15898/j.cnki.11-2131/td.201811150123

Jing-yi CAI, Ke-yan TAN, Guo-hui LU, Xiao-cai YIN, Yu ZHENG, Peng-wei SHAO, Jing WANG, Yong-liang YANG. The Spatial Distribution Characteristics of Heavy Metals in River Sediments and Suspended Matter in Small Tributaries of the Abandoned Wanshan Mercury Mines, Guizhou Province[J]. Rock and Mineral Analysis, 2019, 38(3): 305-315. DOI: 10.15898/j.cnki.11-2131/td.201811150123

Citation:

PDF (4071 KB)

The Spatial Distribution Characteristics of Heavy Metals in River Sediments and Suspended Matter in Small Tributaries of the Abandoned Wanshan Mercury Mines, Guizhou Province

1.
Key Laboratory of Eco-Geochemistry, Ministry of Natural Resources, National Research Center for Geoanalysis, Beijing 100037, China
2.
China University of Geosciences(Beijing), Beijing 100083, China
3.
College of Environmental Sciences and Engineering, Qingdao University, Qingdao 266071, China

More Information

Received Date: November 14, 2018
Revised Date: March 12, 2019
Accepted Date: April 08, 2019
Published Date: April 30, 2019

Abstract

HIGHLIGHTS
(1) Investigation of the pollution status of typical heavy metals in river sediments and suspended solids of abandoned mercury mines.

(2) Comparison and discussion of the spatial distribution characteristics of heavy metals in sediments and suspended matter.

(3) Assessment of the potential ecological risks of heavy metals in the sediments.

ABSTRACT

BACKGROUNDAlthough abandoned mines are no longer exploited, waste mines, old smelting sites and buried tailings can still pollute downstream areas through rainwater leaching and surface runoff. The study on the distribution and relationship of heavy metals in sediments and suspended particulate matter (SPM) along rivers in abandoned mines has important significance.
OBJECTIVESTo preliminarily investigate heavy metals in river sediments and SPM in Wanshan Mercury Mines, and provide basic information for monitoring and remediation of contaminated cultivated land.
METHODSThe contents of Cr, Ni, Cu, Cd, Pb, As, Hg, Zn and Co in sediments and SPM samples were determined by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) and Atomic Fluorescence Spectrometry (AFS) with wet digestion pretreatment. The pollution status and spatial distribution characteristics were identified in order to obtain information of pollutant migration and diffusion downstream.
RESULTSThe total mercury content (Hg) in sediments ranged from 0.10 to 16.0μg/g (dry weight), averaging 5.79μg/g, which was ten times higher than the Hg limit of the Class Ⅱ soil environmental quality standard of China. The average contents of Ni, Cu and Co were not higher than the standard. The variation coefficients of Hg and Cd were large, indicating the heterogeneously spatial distribution of Hg and Cd. Mercury in sediments reached a high potential ecological risk level.
CONCLUSIONSThe Hg in sediments and SPM in the study area are related to the hydrodynamic conditions, and the maximum values occurred at the sites with broad river channel and low flow rate. As the mining and smelting of Wanshan Mercury Mine has been stopped for a long time, the weathering and leaching of the abandoned mining area under natural conditions will cause Hg and Cd pollution in the lower reaches of the river.
- small tributary,
- sediment,
- suspended matter,
- heavy metals,
- Wanshan Mercury Mines

FullText(HTML)

References (33)

References

Dave J, Hugh P, Ceri J, et al.Abandoned Mines and the Water Environment[R].Science Project SC030136-41, UK Environment Agency, 2008.

Ciszewski D, Aleksander-Kwaterczak U, Pociecha A, et al.Small effects of a large sediment contamination with heavy metals on aquatic organisms in the vicinity of an abandoned lead and zinc mine[J]. Environmental Monitoring and Assessment, 2013, 185(12):9825-9842. doi: 10.1007/s10661-013-3295-z

Lecce S A, Pavlowsky R T.Floodplain storage of sediment contaminated by mercury and copper from historic gold mining at Gold Hill, North Carolina, USA[J].Geomorphology, 2014, 206:122-132. doi: 10.1016/j.geomorph.2013.10.004

DeGraff J V.Addressing the Toxic Legacy of Abandoned Mines on Public Land in the Western United States[M]//Reviews in Engineering Geology (Volume XⅦ).DOI: 10.1130/2007.4017(01).

Unger C, Lechner A M, Glenn V, et al.Mapping Impacts and Prioritising Rehabilitation of Abandoned Mines at a National Level in Australia[R].Brisbane: Life of Mine Conference, 2012.

贵州省铜仁市万山特区政府.贵州铜仁典型区域土壤污染综合治理项目实施方案[R].2014.

Government of Wanshan Special Zone, Tongren City, Guizhou Province.Implementation Plan of Comprehensive Soil Pollution Control Project in Typical Area of Tongren City, Guizhou Province[R].2014.

尹德良, 何天容, 安艳玲, 等.万山汞矿区居民食用大米的汞暴露风险评估[J].安全与环境学报, 2016, 16(3):330-337. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201603066

Yin D L, He T R, An Y L, et al.Mercury exposure and its health assessment for the residents in Wanshan mercury-mining areas via the rice consumption[J].Journal of Safety and Environment, 2016, 16(3):330-337. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201603066

胡国成, 张丽娟, 齐剑英, 等.贵州万山汞矿周边土壤重金属污染特征及风险评价[J].生态环境学报, 2015, 24(5):879-885. http://d.old.wanfangdata.com.cn/Periodical/tryhj201505024

Hu G C, Zhang L J, Qi J Y, et al.Contaminant characteristics and risk assessment of heavy metals in soils from Wanshan mercury mine area, Guizhou Province[J].Ecology and Environmental Sciences, 2015, 24(5):879-885. http://d.old.wanfangdata.com.cn/Periodical/tryhj201505024

湛天丽, 黄阳, 滕应, 等.贵州万山汞矿区某农田土壤重金属[J].土壤通报, 2017, 48(2):474-480. http://d.old.wanfangdata.com.cn/Periodical/trtb201702032

Zhan T L, Huang Y, Teng Y, et al.Pollution characteristics and sources of heavy metals in farmland soils in Wanshan mining areas, Guizhou Province[J].Chineae Journal of Soil Science, 2017, 48(2):474-480. http://d.old.wanfangdata.com.cn/Periodical/trtb201702032

吴兰艳, 姚元勇, 唐帮成, 等.万山汞矿区周边土壤重金属污染调查及其风险评价[J].铜仁学院学报, 2017, 19(6):85-90. doi: 10.3969/j.issn.1673-9639.2017.06.021

Wu L Y, Yao Y Y, Tang B C, et al.Pollution investigation and risk assessment of heavy metals in soils from the sourounding areas of Wanshan mining areas[J].Journal of Tongren University, 2017, 19(6):85-90. doi: 10.3969/j.issn.1673-9639.2017.06.021

Zhang H, Feng X, Larssen T.Fractionation, distribution and transport of mercury in rivers and tributaries around Wanshan Hg mining district, Guizhou Province, Southwestern China:Part 1-Total mercury[J].Applied Geochemistry, 2010, 25:633-641. doi: 10.1016/j.apgeochem.2010.01.006

赵西强, 庞绪贵, 王增辉, 等.利用原子荧光光谱-电感耦合等离子体质谱法研究济南市大气干湿沉降重金属含量及年沉降通量特征[J].岩矿测试, 2015, 34(2):245-251. doi: 10.15898/j.cnki.11-2131/td.2015.02.016

Zhao X Q, Pang X G, Wang Z H, et al.Study on the characteristics of heavy metal contents and annual fluxes of atmospheric dry and wet deposition in Jinan City using AFS and ICP-MS[J].Rock and Mineral Analysis, 2015, 34(2):245-251. doi: 10.15898/j.cnki.11-2131/td.2015.02.016

李自强, 李小英, 钟琦, 等.电感耦合等离子体质谱法测定土壤重金属普查样品中铬铜镉铅的关键环节研究[J].岩矿测试, 2016, 35(1):37-41. doi: 10.15898/j.cnki.11-2131/td.2016.01.007

Li Z Q, Li X Y, Zhong Q, et al.Determination of Cr, Cu, Cd and Pb in soil samples by inductively coupled plasma-mass spectrometry for an investigation of heavy metal pollution[J].Rock and Mineral Analysis, 2016, 35(1):37-41. doi: 10.15898/j.cnki.11-2131/td.2016.01.007

田衎, 杨珺, 孙自杰, 等.矿区污染场地土壤重金属元素分析标准样品的研制[J].岩矿测试, 2017, 36(1):82-88. doi: 10.15898/j.cnki.11-2131/td.2017.01.012

Tian K, Yang J, Sun Z J, et al.Preparation of soil certified reference materials for heavy metals in contaminated sites[J].Rock and Mineral Analysis, 2017, 36(1):82-88. doi: 10.15898/j.cnki.11-2131/td.2017.01.012

黎彤.化学元素的地球丰度[J].地球化学, 1976(3):167-174. doi: 10.3321/j.issn:0379-1726.1976.03.004

Li T.Chemical element abundances in the Earth and its major shells[J].Geochimica, 1976(3):167-174. doi: 10.3321/j.issn:0379-1726.1976.03.004

陈若思, 刘定富, 武晓阳.红枫湖沉积物中汞污染评价[J].贵州化工, 2012, 37(4):40-42. doi: 10.3969/j.issn.1008-9411.2012.04.020

Chen R S, Liu D F, Wu X Y.An assessment of mercury pollution in sediments of Hongfeng Lake[J].Guizhou Chemical Industry, 2012, 37(4):40-42. doi: 10.3969/j.issn.1008-9411.2012.04.020

Wu B B, Wang G Q, Wu J, et al.Sources of heavy metals in surface sediments and an ecological risk assessment from two adjacent plateau reservoirs[J].PLoS ONE, 2014, 9(7).DOI: 10.1371/journal.pone.0102101.

Chen C X, Zheng B H, Jiang X, et al.Spatial distribution and pollution assessment of mercury in sediments of Lake Taihu, China[J].Journal of Environmental Sciences, 2013, 25(2):316-325. doi: 10.1016/S1001-0742(12)60033-3

Garcia-Ordiales E, Loredo J, Covelli S, et al.Trace metal pollution in freshwater sediments of the world's largest mercury mining district:Sources, spatial distribution and environmental implications[J].Journal of Soils and Sediments, 2017, 17(7):1893-1904. doi: 10.1007/s11368-016-1503-5

仇广乐, 冯新斌, 王少锋.贵州省万山汞矿区地表水中不同形态汞的空间分布特点[J].地球与环境, 2004, 32(3-4):77-82. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx200403015

Qiu G L, Feng X B, Wang S F.Mercury speciations and their distribution in surface water from Wanshanmercury mining district, Guizhou Province[J].Earth and Environment, 2004, 32(3-4):77-82. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx200403015

USEPA.National Recommended Water Quality Criteria-Correction[R].US Environmental Protection Agency.1999822-Z-99-001.1999.

Håkanson L.An ecological risk index for aquatic pollution control-Sedimentological approach[J].Water Research, 1980, 14:975-1001. doi: 10.1016/0043-1354(80)90143-8

赵志鹏.重金属镉的土壤空间分布机制及迁移转化过程研究[D].贵州: 贵州大学, 2015: 1-51.

Zhao Z P.Cadmium Distribution and Transformation in Soil Profile and Effection Factor[D].Guizhou: Guizhou University, 2015: 1-51.

何天容, 冯新斌, 郭艳娜, 等.红枫湖沉积物中汞的环境地球化学循环[J].环境科学, 2008, 29(7):1768-1774. doi: 10.3321/j.issn:0250-3301.2008.07.002

He T R, Feng X B, Guo Y N, et al.Geochemical cycling of mercury in the sediment of Hongfeng Reservior[J].Environmental Science, 2008, 29(7):1768-1774. doi: 10.3321/j.issn:0250-3301.2008.07.002

Rügner H, Schwientek M, Milačič R, et al.Particle bound pollutants in rivers:Results from suspended sediment sampling in Globaqua River Basins[J].Science of the Total Environment, 2019, 647:645-652. doi: 10.1016/j.scitotenv.2018.08.027

王珊珊, 潘存鸿, 李宏, 等.杭州湾泥沙中重金属元素的分布及影响因[J].中国环境科学, 2017, 37(12):4701-4709. doi: 10.3969/j.issn.1000-6923.2017.12.036

Wang S S, Pan C H, Li H, et al.Distribution and influence factor of Cu, Pb, Hg in surficial sediments and suspended sediments of Hangzhou Bay[J].China Environmental Science, 2017, 37(12):4701-4709. doi: 10.3969/j.issn.1000-6923.2017.12.036

Pont D, Day J W, Ibáñez C.The impact of two large floods (1993-1994) on sediment deposition in the Rhône delta:Implications for sustainable management[J].Science of the Total Environment, 2017, 609:251-262. doi: 10.1016/j.scitotenv.2017.07.155

Rimondi V, Costagliola P, Gray J E, et al.Mass loads of dissolved and particulate mercury and other trace elements in the Mt.Amiata mining district, Southern Tuscany (Italy)[J].Environmental Science and Pollution Research, 2014, 21(8):5575-5585. doi: 10.1007/s11356-013-2476-1

Balogh S J, Meyer M L, Johnson D K.Mercury and suspended sediment loadings in the Lower Minnesota River[J].Environmental Science & Technology, 1997, 31(1):198-202. doi: 10.1021-es960327t/

Zhang J B, Zhou F X, Chen C L, et al.Spatial distri-bution and correlation characteristics of heavy metals in the seawater, suspended particulate matter and sediments in Zhanjiang Bay, China[J].PLoS ONE, 2018, 13(8).DOI: 10.1371/journal.pone.0201414.

Zhu W, Song Y, Adediran G A, et al.Mercury transformations in resuspended contaminated sediment controlled by redox conditions, chemical speciation and sources of organic matter[J].Geochimica et Cosmochimica Acta, 2018, 220:158-179. doi: 10.1016/j.gca.2017.09.045

Lučić M, Jurina I, Ščančar J, et al.Sedimentological and geochemical characterization of river suspended particulate matter (SPM) sampled by time-integrated mass flux sampler (TIMS) in the Sava River (Croatia)[J]. Journal of Soils and Sediments, 2019, 19(2):989-1004. doi: 10.1007/s11368-018-2104-2

Annan S T, Sanful P O, Lartey-Young G, et al.Spatial and temporal patterns of variation in environmental quality of water and sediments of streams in mined and unmined areas with emphasis on mercury (Hg) and arsenic (As)[J].Journal of Geoscience and Environment Protection, 2018, 6(9):125-140. doi: 10.4236/gep.2018.69010

Supplements (0)

Cited By

Cited by

Periodical cited type(16)

1.	张晓东，卢志宏，王婷，杨传东. 贵州万山汞矿区周边赤链蛇重金属富集特征研究. 环境科学学报. 2024(05): 486-495 .
2.	张晓东，卢志宏，王婷，杨传东. 万山汞矿区银环蛇重金属生物富集研究. 环境科学与技术. 2024(04): 159-166 .
3.	张晓东，王婷，卢志宏，钟莉传，陈芬. 万山汞矿区弹琴蛙重金属富集与组织关联分析. 野生动物学报. 2024(03): 596-606 .
4.	张峰，陈佳，范萍萍，牛勇，方怒放，吴泽燕，谭廷俊，龙文涛，邰良. 侵蚀—沉积对土壤重金属形态、浓度及富集影响的研究进展. 水土保持通报. 2024(06): 222-236 .
5.	王代懿，王雷，樊传慧，孙大方，陈冬华. 贵州某流域城市河段沉积物及悬浮物重金属污染研究. 中国环境监测. 2023(01): 159-169 .
6.	陈雪，汪小祥，邱杨，陈彪，景山. 宁镇矿集区小流域水系沉积物重金属污染评价及来源解析. 矿产勘查. 2023(01): 144-152 .
7.	涂春霖，杨坤，和成忠，张连凯，李博，魏总，姜昕，杨明花. 滇东典型煤矿区小流域沉积物重金属来源及风险评价. 中国地质. 2023(01): 206-221 .
8.	张晓东，卢志宏，王婷，杨传东，吴震洋. 万山汞矿区泽陆蛙重金属富集特征及健康评价. 环境科学与技术. 2023(10): 170-180 .
9.	蔡壮，侯国华，高茂生. 中国重点潮间带沉积柱砷和汞的环境本底值构建及污染评价. 岩矿测试. 2022(05): 857-866 . 本站查看
10.	胡雪筠，蒋娟，代亮亮，朱映明，周少奇. 贵州锦江河(梵净山-江口)夏季水质空间分布特征. 贵州科学. 2021(01): 53-57 .
11.	毛志强，田康，刘本乐，张晓辉，卞子金，黄标，袁旭音，吴龙华，罗栋源. 广西某采选废矿区重金属生态风险与源汇关系. 农业环境科学学报. 2021(05): 987-998 .
12.	葛琼琳. 生活污水中SS的测定方法及干扰消除研究. 皮革制作与环保科技. 2021(16): 101-103 .
13.	余楚，李剑锋，吕敦玉. 大兴安岭南段某矿区河流表层沉积物重金属污染及风险评价. 生态环境学报. 2021(11): 2223-2231 .
14.	易玲，高柏，丁小燕，马文洁，杜超超，樊骅，李艳梅. 鄱阳湖流域上游铀尾矿库周边水体中铬形态及健康风险评估. 湖泊科学. 2020(01): 79-88 .
15.	李坦平，吴宜，曾利群，娄晓明，李爱阳. 电感耦合等离子体串联质谱法测定电解二氧化锰废渣浸出液中的重金属元素. 岩矿测试. 2020(05): 682-689 . 本站查看
16.	张立锋，刘杰民，张翼明. 白云鄂博矿区土壤和植物中稀土元素的分布特征. 岩矿测试. 2019(05): 556-564 . 本站查看

Other cited types(8)

Get Citation

PDF

XML

Article views (1727) PDF downloads (55) Cited by(24)

Turn off MathJax

Article Contents

ABSTRACT

References

The Spatial Distribution Characteristics of Heavy Metals in River Sediments and Suspended Matter in Small Tributaries of the Abandoned Wanshan Mercury Mines, Guizhou Province

ABSTRACT

References

Cited by

Periodical cited type(16)

Other cited types(8)

Catalog

Export File

Citation

Format

Content