Petrogeochemical Characteristics and Metallogenetic Potential of Epimetamorphic Rocks in South Jiangxi Province

Zhen WANG; Zhi ZHAO; Xin-yong ZOU; Zhen-yu CHEN; Xue-jing TU

doi:10.15898/j.cnki.11-2131/td.201710160167

Rock and Mineral Analysis > 2018 > 37(1): 96-107. > DOI: 10.15898/j.cnki.11-2131/td.201710160167

Zhen WANG, Zhi ZHAO, Xin-yong ZOU, Zhen-yu CHEN, Xue-jing TU. Petrogeochemical Characteristics and Metallogenetic Potential of Epimetamorphic Rocks in South Jiangxi Province[J]. Rock and Mineral Analysis, 2018, 37(1): 96-107. DOI: 10.15898/j.cnki.11-2131/td.201710160167

Citation:

PDF (17513 KB)

Petrogeochemical Characteristics and Metallogenetic Potential of Epimetamorphic Rocks in South Jiangxi Province

1.
Institute of Mineral Resources, Chinese Academy of Geological Sciences; Key Laboratory of Metallogeny and Mineral Resource Assessment, Ministry of Land and Resources, Beijing 100037, China
2.
Geological Survey Team of Gannan, Jiangxi Bureau of Geology & Mineral Exploration and Development, Ganzhou 341000, China
3.
School of Earth Sciences and Resources, China University of Geosciences(Beijing), Beijing 100083, China

More Information

Received Date: October 15, 2017
Revised Date: December 13, 2017
Accepted Date: January 01, 2018
Published Date: December 31, 2017

Abstract

Highlights
· The epimetamorphic rocks widely distributed in South Jiangxi Province mainly include blastopsammite, metamorphic tuff, slate, phyllite, and schist.

· The epimetamorphic rocks are characteristic with generally siliceous, peraluminous, low-alkaline and have relatively high ∑REEs.

· Metamorphic tuff is the most likely potential parent rock type for ion-adsorption REEs deposits.

ABSTRACT

Epimetamorphic rocks and related weathered crusts are widely distributed in South Jiangxi province. Identifying the petrological and geochemical characteristics of epimetamorphic rocks has a significant effect on the metallogenetic potential analysis on ion-adsorption REEs deposits. At present, there is little research about the metamorphic rock ion-adsorbed rare earth deposits. Epimetamorphic rocks of Neoproterozoic to Cambrian age are widely distributed in this region. Petrological and geochemical methods are used to classify these epimetamorphic rocks. Results show that the epimetamorphic rocks in this region have a large age span, ranging from Qingbaikou to Devonian. Minor epimetamorphic rocks also occur in Jurassic strata. Neoproterozoic epimetamorphic rocks are most widespread and mainly include blastopsammite, metamorphic tuff, slate, phyllite, and schist. Blastopsammite and metamorphic tuff have the highest REEs content with average contents of 302 μg/g and 246 μg/g, respectively, and show the LREE enrichment patterns with LREEs/HREEs of 2.68-5.43. Monazite and xenotime are the two most common rare earth minerals found in the epimetamorphic rocks so far. The metamorphic tuffs in the area have a large outcrop thickness, high REE content and well-weathered crusts, which are good metallogenic parent rocks for ion-adsorbed rare earth deposits. Phyllite, schist and granulite have lower REE contents (>224 μg/g, on average), but they are resistant to weathering and thus have a low potential in forming REE ore bodies. This study was a preliminary discussion of ion-adsorption rare earth deposits related to epimetamorphic parent rocks, which provides basic information and reference for further studies and prospecting.

FullText(HTML)

References (29)

References

白鸽, 吴澄宇, 丁孝石, 等. 南岭地区离子型稀土矿床形成条件和分布规律[R]. 北京: 地质矿产部矿床地质研究所, 1989.

Bai G, Wu C Y, Ding X S, et al. The Forming Condition and Distribution Law of Ionic Type Rare-Earth Ore Deposit in Nanling Region[R]. Beijing: Institute of Ore Deposit Geology, 1989.

Bern C R, Yesavage T, Foley N K.Ion-adsorption REEs in regolith of the Liberty Hill pluton, South Carolina, USA:An effect of hydrothermal alteration[J].Journal of Geochemical Exploration, 2017, 172:29-40. doi: 10.1016/j.gexplo.2016.09.009

王登红, 赵芝, 于扬, 等.我国离子吸附型稀土矿产科学研究和调查评价新进展[J].地球学报, 2017, 38(3):317-325. doi: 10.3975/cagsb.2017.03.02

Wang D H, Zhao Z, Yu Y, et al.A review of the achievements in the survey and study of ion-adsorption type REE in China[J].Acta Geoscientica Sinica, 2017, 38(3):317-325. doi: 10.3975/cagsb.2017.03.02

Sanematsu K, Murakami H, Watanabe Y, et al.Enrichment of rare elements (REE) in granitic rocks and their weathered crusts in central and southern Laos[J].Bulletin of the Geological Survey of Japan, 2009, 60(11/12):527-558. https://www.jstage.jst.go.jp/article/bullgsj/60/11-12/60_527/_article

Foley N, Ayuso R.REE enrichment in granite-derived regolith deposits of the Southeastern United States:Prospective source rocks and accumulation processes[J].British Columbia Geological Survey Paper, 2015, 3:131-138. https://www.researchgate.net/profile/Nora_Foley/publication...

Murakami H, Ishihara S.REE mineralization of weathered crust and clay sediment on granitic rocks in the Sanyo Belt, SW Japan and the Southern Jiangxi Province, China[J].Resource Geology, 2008, 58(4):373-401. doi: 10.1111/rge.2008.58.issue-4

Ishihara S, Hua R, Hoshino M, et al.REE abundance and REE minerals in granitic rocks in the Nanling Range, Jiangxi Province, Southern China, and generation of the REE-rich weathered crust deposits[J].Resource Geology, 2008, 58(4):355-372. doi: 10.1111/rge.2008.58.issue-4

Maulana A, Yonezu K, Watanabe K.Geochemistry of rare earth elements (REE) in the weathered crusts from the granitic rocks in Sulawesi Island, Indonesia[J].Journal of Earth Science, 2014, 25(3):460-472. doi: 10.1007/s12583-014-0449-z

杨岳清, 胡淙声, 罗展明.离子吸附型稀土矿床成矿地质特征及找矿方向[J].中国地质科学院院报矿床地质研究所分刊, 1981:102-118. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201504018.htm

Yang Y Q, Hu Z S, Luo Z M.Geological characteristics of mineralization of rare earth deposits of the ion-absorption type and their prospecting direction[J].Bulletin of the Chinese Academy of Geological Sciences, 1981:102-118. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201504018.htm

Bao Z W, Zhao Z H.Geochemistry of mineral with exchangeable REY in the weathering crusts of granitic rocks in South China[J].Ore Geology Reviews, 2008, 33:519-535. doi: 10.1016/j.oregeorev.2007.03.005

Sanematsu K, Watanabe Y. Characteristics and Genesis of Ion Adsorption-type Rare Earth Element Deposits[C]//Verplanck P L, Hitzman M W. Reviews in Economic Geology Vol. 18. Society of Economic Geologists. 2016: 55-79. https://www.researchgate.net/publication/299823978_Characteristics_and_Genesis_of_Ion_Adsorption-Type_Rare_Earth_Element_Deposits

吴澄宇.风化壳稀土成矿作用——一种不平衡过程[J].矿床地质, 1989, 8(4):85-90. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE198804003.htm

Wu C Y.Rare earth mineralization in weathering crust-A nonequilibrium process[J].Mineral Deposits, 1989, 8(4):85-90. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE198804003.htm

王登红, 陈毓川, 陈郑辉, 等.南岭地区矿产资源形势分析和找矿方向研究[J].地质学报, 2007, 81(7):882-890. http://www.oalib.com/paper/4874143

Wang D H, Chen Y C, Chen Z H, et al.Assessment on mineral resource in Nanling region and suggestion for further prospecting[J].Acta Geologica Sinica, 2007, 81(7):882-890. http://www.oalib.com/paper/4874143

王登红, 赵芝, 于扬, 等.离子吸附型稀土资源研究进展、存在问题及今后研究方向[J].岩矿测试, 2013, 32(5):796-802. http://www.ykcs.ac.cn/article/id/70179d82-4d1a-4971-a71f-dcaf6942ab7b

Wang D H, Zhao Z, Yu Y, et al.Progress, problems and research orientation of ion-adsorption type rare earth resources[J].Rock and Mineral Analysis, 2013, 32(5):796-802. http://www.ykcs.ac.cn/article/id/70179d82-4d1a-4971-a71f-dcaf6942ab7b

王登红, 陈毓川, 王瑞江, 等.对南岭与找矿有关问题的探讨[J].矿床地质, 2013, 32(4):854-863. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=kcdz201304018&dbname=CJFD&dbcode=CJFQ

Wang D H, Chen Y C, Wang R J.Disscussion on some problems related to prospecting breakthrough in Nanling region[J].Mineral Deposits, 2013, 32(4):854-863. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=kcdz201304018&dbname=CJFD&dbcode=CJFQ

宋云华, 沈丽璞.江西某酸性火山岩风化壳中粘土矿物及其形成条件的讨论[J].矿物学报, 1982(3):207-212. http://www.cnki.com.cn/Article/CJFDTotal-JXDZ504.005.htm

Song Y H, Shen L P.Discussion of clay minerals and forming conditions in some acidic volcanic weathering crusts in Jiangxi Province[J].Acta Mineralogica Sinica, 1982(3):207-212. http://www.cnki.com.cn/Article/CJFDTotal-JXDZ504.005.htm

张祖海.华南风化壳离子吸附型稀土矿床[J].地质找矿论丛, 1990, 5(1):57-71. http://www.cnki.com.cn/Article/CJFDTotal-XTXB201501002.htm

Zhang Z H.A study on weathering crust ion adsorption type REEdeposits, South China[J]. Contribution to Geology and Mineral Resource Research, 1990, 5(1):57-71. http://www.cnki.com.cn/Article/CJFDTotal-XTXB201501002.htm

华仁民, 张文兰, 顾晟彦, 等.南岭稀土花岗岩、钨锡花岗岩及其成矿作用的对比[J].岩石学报, 2007, 23(10):2321-2328. doi: 10.3969/j.issn.1000-0569.2007.10.001

Hua R M, Zhang W L, Gu S Y, et al.Comparison between REE granite and W-Sn granite in the Nanling region, South China, and their mineralizations[J].Acta Petrologica Sinica, 2007, 23(10):2321-2328. doi: 10.3969/j.issn.1000-0569.2007.10.001

赵芝, 王登红, 陈振宇, 等.南岭东段与稀土矿有关岩浆岩的成矿专属性特征[J].大地构造与成矿学, 2014, 38(2):255-263. http://www.oalib.com/paper/4891493

Zhao Z, Wang D H, Chen Z Y, et al.Metallogenic specialization of rare earth mineralized igneous rocks in the Eastern Nanling Region[J].Geotectonica et Metallogenia, 2014, 38(2):255-263. http://www.oalib.com/paper/4891493

刘邦秀, 刘春根, 邱永泉.江西南部鹤仔片麻状花岗岩类Pb-Pb同位素年龄及地质意义[J].火山地质与矿产, 2001, 22(4):264-268. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=hsdz200104004&dbname=CJFD&dbcode=CJFQ

Liu B X, Liu C G, Qiu Y Q.The Pb-Pb isotopic ages and geologic significance of gneissic granite in Hezi, Jiangxi[J].Volcanology & Mineral Resources, 2001, 22(4):264-268. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=hsdz200104004&dbname=CJFD&dbcode=CJFQ

王丽娟, 于津海, O'Reilly S Y, 等.华夏南部可能存在Grenville期造山作用:来自基底变质岩中锆石U-Pb定年及Lu-Hf同位素信息[J].科学通报, 2008, 53(14):1680-1692. doi: 10.3321/j.issn:0023-074X.2008.14.009

Wang L J, Yu J H, O'Reilly S Y, et al.Grenvillian orogeny in the Southern Cathaysia Block:Constraints from U-Pb ages and Lu-Hf isotopes in zircon from metamorphic basement[J].Chinese Science Bulletin, 2008, 53(14):1680-1692. doi: 10.3321/j.issn:0023-074X.2008.14.009

于津海, 王丽娟, O'Reilly S Y, 等.赣南存在古元古代基底:来自上犹陡水煌斑岩中捕虏锆石的U-Pb-Hf同位素证据[J].科学通报, 2009, 54(7):898-905. http://www.oalib.com/paper/4893143

Yu J H, Wang L J, O'Reilly S Y, et al.Paleoproterozoic basement beneath the Southern Jiangxi Province:Evidence from U-Pb ages and Lu-Hf isotopes in zircons from the Doushui lamprophyre[J].Chinese Science Bulletin, 2009, 54(7):898-905. http://www.oalib.com/paper/4893143

靳松, 张利, 钟增球, 等.浙闽地区华夏地块新元古代变沉积岩地球化学特征及其地质意义[J].地球科学——中国地质大学学报, 2008, 33(6):764-774. http://www.cqvip.com/QK/94035X/200806/28695318.html

Jin S, Zhang L, Zhong Z Q, et al.Geochemical characteristics and geological implications for the Neoproterozoic meta-sedimentary rocks of the Cathaysia block in Zhejiang and Fujian Province[J].Earth Science-Journal of China University of Geosciences, 2008, 33(6):764-774. http://www.cqvip.com/QK/94035X/200806/28695318.html

王仁民, 贺高品, 陈珍珍, 等.变质岩原岩图解判别法[M].北京:地质出版社, 1987:1-51.

Wang R M, He G P, Chen Z Z, et al.Graphic Method for Protolith Metamorphic Rocks[M].Beijing:Geological Publishing House, 1987:1-51.

Shaw D M.The origin of the Apsley gneiss, Ontario[J].Canadian Journal of Earth Sciences, 1972, 9:18-35. doi: 10.1139/e72-002

赵芝, 王登红, 刘新星, 等.广西花山岩体不同风化阶段稀土元素特征及其影响因素[J].稀土, 2015, 36(3):14-20. http://or.nsfc.gov.cn/bitstream/00001903-5/257165/1/1000013572269.pdf

Zhao Z, Wang D H, Liu X X, et al.Geochemical features of rare earth elements in different weathering stage of the Guangxi Huashan granite and its influence factors[J].Chinese Rare Earths, 2015, 36(3):14-20. http://or.nsfc.gov.cn/bitstream/00001903-5/257165/1/1000013572269.pdf

池汝安, 田君, 罗仙平, 等.风化淋积型稀土矿的基础研究[J].有色金属科学与工程, 2012, 3(4):1-13. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=jxys201204003&dbname=CJFD&dbcode=CJFQ

Chi R A, Tian J, Luo X P, et al.The basic research on the weathered crust elution-deposited rare earth ores[J].Nonferrous Metals Science and Engineering, 2012, 3(4):1-13. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=jxys201204003&dbname=CJFD&dbcode=CJFQ

宋云华, 沈丽璞, 王贤觉.某些岩石风化壳中稀土元素的初步探讨[J].科学通报, 1987, 32(9):695-698. http://www.oalib.com/paper/1676958

Song Y H, Shen L P, Wang X J.Preliminary discussion of rare earth elements in some weathering crusts[J].Chinese Science Bulletin, 1987, 32(9):695-698. http://www.oalib.com/paper/1676958

包志伟.华南花岗岩风化壳稀土元素地球化学研究[J].地球化学, 1992(2):166-174. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=dqhx199202007&dbname=CJFD&dbcode=CJFQ

Bao Z W.A geochemical study of the granitoid weathering crust in Southeast China[J].Geochimica, 1992(2):166-174. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=dqhx199202007&dbname=CJFD&dbcode=CJFQ

[1]	XIAO Xilian, GUO Min, SHAO Xin, TAN Juanjuan, WANG Lei, QIU Xiaofei. Rare Earth Element Contents and Occurrence Forms in Weathering Crust Ion Adsorption Rare Earth Ore[J]. Rock and Mineral Analysis, 2024, 43(6): 866-879. DOI: 10.15898/j.ykcs.202403130042
[2]	ZHU Li, YANG Yong-qiong, GU Han-nian, WEN Han-jie, DU Sheng-jiang, LUO Chong-guang. Mineralogical Characteristics of Two Clay-type Lithium Resources in Yuxi, China, and Nevada, the United States of America[J]. Rock and Mineral Analysis, 2021, 40(4): 532-541. DOI: 10.15898/j.cnki.11-2131/td.202008130112
[3]	Chun-hua WEN, Xiao-ya LUO, Sheng-miao LI, Jian-kang LI. Application of X-ray Fluorescence Spectrometry and Inductively Coupled Plasma-Mass Spectrometry in the Geochemical Study of Rare Metal Deposits in Chuan-ziyuan Area, Hunan Province[J]. Rock and Mineral Analysis, 2015, 34(3): 359-365. DOI: 10.15898/j.cnki.11-2131/td.2015.03.017
[4]	Lin LU, Ting LIANG, Zheng-hui CHEN, Yong WANG, Huan HEI, Xing XIE. Application of X-ray Powder Diffraction and Inductively Coupled Plasma-Mass Spectrometry in Study on Mineralogical Characteristics and Significance of Wolframite from Xihuashan Tungsten Deposit, Jiangxi Province[J]. Rock and Mineral Analysis, 2015, 34(1): 150-160. DOI: 10.15898/j.cnki.11-2131/td.2015.01.019
[5]	LI Tianyi, KE Ling. Determination of Multi-elements in Ore Samples by Xray Fluorescence Spectrometry with Filter Paper Sample Preparation[J]. Rock and Mineral Analysis, 2010, 29(1): 77-79.
[6]	LIU Jiangbin, ZHAO Feng, YU Yu, DANG Liang, ZHANG Wangqiang, CHEN Yueyuan. Simultaneous Determination of Nb， Ta， Zr， Hf， Ce， Ga， Sc and U in Geological Samples by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2010, 29(1): 74-76.
[7]	Interference and Its Elimination in Determination of Germanium and Cadmium in Geological Samples by Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(3): 197-200.
[8]	Determination of Iron in High Purity Indium by Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(3): 193-196.
[9]	Simultaneous Determination of Boron, Bromine and Iodine in Groundwater Samples by Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(1): 25-28.
[10]	Determination of 31 Components in Soil Samples by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2007, 26(6): 490-492.

Supplements (0)

Cited By

Cited by

Periodical cited type(9)

1.	龚婉莉，马克富，车永芳，李梦凡. 热导法测定固体生物质燃料中碳氢氮含量的称样量试验研究. 煤质技术. 2024(04): 79-84+91 .
2.	杨宗彩，徐学敏，杨佳佳，沈斌，苑坤，张小涛，许智超，翟佳. 沉积岩有机碳同位素组成测定的前处理方法研究. 岩矿测试. 2024(06): 847-857 . 本站查看
3.	栗敏，秦婧，白杨，何晨，徐学敏，陈践发. 原油不同含氮组分氮同位素的测定方法与分布特征. 岩矿测试. 2023(04): 771-780 . 本站查看
4.	胡志中，晏雄，金鹭，赵安坤，徐国栋，杜谷. 富有机质页岩氮同位素分析方法研究. 岩矿测试. 2023(04): 677-690 . 本站查看
5.	李宣孛，王瑞敏，黄天正，帅歌伟，沈冰. 贵州埃迪卡拉系陡山沱组磷块岩中硫酸根硫同位素测定与硫来源研究. 岩矿测试. 2022(04): 531-540 . 本站查看
6.	尹希杰，刘维维，王永涛，苏静，李廷伟. 元素分析-同位素质谱联用测定微量氮元素同位素方法研究. 质谱学报. 2021(03): 346-352 .
7.	常文博，李凤，张媛媛，贺行良. 元素分析-同位素比值质谱法测量海洋沉积物中有机碳和氮稳定同位素组成的实验室间比对研究. 岩矿测试. 2020(04): 535-545 . 本站查看
8.	李科，张琳，刘福亮，贾艳琨. 有机化学物质碳氮稳定同位素系列标准物质研制. 岩矿测试. 2020(05): 753-761 . 本站查看
9.	罗雪华，王文斌，吴小平，王大鹏，张永发，薛欣欣，赵春梅. 元素分析仪-稳定同位素比值质谱仪测定胶乳总固形物碳含量及其稳定碳同位素. 理化检验(化学分册). 2019(12): 1365-1372 .

Other cited types(1)

Get Citation

PDF

XML

Article views (2167) PDF downloads (46) Cited by(10)

Turn off MathJax

Article Contents

ABSTRACT

References

Petrogeochemical Characteristics and Metallogenetic Potential of Epimetamorphic Rocks in South Jiangxi Province