• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
Advanced Search
XU Guo-dong, GE Jian-hua, JIA Hui-xian, DU Gu, CHENG Jiang, DONG Jun. Simultaneous Determination of Trace Arsenic and Mercury in Geological Samples by Hydride Generation-Atomic Fluorescence Spectrometry with Water Bath Soaking Sample Preparation[J]. Rock and Mineral Analysis, 2010, 29(4): 391-394.
Citation: XU Guo-dong, GE Jian-hua, JIA Hui-xian, DU Gu, CHENG Jiang, DONG Jun. Simultaneous Determination of Trace Arsenic and Mercury in Geological Samples by Hydride Generation-Atomic Fluorescence Spectrometry with Water Bath Soaking Sample Preparation[J]. Rock and Mineral Analysis, 2010, 29(4): 391-394.
shu

Simultaneous Determination of Trace Arsenic and Mercury in Geological Samples by Hydride Generation-Atomic Fluorescence Spectrometry with Water Bath Soaking Sample Preparation

  • 1.

    Chengdu Institute of Geology and Mineral Resources, Chengdu 610081, China

  • 2.

    Chengdu Institute of Geology and Mineral Resources, Chengdu 610081, China

  • 3.

    Chengdu Institute of Termite Control, Chengdu 610016, China

  • 4.

    Chengdu Institute of Geology and Mineral Resources, Chengdu 610081, China

  • 5.

    Chengdu Institute of Geology and Mineral Resources, Chengdu 610081, China

  • 6.

    Chengdu Institute of Geology and Mineral Resources, Chengdu 610081, China

More Information
  • Received Date: November 22, 2009
  • Revised Date: January 26, 2010
    Abstract
  • Geological sample was digested with mixed acid (VHCl∶VHNO3∶VH2O=3∶1∶4) in water bath and then the mixed solution of thiourea and ascorbic acid as the reductant was directly added in the sample solution. The arsenic and mercury in the sample solution were determined simultaneously by hydride generation-atomic fluorescence spectrometry. The detection limits of the method for arsenic and mercury were 0.0336 ng/mL and 0.0037 ng/mL, respectively. The reliability of the method was tested by determination of arsenic and mercury in National Standard Reference materials of GBW 07109~07114, GBW 07301~07312, GBW 07401~07408. The results were in agreement with the certified values with precision of 1.1%RSD for As and 3.0%RSD for Hg.
    • FullText(HTML)
    • References (10)
  • 岩石矿物分析编写组.岩石矿物分析(第一分册)[M].3版.北京:地质出版社,1991:466,514.
    邱宏喜,张汝生,张永红.快速测定金矿样品中的砷锑铋汞[J].黄金,2007,28(6):54-56.
    高皴,杨海霞,于卫荣.氢化物发生原子荧光光谱法同时测定海洋沉积物中的砷和汞[J].海洋水产研究,2005,26(4):53-59.
    沈志群.双道原子荧光同时测定海水中痕量砷和汞[J].环境监测管理与技术,2005,17(6):30-31.
    赵立红,刘亚丽.水浴浸提-氢化物发生-原子荧光光谱法检测土壤中痕量砷和汞[J].光谱实验室,2007,24(6):1090-1094.
    赵振平,张怀成,冷家峰,邓保军.王水消解蒸气发生-原子荧光光谱法测定土壤中的砷、锑和汞[J].中国环境监测,2004,20(1):44-46.
    李晓红.原子荧光光谱法测定化探样品中的砷锑铋汞[J].理化检验:化学分册,1999,35(3):119-123.
    邬春华,吕元琦,袁倬斌.微波消解原子荧光光谱法测定生物样品中砷汞[J].理化检验:化学分册,2006,42(1):41-42.
    邱宏喜.原子荧光光谱法直接连续测定化探样品中的As、Sb、Bi、Hg[J].黄金地质,1999, 5(1):73-76.
    郭小伟,李立.氢化物-原子吸收及荧光法中的干扰及消除[J].分析化学,1986,14(2):151-158.
    • Related Articles

  • Related Articles

    [1]Zhen YANG, Pan-hong HE, Yan-ling ZHANG, Yin-sheng SUN, Yao RONG, Wei ZHANG. Determination of Trace Lead in Uranium-bearing Geological Samples by Inductively Coupled Plasma-Optical Emission Spectrometry with Double Capillary On-line Interference Correction[J]. Rock and Mineral Analysis, 2015, 34(5): 528-532. DOI: 10.15898/j.cnki.11-2131/td.2015.05.005
    [2]Bin-bin XI, Wei-jun SHI, Fang BAO, Hong JIANG. Using Laser Raman Microprobe and Fused Silica Capillaries to Determine Salinity of Fluid Inclusions[J]. Rock and Mineral Analysis, 2013, 32(1): 34-39.
    [3]ZENG Fan-gang. Analysis of Organochlorine Pesticide Residues in Marine Fishes from South China Sea[J]. Rock and Mineral Analysis, 2010, 29(3): 241-244.
    [4]YAN Na, CEHN Xingguo. Recent Progress of On-line Sample Preconcentration in Capillary Electrophoresis[J]. Rock and Mineral Analysis, 2009, 28(4): 351-360.
    [5]Determination of Organophosphorous Pesticide Residues in Water Samples by Large-bore Capillary Column-Gas Chromatography with Flame Photometric Detector[J]. Rock and Mineral Analysis, 2007, 26(1): 17-20.
    [6]Capillary Electrophoresis and Its Application Progress in Environmental Analysis[J]. Rock and Mineral Analysis, 2003, (2): 144-150.
    [7]Determination of BTEX Compounds in Marine Shallow Sediments by Micellar Electrokinetic Capillary Chromatography[J]. Rock and Mineral Analysis, 2001, (1): 20-22.
    [8]Determination of BTEX Compounds in Debris Samples by Micellar Electrokinetic Capillary Chromatography[J]. Rock and Mineral Analysis, 2000, (2): 93-96.
    [9]A Novel Hydride Generation Technique\=Movable Reduction Bed Hydride Generator\=. As an Interface between Capillary Zone\=Electrophoresis and ICPAES for\= Arsenic Speciation Analysis[J]. Rock and Mineral Analysis, 1999, (3): 165-170.
    [10]Determination of Methylmercury and Ethylmercury in Environmental Water by Megabore Capillary Gas Chromatography after Preconcentration[J]. Rock and Mineral Analysis, 1993, (2): 131-134.
    • Supplements (0)

Catalog

    Get Citation
    PDF
    XML
    Article views (2008) PDF downloads (1312) Cited by()
    Turn off MathJax
    Article Contents
    ABSTRACT
    References
    Related Articles

    Competent Authorities：China Association for Science and Technology

    Sponsored by：Geological Society of China; National Research Center for Geoanalysis

    Address：No. 26 Baiwanzhuang Road, Xicheng District, Beijing 100037, China Email：ykcs_zazhi@163.com Tel：010-68999562

    京公网安备 11010202008159号 京ICP备2022024991号

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return