Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in Typical Shallow Pore Water and Karst Water

Rong-zhen XU; Fei LIU; Ji-hong JING; Zi-yi AN; Sheng-zhang ZOU

doi:10.15898/j.cnki.11-2131/td.201801120004

Rock and Mineral Analysis > 2018 > 37(4): 411-418. > DOI: 10.15898/j.cnki.11-2131/td.201801120004

Rong-zhen XU, Fei LIU, Ji-hong JING, Zi-yi AN, Sheng-zhang ZOU. Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in Typical Shallow Pore Water and Karst Water[J]. Rock and Mineral Analysis, 2018, 37(4): 411-418. DOI: 10.15898/j.cnki.11-2131/td.201801120004

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Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in Typical Shallow Pore Water and Karst Water

1.
Beijing Key Laboratory of Water Resources and Environmental Engineering, China University of Geosciences(Beijing), Beijing 100083, China
2.
Center for Hydrogeology and Environmental Geology, CGS, Baoding 071051, China
3.
Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, China
4.
National Research Center for Geoanalysis, Beijing 100037, China
5.
Institute of Karst Geology, Chinese Academy of Geological Sciences, Guilin 541004, China

More Information

Received Date: January 11, 2018
Revised Date: March 19, 2018
Accepted Date: May 06, 2018
Published Date: June 30, 2018

Abstract

HIGHLIGHTS
(1) The highest detection frequency of PAHs was chrysene (6.10%) in groundwater.

(2) In this study, PAHs in groundwater are mainly 2-4 rings.

(3) The source pollution of PAHs was from combustion in Shijiazhuang; and it was related to industrial layout in Guangzhou; while it was mainly affected by precipitation in Qujing.

ABSTRACT

BACKGROUNDIn recent years, reports of the detection of PAHs in groundwater have gradually increased, but research on PAHs in groundwater of major hydrogeological units in China is not being conducted.
OBJECTIVESTo study and compare the distribution characteristics of PAHs in groundwater under different hydrogeological conditions, using a total of 82 samples of shallow pore water and Karst groundwater samples collected in the Huabei plain, the Pearl River Delta plain, and the Southwestern Karst area.
METHODSGas Chromatography-Mass Spectrometry (GC-MS) was used to test PAHs in groundwater samples, and statistical methods were used to compare the detection frequency, concentration and composition of PAHs in the three different areas.
RESULTS16 PAHs were detected and each PAH was detected in at least one sample. The highest detection rate of PAHs was chrysene (6.10%). The PAH with the highest concentration was naphthalene (5.41 μg/L). Only the concentration of benzo(a)pyrene exceeded the Class Ⅲ limit in the standard for groundwater quality, and the over-standard rate was 2.44%. The PAHs in groundwater are mainly 2-4 rings, but the composition of PAHs in the three regions was different. The relative proportion of 4-rings PAHs in the northern pore water was high, accounting for 52.48%, whereas the pore water in the South and the Karst water in the Southwest were dominated by 3-rings (56.60%) and 2-rings (95.66%), respectively.
CONCLUSIONSThe main cause of contamination of PAHs in Northern pore water was by combustion. The PAHs contamination in the Southern pore water was related to the industrial layout of the Pearl River Delta, whereas the PAHs of Qujing Karst water were mainly affected by atmospheric precipitation. The detection differences of PAHs in different districts were related to their physicochemical properties, hydrogeological conditions, pollution sources, meteorological and hydrological factors. The results provide basic data support for groundwater PAHs pollution monitoring and the formulation of a groundwater related standard in China.

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References (27)

References

Menzie C A, Potoki B B, Santodomato J.Exposure to carcinogenic PAHs in the environment[J].Environmental Science & Technology, 1992, 26(7):1278-1284. doi: 10.1021-es00031a002/

Harkov R, Greenberg A, Darack F, et al.Summer time variations in polycyclic aromatic hydro-carbons at four sites in New Jersey[J].Environmental Science & Technology, 1984, 18(4):287-291. http://europepmc.org/abstract/med/22263771

Krupadam R J, Khan M S, Wate S R.Removal of probable human carcinogenic polycyclic aromatic hydrocarbons from contaminated water using molecularly imprinted polymer[J].Water Research, 2010, 44(3):681-688. doi: 10.1016/j.watres.2009.09.044

曹云者, 柳晓娟, 谢云峰, 等.我国主要地区表层土壤中多环芳烃组成及含量特征分析[J].环境科学学报, 2012, 32(1):197-203. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201201026

Cao Y Z, Liu X J, Xie Y F, et al.Patterns of PAHs concentrations and components in surface soils of main areas in China[J].Acta Scientiae Circumstantiae, 2012, 32(1):197-203. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201201026

Page D S, Boehm P D, Douglas G S, et al.Pyrogenic polycyclic aromatic hydrocarbons in sediments record past human activity:A case study in Prince William Sound, Alaska[J]. Marine Pollution Bulletin, 1999, 38(4):247-260. doi: 10.1016/S0025-326X(98)00142-8

Argiriadis E, Rada E C, Vecchiato M, et al.Assessing the influence of local sources on POPs in atmospheric depositions and sediments near Trento (Italy)[J].Atmospheric Environment, 2014, 98:32-40. doi: 10.1016/j.atmosenv.2014.08.035

Luo X, Zheng Y, Lin Z, et al.Evaluating potential non-point source loading of PAHs from contaminated soils:A fugacity-based modeling approach[J].Environmental Pollution, 2015, 196:1-11. doi: 10.1016/j.envpol.2014.09.011

Mielke H W, Wang G D, Gonzales C R, et al.PAHs and metals in the soils of inner-city and suburban New Orleans, Louisiana, USA[J].Environmental Toxicology and Pharmacology, 2004, 18:243-247. doi: 10.1016/j.etap.2003.11.011

Ma L L, Chu S G, Wang X T, et al.Polycyclic aromatic hydrocarbons in the surface soils from outskirts of Beijing, China[J].Chemosphere, 2005, 58:1355-1363. doi: 10.1016/j.chemosphere.2004.09.083

Wang X C, Sun S, Ma H Q, et al.Sources and distri-bution of aliphatic and polycyclic aromatic hydrocarbons in sediments of Jiaozhou Bay, Qingdao, China[J].Marine Pollution Bulletin, 2006, 52(2):129-138. doi: 10.1016/j.marpolbul.2005.08.010

Shi Z, Tao S, Pan B, et al.Partitioning and source diagnostics of polycyclic aromatic hydrocarbons in rivers in Tianjin, China[J].Environmental Pollution, 2007, 146:492-500. doi: 10.1016/j.envpol.2006.07.009

Liu M, Cheng S B, Ou D N, et al.Characterization, identification of road dust PAHs in central Shanghai areas, China[J].Atmospheric Environment, 2007, 41:8785-8795. doi: 10.1016/j.atmosenv.2007.07.059

Jiang Y, Yves U J, Sun H, et al.Distribution, composi-tional pattern and sources of polycyclic aromatic hydrocarbons in urban soils of an industrial city, Lanzhou, China[J].Ecotoxicology & Environmental Safety, 2016, 126(7):154-162.

Velaa N, Martínez-Menchónb M, Navarrob G, et al.Removal of polycyclic aromatic hydrocarbons (PAHs) from groundwater by heterogeneous photocatalysis under natural sunlight[J].Journal of Photochemistry and Photobiology A-Chemistry, 2012, 232(5):32-40. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=JJ0225786108

崔虎群, 康卫东, 李文鹏, 等.定靖油气田区地下水有机污染特征初步分析[J].环境化学, 2016, 35(6):1212-1218. http://d.old.wanfangdata.com.cn/Periodical/hjhx201606014

Cui H Q, Kang W D, Li W P, et al.Preliminary analysis on the organic contamination in groundwater of Dingjing oil-gas field region[J].Environmental Chemistry, 2016, 35(6):1212-1218. http://d.old.wanfangdata.com.cn/Periodical/hjhx201606014

苗迎, 孔祥胜.南宁市多环境介质中多环芳烃分布特征[J].环境科学, 2016, 37(11):4333-4340. http://d.old.wanfangdata.com.cn/Periodical/hjkx201611039

Miao Y, Kong X S.Distribution characteristics of polycyclic aromatic hydrocarbons in environmental media in Nanning city[J].Environmental Science, 2016, 37(11):4333-4340. http://d.old.wanfangdata.com.cn/Periodical/hjkx201611039

昌盛, 耿梦娇, 刘琰, 等.滹沱河冲洪积扇地下水中多环芳烃的污染特征[J].中国环境科学, 2016, 36(7):2058-2066. doi: 10.3969/j.issn.1000-6923.2016.07.022

Chang S, Geng M J, Liu Y, et al.Pollution characteristic of polycyclic aromatic hydrocarbons in the groundwater of Hutuo River Pluvial Fan[J].China Environmental Science, 2016, 36(7):2058-2066. doi: 10.3969/j.issn.1000-6923.2016.07.022

龚香宜, 何炎志, 孙云雷.江汉平原四湖流域上区地下水中多环芳烃分布特征与源解析[J].环境科学学报, 2015, 35(3):789-796. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201503024

Gong X Y, He Y Z, Sun Y L.Distribution and source of polycyclic aromatic hydrocarbons in groundwater in the upper region of Sihu Lake Basin from Jianghan Plain[J].Acta Scientiae Circumstantiae, 2015, 35(3):789-796. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201503024

赵红梅, 赵华, 毛洪亮, 等.华北平原滹沱河冲洪积扇第四纪地层划分[J].地层学杂志, 2014, 38(2):137-146. http://www.cnki.com.cn/Article/CJFDTOTAL-DCXZ201402002.htm

Zhao H M, Zhao H, Mao H L, et al.Quaternary stratigraphy division of Hutuohe alluvial fan deposits in the North China Plain[J].Journal of Stratigraphy, 2014, 38(2):137-146. http://www.cnki.com.cn/Article/CJFDTOTAL-DCXZ201402002.htm

李亚松, 张兆吉, 费宇红, 等.河北省滹沱河冲积平原地下水质量及污染特征研究[J].地球学报, 2014, 35(2):169-176. http://d.old.wanfangdata.com.cn/Conference/8307619

Li Y S, Zhang Z J, Fei Y H, et al.Groundwater quality and contamination characteristics in the Hutuo River Plain area, Hebei Province[J].Acta Geoscientica Sinica, 2014, 35(2):169-176. http://d.old.wanfangdata.com.cn/Conference/8307619

郭秀红. 珠江三角洲地区浅层地下水有机污染研究[D]. 北京: 中国地质大学(北京), 2006.

Guo X H. Research on Characteristics of Shallow Groundwater Organic Contamination in Pearl River Delta[D]. Beijing: China University of Geosciences (Beijing), 2006.

杨艳华, 朱培秋, 和怀忠, 等. 云南省地下水水资源评价[R]. 2002.

Yang Y H, Zhu P Q, He H Z, et al. Water Resource Assessment on Groundwater in Yunnan Province[R]. 2002.

Suman S, Sinha A, Tarafdar A.Polycyclic aromatic hydrocarbons (PAHs) concentration levels, pattern, source identification and soil toxicity assessment in urban traffic soil of Dhanbad, India[J].Science of the Total Environment, 2016, 545-546:353-360. doi: 10.1016/j.scitotenv.2015.12.061

于国光, 王铁冠, 吴大鹏.薪柴燃烧源和燃煤源中多环芳烃的成分谱研究[J].生态环境, 2007, 16(2):285-289. doi: 10.3969/j.issn.1674-5906.2007.02.004

Yu G G, Wang T G, Wu D P.Study on fingerprints of PAHs from the combustion of bavin and coal[J].Ecology and Environment, 2007, 16(2):285-289. doi: 10.3969/j.issn.1674-5906.2007.02.004

王丽娟.多环芳烃类污染物在部分水体中的分布及其降解途径[J].渔业研究, 2017, 39(4):325-330. http://d.old.wanfangdata.com.cn/Periodical/fjsc201704011

Wang L J.Distribution of polycyclic aromatic hydrocarbons in some water bodies and degradation pathways[J].Journal of Fisheries Research, 2017, 39(4):325-330. http://d.old.wanfangdata.com.cn/Periodical/fjsc201704011

Ford D C, Williams P.Karst Hydrogeology and Geo-morphology[M].Chichester:John Wiley & Sons, 2007.

蓝家程, 孙玉川, 师阳, 等.岩溶地下河流域表层土壤多环芳烃污染特征及来源分析[J].环境科学, 2014, 35(8):2937-2943. http://d.old.wanfangdata.com.cn/Periodical/hjkx201408017

Lan J C, Sun Y C, Shi Y, et al.Source and contamination of polycyclic aromatic hydrocarbons in surface soil in Karst underground river basin[J].Environmental Science, 2014, 35(8):2937-2943. http://d.old.wanfangdata.com.cn/Periodical/hjkx201408017

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Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in Typical Shallow Pore Water and Karst Water