Geochemical Characteristics of Selenium in Rocks from the Western Sichuan Plateau

YANG Yan-ping; LIU Xiao-duan; LIU Jiu-chen; TANG Qi-feng; MENG Tuo; ZHU Xiao-hua

doi:10.15898/j.cnki.11-2131/td.201808290098

Rock and Mineral Analysis > 2020 > 39(1): 115-126. > DOI: 10.15898/j.cnki.11-2131/td.201808290098

YANG Yan-ping, LIU Xiao-duan, LIU Jiu-chen, TANG Qi-feng, MENG Tuo, ZHU Xiao-hua. Geochemical Characteristics of Selenium in Rocks from the Western Sichuan Plateau[J]. Rock and Mineral Analysis, 2020, 39(1): 115-126. DOI: 10.15898/j.cnki.11-2131/td.201808290098

Citation:

PDF (3914 KB)

Geochemical Characteristics of Selenium in Rocks from the Western Sichuan Plateau

1.
Key Laboratory of Eco-Geochemistry, Ministry of Natural Resources, National Research Center for Geoanalysis, Beijing 100037, China
2.
The Sceond Geological Brigade of Hebei Coal Geology Bureau, Xingtai 054001, China

More Information

Received Date: August 28, 2018
Revised Date: September 16, 2019
Accepted Date: October 20, 2019
Published Date: December 31, 2019

Abstract

HIGHLIGHTS
(1) The geochemical characteristics of selenium in rocks from western Sichuan were revealed.

(2) The selenium contents in different regions and different lithologies were quite different.

(3) Selenium content in rocks from Western Sichuan was mainly affected by geological environment, organic matter and rock compactness.

ABSTRACT

BACKGROUNDStudies on soil, water and other media in the Western Sichuan Plateau show that the selenium content in this area is very low. The selenium concentrations of the natural soil profile, surface soil, sediment, surface water, and groundwater are 0.06-0.16μg/g, 0.075-0.204μg/g, 0.069-0.310μg/g, nd-0.096μg/L and nd-0.058μg/L, respectively, which are all lower than the average selenium content in the corresponding environmental media in China, affecting the health of local people.
OBJECTIVESTo explore the geochemical characteristics of selenium in rocks in the study area and to find the influencing factors for low selenium in rocks.
METHODSEighty rock samples were collected from the Western Sichuan Plateau, and six core samples were collected at the same time. These samples were mainly slate, sandstone, limestone and shale. Atomic fluorescence spectrometry (AFS) was used to determine the selenium content, and the geochemical characteristics of selenium in rocks and core samples in the Aba area of the Western Sichuan Plateau were studied.
RESULTSThe selenium content of rocks ranged from 0.030 to 0.282μg/g, with an average value of 0.09μg/g, which was lower than the crustal abundance of selenium. The content of selenium in different types of rocks was:shale > limestone > slate > sandstone. The selenium content in the rock also showed large differences in different regions:Songpan > Aba > Land Pond > Maerkang > Jiuzhaigou > Ruoergai > Hongyuan, which may be caused by rock type, organic matter and geological environment. The minimum, maximum and average selenium content in each section of the core was 0.02-0.07μg/g, 0.21-0.34μg/g and 0.06-0.17μg/g, respectively. Moreover, the selenium content of each borehole was significantly lower than the crustal abundance of selenium.
CONCLUSIONSThe distribution of selenium in rocks is significantly affected by organic matter, lithology and rock compactness. Low selenium in rocks is mainly due to low selenium in environmental media in Western Sichuan.
- rocks,
- core,
- selenium,
- organic matter,
- atomic fluorescence spectrometry,
- geological environment

FullText(HTML)

References (41)

References

Rudnick R L, Gao S.Composition of the Continental Crust[M]//Rudnick R L.The Crust.Oxford: Elsevier-Pergamon, 2003: 1-64.

Zhu J M, Zuo W, Lian X B, et al.Occurrence of native selenium in Yutangba and its environmental implications[J].Applied Geochemistry, 2004, 19(3):461-467. doi: 10.1016/j.apgeochem.2003.09.001

Zhang B, Yang L, Wang W, et al.Environmental selenium in the Kaschin-Beck disease area, Tibetan Plateau, China[J].Environmental Geochemistry and Health, 2011(33):495-501. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=3e0b920bfa8d6ffda60bf1af2f61be95

Rayman M P.Selenium and human health[J].Lancel, 2012, 379:1256-1268. doi: 10.1016/S0140-6736(11)61452-9

郭宇.恩施地区硒的地球化学研究及富硒作物栽培实验研究[D].武汉: 中国地质大学(武汉), 2012. http://d.wanfangdata.com.cn/Thesis/Y2189942

Guo Y.Geochemistry of Selenium in Enshi Area and Experimental Study of Selenium-enriched Crop Cultivation[D].Wuhan: China University of Geosciences (Wuhan), 2012. http://d.wanfangdata.com.cn/Thesis/Y2189942

倪师军, 张成江, 徐争启, 等.四川万源地区硒的地球化学特征[J].矿物岩石, 2007, 27(4):39-44. doi: 10.3969/j.issn.1001-6872.2007.04.007

Ni S J, Zhang C J, Xu Z Q, et al.Geochemical characteristics of selenium in Wanyuan Area, Sichuan Province[J].Journal of Mineralogy and Petrology, 2007, 27(4):39-44. doi: 10.3969/j.issn.1001-6872.2007.04.007

朱晓华, 刘晓端, 汤奇峰, 等.阿坝高海拔地区多环境介质中硒的分布研究[J].西南师范大学学报(自然科学版), 2016, 41(9):30-36. http://d.old.wanfangdata.com.cn/Periodical/xnsfdxxb201609006

Zhu X H, Liu X D, Tang Q F, et al.On distribution of Se in multi-medium in Aba high-altitude areas[J].Journal of Southwest China Normal University (Natural Science Edition), 2016, 41(9):30-36. http://d.old.wanfangdata.com.cn/Periodical/xnsfdxxb201609006

李杰, 刘久臣, 汤奇峰, 等.川西高原地区水体中硒含量及分布特征研究[J].岩矿测试, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

Li J, Liu J C, Tang Q F, et al.Study of the contents and distribution of selenium in water samples from the Western Sichuan Plateau and the incidence of Kaschin Beck Disease[J].Rock and Mineral Analysis, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

张宝军, 杨林生, 王五一, 等.壤塘县大骨节病病区环境中硒的分布特征[J].地理科学进展, 2009, 28(6):886-891. http://d.old.wanfangdata.com.cn/Periodical/dlkxjz200906008

Zhang B J, Yang L S, Wang W Y, et al.Distribution characteristics of selenium in the environment of Kaschin-Beck Disease in Rangtang County[J].Progress in Geography, 2009, 28(6):886-891. http://d.old.wanfangdata.com.cn/Periodical/dlkxjz200906008

朱晓华, 刘晓端, 刘久臣, 等.川西高原天然剖面土壤硒的含量及分布特征[J].生态环境学报, 2015, 24(4):673-682. http://d.old.wanfangdata.com.cn/Periodical/tryhj201504019

Zhu X H, Liu X D, Liu J C, et al.Contents and distributions characteristics of selenium in natural soil profile samples from the Western Sichuan Plateau Area[J].Ecology and Environmental Sciences, 2015, 24(4):673-682. http://d.old.wanfangdata.com.cn/Periodical/tryhj201504019

吕瑶瑶, 余涛, 杨忠芳, 等.阿坝大骨节病区硒元素地球化学行为的研究[J].地球科学进展, 2012, 27(增刊1):386-387. http://d.old.wanfangdata.com.cn/Conference/7956036

Lü Y Y, Yu T, Yang Z F, et al.Study on geochemical behavior of selenium in Aba Kashin-Beck Disease area[J].Advances in Earth Science, 2012, 27(Supplement 1):386-387. http://d.old.wanfangdata.com.cn/Conference/7956036

吕瑶瑶.典型生态地带硒元素生物有效性的控制机理研究[D].北京: 中国地质大学(北京), 2016. Lü Y Y. http://cdmd.cnki.com.cn/Article/CDMD-11415-1016067634.htm

Study on Biological Effectiveness Control Mechanism of Selenium in Typical Ecological Zone[D].Beijing: China University of Geosciences (Beijing), 2016. http://cdmd.cnki.com.cn/Article/CDMD-11415-1016067634.htm

陈杜军.若尔盖地区硒地球化学特征[D].成都: 成都理工大学, 2012. http://cdmd.cnki.com.cn/Article/CDMD-10616-1012500468.htm

Chen D J.Geochemical Characteristics of Selenium in Zoige[D].Chengdu: Chengdu University of Technology, 2012. http://cdmd.cnki.com.cn/Article/CDMD-10616-1012500468.htm

肖先煊, 夏克勤.九寨沟县大录乡大骨节病区水文地球化学特征[J].南水北调与水利科技, 2010, 8(4):62-66. doi: 10.3969/SP.J.1201.2010.04062

Xiao X X, Xia K Q.Hydrogeochemical characteristics of the Kashin-Beck Disease distribution in Dalu Township, Jiuzhaigou County[J].South-to-North Water Transfers and Water Science & Technology, 2010, 8(4):62-66. doi: 10.3969/SP.J.1201.2010.04062

宋洁.四川省万源市典型特色农业区硒的地球化学特征[D].成都: 成都理工大学, 2015. http://cdmd.cnki.com.cn/Article/CDMD-10616-1017219194.htm

Song J.Geochemical Characteristics of Selenium in Typical Characteristic Agricultural Areas of Wanyuan City, Sichuan Province[D].Chengdu: Chengdu University of Technology, 2015. http://cdmd.cnki.com.cn/Article/CDMD-10616-1017219194.htm

黄慧, 李富忠, 邓佳云, 等.2007年四川省大骨节病监测结果分析[J].预防医学情报杂志, 2009, 25(6):467-468. http://d.old.wanfangdata.com.cn/Periodical/yfyxqbzz200906027

Huang H, Li F Z, Deng J Y, et al.Surveillance of Kashin-Bek syndrome in Sichuan Province, 2007[J].Journal of Preventive Medicine Information, 2009, 25(6):467-468. http://d.old.wanfangdata.com.cn/Periodical/yfyxqbzz200906027

Rahman M U, Kazi T G, Shaikh H, et al.Fractionation of manganese in soil samples collected from the Lakhracoal field in Pakistan using two modes of atomic absorption spectrometry[J].Atomic Spectroscopy, 2018, 39(6):258-263. https://www.sciencedirect.com/science/article/pii/S016651621630026X

Greco A D S, Sanjinez Argandona E J, Corazza M Z, et al.Use of chemometric tools for HG-AAS instrumental optimization in the determination of Se in nuts grown in Brazil[J].Atomic Spectroscopy, 2018, 39(6):251-257. https://www.researchgate.net/publication/333370130_Use_of_chemometric_tools_for_HG-AAS_instrumental_optimization_in_the_determination_of_se_in_nuts_grown_in_Brazil

Yuksel B, Arica E.Assessment of toxic, essential, and other metal levels by ICP-MS in Lake Eymir and Mogan in Ankara, Turkey:An environmental application[J].Atomic Spectroscopy, 2018, 39(5):179-184.

姜磊.万源富硒区土壤中硒元素环境化学特征研究[D].成都: 成都理工大学, 2010.

Jiang L.Wanyuan Selenium-rich Soil Environmental Geochemical Characteristics of Selenium[D].Chengdu: Chengdu University of Technology, 2010.

樊海峰, 温汉捷, 凌宏文, 等.表生环境中硒形态研究现状[J].地球与环境, 2006, 34(2):19-26. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx200602003

Fan H F, Wen H J, Ling H W, et al.Recent progress in research on selenium speciation in the supergene environment[J].Earth and Environment, 2006, 34(2):19-26. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx200602003

雒昆利, 潘云唐, 王五一, 等.南秦岭早古生代地层含硒量及硒的分布规律[J].地质论评, 2001, 47(2):211-217. doi: 10.3321/j.issn:0371-5736.2001.02.016

Luo K L, Pan Y T, Wang W Y, et al.Selenium content and distribution pattern in the Palaeozoic strata in the Sothern Qinling mountains[J].Geological Review, 2001, 47(2):211-217. doi: 10.3321/j.issn:0371-5736.2001.02.016

Savin S M, Epstein S.The oxygen isotopic compositions of coarse grained sedimentary rocks and minerals[J].Geochimica et Cosmochimica Acta, 1970, 34(3):323-329. doi: 10.1016/0016-7037(70)90109-2

冯彩霞, 刘燊, 胡瑞忠, 等.遵义下寒武统富硒黑色岩系地球化学:成因和硒富集机理[J].地球科学——中国地质大学学报, 2010, 35(6):947-958. http://d.old.wanfangdata.com.cn/Periodical/dqkx201006006

Feng C X, Liu S, Hu R Z, et al.Geochemistry of lower cambrian Se-rich black rock series in Zunyi, Guizhou Province, Southwest China:The petrogenesis and enrichment mechanism of selenium[J].Earth Sciences-Journal of China Geological University, 2010, 35(6):947-958. http://d.old.wanfangdata.com.cn/Periodical/dqkx201006006

刘英俊.曹励明, 李兆麟, 等.元素地球化学[M].北京:科学出版社, 1984:372-377.

Liu Y J, Cao L M, Li Z L, et al.Elemental Geochemistry[M].Beijing:Science Press, 1984:372-377.

李明龙, 徐辉, 许克元, 等.恩施地区富硒地层分布规律及其控制因素探讨[J].资源环境与工程, 2018, 32(4):557-562. http://d.old.wanfangdata.com.cn/Conference/9506017

Li M L, Xu H, Xu K Y, et al.Discussion on distribution regularity and controlling factors of selenium-rich strata in Enshi, Hubei Province[J].Resources Environment & Engineering, 2018, 32(4):557-562. http://d.old.wanfangdata.com.cn/Conference/9506017

程湘, 李福林, 王成刚, 等.鄂西地层硒的分布、富硒岩石成因及硒的来源[J].地质科技情报, 2019, 38(2):45-52. http://d.old.wanfangdata.com.cn/Periodical/dzkjqb201902006

Cheng X, Li F L, Wang C G, et al.Distribution law and control factors of selenium rich strata in Enshi area[J].Geological Science and Technology Information, 2019, 38(2):45-52. http://d.old.wanfangdata.com.cn/Periodical/dzkjqb201902006

Bech J, Suarez M, Reverter F, et al.Selenium and other trace elements in phosphate rock of Bayovar-Sechura (Peru)[J].Journal of Geochemical Exploration, 2010, 11:136-145. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=14d43fc6abaa0cf05e4d6de431ade15f

田欢.典型富硒区岩石-土壤-植物中硒的赋存状态及环境行为研究[D].北京: 中国地质大学(北京), 2017. http://cdmd.cnki.com.cn/Article/CDMD-10491-1017740241.htm

Tian H.The Occurrence State and Speciation of Selenium and Its Environmental Behaviors in Rock-Soil-Plant from Typical High-Se Areas[D].Beijing: China University of Geosciences (Beijing), 2017. http://cdmd.cnki.com.cn/Article/CDMD-10491-1017740241.htm

Li Z, Liang D L, Peng Q, et al.Interaction between selenium and soil organic matter and its impact on soil selenium bioavailability:A review[J].Geoderma, 2017, 295:69-79. doi: 10.1016/j.geoderma.2017.02.019

Supriatin S, Weng L P, Comans R N J.Selenium-rich dissolved organic matter determines selenium uptake in wheat grown on low-selenium arable land soils[J].Plant and Soil, 2016, 408(1-2):73-94. doi: 10.1007/s11104-016-2900-7

张聪, 夏响华, 杨玉茹, 等.安页1井志留系龙马溪组页岩有机质拉曼光谱特征及其地质意义[J].岩矿测试, 2019, 38(1):26-34. doi: 10.15898/j.cnki.11-2131/td.201803220025

Zhang C, Xia X H, Yang Y R, et al.Raman spectrum characteristics of organicmatter in Silurian Longmaxi Formation Shale of Well Anye-1 and its geological significance[J].Rock and Mineral Analysis, 2019, 38(1):26-34. doi: 10.15898/j.cnki.11-2131/td.201803220025

庞河清, 曾焱, 刘成川, 等.基于氮气吸附-核磁共振-氩离子抛光场发射扫描电镜研究川西须五段泥质岩储层孔隙结构[J].岩矿测试, 2017, 36(1):66-74. doi: 10.15898/j.cnki.11-2131/td.2017.01.010

Pang H Q, Zeng Y, Liu C C, et al.Investigation of pore structure of an argillaceous rocks reservoir in the 5th member of Xujiahe Formation in Western Sichuan, using NAM, NMR and AIP-FESEM[J].Rock and Mineral Analysis, 2017, 36(1):66-74. doi: 10.15898/j.cnki.11-2131/td.2017.01.010

邱灵佳, 黄国林, 帅琴, 等.灼烧法中有机质与总有机碳换算关系的重建及其在页岩分析中的应用[J].岩矿测试, 2015, 34(2):218-223. doi: 10.15898/j.cnki.11-2131/td.2015.02.011

Qiu L J, Huang G L, Shuai Q, et al.Reconstruction of the conversion relationship between organic matter and total organic carbon in calcination method and its application in shale analysis[J].Rock and Mineral Analysis, 2015, 34(2):218-223. doi: 10.15898/j.cnki.11-2131/td.2015.02.011

吴跃东, 向钒, 马玲, 等.安徽石台大山地区硒的地球化学研究[J].矿物岩石, 2007, 27(4):53-59. doi: 10.3969/j.issn.1001-6872.2007.04.009

Wu Y D, Xiang F, Ma L, et al.The geochemistry study of selenium in the stone mountain area of Anhui Province[J].Journal of Mineralogy and Petrology, 2007, 27(4):53-59. doi: 10.3969/j.issn.1001-6872.2007.04.009

秦海波, 朱建明.中国典型高硒区硒的环境地球化学研究进展[J].生物技术进展, 2017, 7(5):367-373. http://d.old.wanfangdata.com.cn/Periodical/swjsjz201705004

Qin H B, Zhu J M.Progress on environmental geochemistry of selenium in typical high-Se areas in China[J].Current Biology, 2017, 7(5):367-373. http://d.old.wanfangdata.com.cn/Periodical/swjsjz201705004

杨剑.黔北地区下寒武统黑色岩系形成环境与地球化学研究[D].西安: 长安大学, 2009. http://cdmd.cnki.com.cn/Article/CDMD-11941-2009176704.htm

Yang J.Study on the Formation Environment and Geochemistry of Lower Cambrian Black Shale Series, Northern Guizhou Province, China[D].Xi'an: Chang'an University, 2009. http://cdmd.cnki.com.cn/Article/CDMD-11941-2009176704.htm

樊海峰.中国南方含硒建造中硒稳定同位素与化学形态的地质意义[D].贵州: 中国科学院地球化学研究所, 2008. http://d.wanfangdata.com.cn/Thesis_Y1620917.aspx

Fan H F.Geological Significance of Stable Isotope and Chemical Form of Selenium in Construction of Selenium in Southern China[D].Guizhou: Institute of Geochemistry, Chinese Academy of Sciences, 2008. http://d.wanfangdata.com.cn/Thesis_Y1620917.aspx

韩文亮.恩施渔塘坝富硒碳质岩中硒的形态分析[D].贵阳: 中国科学院研究生院(地球化学研究所), 2006. http://d.wanfangdata.com.cn/Thesis_Y1615342.aspx

Han W L.Selenium Speciation of Se-rich Carbonaceous Rocks from Yutangba, Enshi, Hubei Province, China[D].Guiyang: Graduate School of Chinese Academy of Sciences (Institute of Geosciences), 2006. http://d.wanfangdata.com.cn/Thesis_Y1615342.aspx

李永华, 王五一.硒的土壤环境化学研究进展[J].土壤通报, 2002, 33(3):230-233. doi: 10.3321/j.issn:0564-3945.2002.03.018

Li Y H, Wang W Y.Process on the study soil environmental chemistry of selenium[J].Chinese Journal of Soil Science, 2002, 33(3):230-233. doi: 10.3321/j.issn:0564-3945.2002.03.018

张东威.中国土壤中硒及其土壤环境质量标准研究(简报)[J].水土保持研究, 1994(增刊):112. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400438601

Zhang D W.Research on the quality standards of selenium and its soil environment in Chinese soil (Brief)[J].Research of Soil and Water Conservation, 1994(Supplement):112. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400438601

[1]	JIAO Xingchun, ZHANG Zhaohe, FANG Wei, LI Ruimin, LIU Jiuchen, JIA Wenbin. Index System and Evaluation Method of Geological Environment Suitability for Human Health[J]. Rock and Mineral Analysis, 2023, 42(3): 433-444. DOI: 10.15898/j.ykcs.202211090214
[2]	MA Wan-ping, WEN Han-jie, YE Qin, ZHAO Yue, YANG Ji-hua. Determination of Trace Selenium in High-Carbon and High-Sulfur Geological Samples by Thiol Cotton Fiber Separation-Atomic Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2021, 40(4): 550-560. DOI: 10.15898/j.cnki.11-2131/td.202101220013
[3]	Cong ZHANG, Xiang-hua XIA, Yu-ru YANG, Ming-gang BAI, Feng DAI, Jie XIONG. Raman Spectrum Characteristics of Organic Matter in Silurian Longmaxi Formation Shale of Well Anye-1 and Its Geological Significance[J]. Rock and Mineral Analysis, 2019, 38(1): 26-34. DOI: 10.15898/j.cnki.11-2131/td.201803220025
[4]	MA Jian-xue, LU Xue-dong, XU Zhuo. Determination of Micro-amount and Trace Gold in Geological Samples by Chemical Vapor Generation-non-Dispersive Atomic Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(3): 343-348.
[5]	ZHU Yuan-yuan, SONG Hu-yue, QIU Hai-ou, TANG Zhi-yong. Determination of Zinc in Geological Samples by Steam Generation- Atomic Fluorescence Spectrometry with Alkaline System[J]. Rock and Mineral Analysis, 2010, 29(6): 695-698.
[6]	XU Guo-dong, GE Jian-hua, JIA Hui-xian, DU Gu, CHENG Jiang, DONG Jun. Simultaneous Determination of Trace Arsenic and Mercury in Geological Samples by Hydride Generation-Atomic Fluorescence Spectrometry with Water Bath Soaking Sample Preparation[J]. Rock and Mineral Analysis, 2010, 29(4): 391-394.
[7]	Determination of Trace Selenium in Soil Samples by Hydride Generation-Atomic Fluorescence Spectrometry with Baking Separation[J]. Rock and Mineral Analysis, 2008, 27(2): 120-122.
[8]	Determination of Trace Bismuth in Geological Samples by Hydride Generation-Atomic Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2005, (3): 217-220.
[9]	Determination of Trace Germanium in Geological Samples by Hydride Generation Atomic Fluorescence Spectrometry with Alkaline Mode[J]. Rock and Mineral Analysis, 2004, (4): 295-299.
[10]	Determination of Trace Germanium in Geological Samples by Hydride Generation Atomic Fluorescence Sepctrometry[J]. Rock and Mineral Analysis, 2004, (3): 231-234.

Supplements (0)

Cited By

Cited by

Periodical cited type(18)

1.	赵芳芳，诸堃，文芳. 超级微波消解-电感耦合等离子体发射光谱测银矿石中的银. 四川地质学报. 2024(01): 167-170 .
2.	赵凯，芦新根，肖千鹏，张晶晶，谭书宇. 镍锍试金法富集地质样品中铂、钯、铑、铱. 化学分析计量. 2024(05): 66-71 .
3.	郭家凡，陈笑语，孙勇，仲伟路，朱少璇，王琳. 镍锍试金富集-电感耦合等离子体质谱法测定地质样品中超痕量铂族元素. 岩矿测试. 2024(05): 693-702 . 本站查看
4.	王夺. 镍锍试金-微波消解法联合测定汽车三元催化剂中铑. 有色矿冶. 2023(02): 59-61+49 .
5.	刘芳美，甘聪，廖彬玲，罗小兵，赖秋祥. 锍镍试金富集-电感耦合等离子体质谱法测定铜阳极泥中微量元素铱铑. 岩矿测试. 2023(02): 298-306 . 本站查看
6.	周彧琛，曲少鹏，吴俊，贾正勋，马景治. 改性三聚氰胺泡塑富集-电感耦合等离子体质谱(ICP-MS)法测定矿样中的钯. 中国无机分析化学. 2023(07): 735-740 .
7.	李杰阳. 复杂多金属铜硫矿物中金含量的测定. 云南冶金. 2022(01): 110-115 .
8.	陈永红，韩冰冰，洪博，芦新根，孟宪伟. 2019—2020年中国银分析测定的进展. 黄金. 2022(02): 104-110 .
9.	杨昆. 铜镍硫化物矿物中铂族元素的分析研究. 化工管理. 2022(08): 13-15 .
10.	张广安，张福元. 火试金灰皿在乙酸-H_2O体系中铅的浸出动力学. 过程工程学报. 2022(06): 774-781 .
11.	樊蕾，王甜甜，姚明星，孙启亮，郭晓瑞. 锑铜试金-石墨炉原子吸收光谱法测定地球化学样品中痕量钌. 冶金分析. 2022(08): 35-41 .
12.	胡振隆. 金矿的样品制备与分析方法研究进展. 世界有色金属. 2022(11): 187-189 .
13.	刘向磊，孙文军，文田耀，王腾飞，王凯凯，刘宗超. 地质样品中贵金属分析方法现状及展望. 冶金分析. 2022(12): 23-35 .
14.	王楠，周宇，任士远，陈明丽，刘西. 分离富集技术在痕量贵金属分析中的应用与进展. 冶金分析. 2022(12): 12-22 .
15.	郭家凡，来新泽，王琳，胡家祯，高志军，来佳仪. 火试金反应原理及熔渣影响因素探究. 冶金分析. 2022(12): 1-11 .
16.	贾欣欣. 地质样品中金的测定研究. 世界有色金属. 2020(06): 164-165 .
17.	张强. 地质矿石样品中金、银含量测定方法的探讨. 世界有色金属. 2020(10): 157-158 .
18.	张明，杨生鸿，朱琳，安国荣，韩永辉. 铜镍硫化物矿物中铂族元素的分析研究. 化工矿产地质. 2020(04): 343-347 .

Other cited types(1)

Get Citation

PDF

XML

Article views (2600) PDF downloads (53) Cited by(19)

Turn off MathJax

Article Contents

ABSTRACT

References

Geochemical Characteristics of Selenium in Rocks from the Western Sichuan Plateau