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BAO Zhi-an, YUAN Hong-lin, CHEN Kai-yun, SONG Jia-yao, DAI Meng-ning, ZONG Chun-lei. Primary Research on A Synthetic Experimental Method of Andesite Standard Glass References by Using High-Temperature Fusion[J]. Rock and Mineral Analysis, 2011, 30(5): 521-527.
Citation: BAO Zhi-an, YUAN Hong-lin, CHEN Kai-yun, SONG Jia-yao, DAI Meng-ning, ZONG Chun-lei. Primary Research on A Synthetic Experimental Method of Andesite Standard Glass References by Using High-Temperature Fusion[J]. Rock and Mineral Analysis, 2011, 30(5): 521-527.

Primary Research on A Synthetic Experimental Method of Andesite Standard Glass References by Using High-Temperature Fusion

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  • Received Date: January 12, 2011
  • Revised Date: April 24, 2011
  • Geological standard glass materials are playing an important role in Laser Ablation Quadrupole Inductively Coupled Plasma-Mass Spectrometry (LA-Q-ICPMS). However, the intensive applications in LA-Q-ICPMS are restrained due to the lack of research on synthetic methods of geological standard glass materials. In this paper, the method of high-temperature fusion was chosen to synthesize standard andesite glass (GSR-2G) by using national standard andesite powder (GSR-2). Three effect factors of time, temperature and quenching were studied to ascertain homogeneity. Results show that the homogeneity of andesite glass is optimal when the synthetic temperature is 1300 ℃ for 4 hours and the andesite glass is quenched by liquid nitrogen. Therefore, andesite glass can be used as an internal standard material for microprobe analysis. The relative deviations of 35 trace elements and 10 major elements were less than 10% for GSR-2G andesite glass by using 193 nm ArF LA-Q-ICPMS. The relative deviations of measured values obtained for 35 trace elements from 7Li to 238U by chemical method (SN-Q-ICPMS) and LA-Q-ICPMS were generally better than 10%. The results obtained by Electron Microprobe Analysis (EMPA) for 10 major elements from 23Na to 56Fe were consistent with these by LA-Q-ICPMS. The obtained average values of 40 elements by LA-Q-ICPMS can be used as primary reference values for andesite glass of GSR-2G.
  • Darke S A, Long S E, Pickford C J, Tyson J F. A study of laser ablation and slurry nebulisation sample introduction for the analysis of geochemical materials by inductively coupled plasma spectrometry [J].Fresenius' Journal of Analytical Chemistry,1990, 337(3):284-289.

    Darke S A, Long S E, Pickford C J, Tyson J F. A study of laser ablation and slurry nebulisation sample introduction for the analysis of geochemical materials by inductively coupled plasma spectrometry [J].Fresenius' Journal of Analytical Chemistry,1990, 337(3):284-289.
    Jackson S E, Longerich H P, Dunning C R, Fryer B J. The application of laser ablation microprobe-inductively coupled plasma-mass specmetry (LAM-ICP-MS) to in-situ trace element determinations in minerals [J].Canadian Mineral-ogist,1992,30:1049-1064.

    Jackson S E, Longerich H P, Dunning C R, Fryer B J. The application of laser ablation microprobe-inductively coupled plasma-mass specmetry (LAM-ICP-MS) to in-situ trace element determinations in minerals [J].Canadian Mineral-ogist,1992,30:1049-1064.
    Fedorowich J S, Richards J P, Jain J C, Kerrich R, Fan J. A rapid method for REE and trace-element analysis using laser sampling ICP-MS on direct fusion whole-rock glasses [J].Chemical Geology,1993, 106(3-4):229-249.

    Fedorowich J S, Richards J P, Jain J C, Kerrich R, Fan J. A rapid method for REE and trace-element analysis using laser sampling ICP-MS on direct fusion whole-rock glasses [J].Chemical Geology,1993, 106(3-4):229-249.
    Jarvis K E, Williams J G. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS): A rapid technique for the direct, quantitative determination of major, trace and rare-earth elements in geological samples[J].Chemical Geology,1993,106(3-4):251-262.

    Jarvis K E, Williams J G. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS): A rapid technique for the direct, quantitative determination of major, trace and rare-earth elements in geological samples[J].Chemical Geology,1993,106(3-4):251-262.
    Jenner G A, Foley S F, Jackson S E, Green T H, Fryer B J, Longerich H P. Determination of partition coefficients for trace elements in high pressure-temperature experimental run products by laser ablation microprobe-inductive coupled plasma-mass spectrometry (LAM-ICP-MS )[J].Geochim-ica et Cosmochimica Acta,1993,58(23-24):5099-5103.

    Jenner G A, Foley S F, Jackson S E, Green T H, Fryer B J, Longerich H P. Determination of partition coefficients for trace elements in high pressure-temperature experimental run products by laser ablation microprobe-inductive coupled plasma-mass spectrometry (LAM-ICP-MS )[J].Geochim-ica et Cosmochimica Acta,1993,58(23-24):5099-5103.
    Feng R. In-situ trace element determination of carbonates by Laser-Probe inductively coupled plasma mass spectrometry using nonmatrix matched standardization [J].Geochimica et Cosmochimica Acta,1994,58(6):1615-1623.

    Feng R. In-situ trace element determination of carbonates by Laser-Probe inductively coupled plasma mass spectrometry using nonmatrix matched standardization [J].Geochimica et Cosmochimica Acta,1994,58(6):1615-1623.
    Jeffries T E, Perkins W T, Pearce N J G. Measurements of trace elements in basalts and their phenocrysts by laser probe microanalysis inductively coupled plasma mass spectrometry (LPMA-ICP-MS) [J].Chemical Geology,1995,121(1-4):131-144.

    Jeffries T E, Perkins W T, Pearce N J G. Measurements of trace elements in basalts and their phenocrysts by laser probe microanalysis inductively coupled plasma mass spectrometry (LPMA-ICP-MS) [J].Chemical Geology,1995,121(1-4):131-144.
    Morrison C A, Lambert D D, Morrison R J S, Ahlers W W, Nicholls I A. Laser ablation-inductively coupled plasma-mass spectrometry: An investigation of elemental responses and matrix effects in the analysis of geological materials[J].Chemical Geology,1995,119(1-4):13-29.

    Morrison C A, Lambert D D, Morrison R J S, Ahlers W W, Nicholls I A. Laser ablation-inductively coupled plasma-mass spectrometry: An investigation of elemental responses and matrix effects in the analysis of geological materials[J].Chemical Geology,1995,119(1-4):13-29.
    Hirata T, Nesbitt R W. U-Pb isotope geochronology of zircon: Evaluation of the laser probe-inductively coupled plasma mass spectrometry technique[J].Geochimica et Cosmochimica Acta,1995,59(12):2491-2500.

    Hirata T, Nesbitt R W. U-Pb isotope geochronology of zircon: Evaluation of the laser probe-inductively coupled plasma mass spectrometry technique[J].Geochimica et Cosmochimica Acta,1995,59(12):2491-2500.
    Shepherd T J, Chenery S R. Laser ablation ICP-MS elemental analysis of individual fluid inclusions: An evaluation study[J].Geochimica et Cosmochimica Acta,1995,59(19):3997-4007.

    Shepherd T J, Chenery S R. Laser ablation ICP-MS elemental analysis of individual fluid inclusions: An evaluation study[J].Geochimica et Cosmochimica Acta,1995,59(19):3997-4007.
    Günther D, Jackson S E, Longerich H P. Laser ablation and arc/spark solid sample introduction into inductively coupled plasma mass spectrometers[J].Spectrochimica Acta Part B: Atomic Spectroscopy,1999,54(3-4):381-409.

    Günther D, Jackson S E, Longerich H P. Laser ablation and arc/spark solid sample introduction into inductively coupled plasma mass spectrometers[J].Spectrochimica Acta Part B: Atomic Spectroscopy,1999,54(3-4):381-409.
    罗彦,胡圣虹,刘勇胜,高山,林守麟.激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)微区分析新进展[J]. 分析化学,2001,29(11):1345-1352.
    Günther D, Hattendorf B. Solid sample analysis using laser ablation inductively coupled plasma mass spectrometry[J].Trends in Analytical Chemistry,2005,24(3):255-263.

    Günther D, Hattendorf B. Solid sample analysis using laser ablation inductively coupled plasma mass spectrometry[J].Trends in Analytical Chemistry,2005,24(3):255-263.
    Guzmics T, Zajacz Z, Kodolányi J, Halter W, Szabó C. LA-ICP-MS study of apatite- and K feldspar-hosted primary carbonatite melt inclusions in clinopyroxenite xenoliths from lamprophyres, Hungary: Implications for significance of carbonatite melts in the Earth's mantle[J].Geochimica et Cosmochimica Acta,2008,72(7):1864-1886.

    Guzmics T, Zajacz Z, Kodolányi J, Halter W, Szabó C. LA-ICP-MS study of apatite- and K feldspar-hosted primary carbonatite melt inclusions in clinopyroxenite xenoliths from lamprophyres, Hungary: Implications for significance of carbonatite melts in the Earth's mantle[J].Geochimica et Cosmochimica Acta,2008,72(7):1864-1886.
    Mcleod C W, Date A R, Cheung Y Y. Metal oxide ions in inductively coupled plasma mass spectrometric analysis of nickel base alloys[J].Spectrochimica Acta Part B: Atomic Spectroscopy,1986,41(1-2):169-174.

    Mcleod C W, Date A R, Cheung Y Y. Metal oxide ions in inductively coupled plasma mass spectrometric analysis of nickel base alloys[J].Spectrochimica Acta Part B: Atomic Spectroscopy,1986,41(1-2):169-174.
    Chen Z X. Inter-element fractionation and correction in laser ablation-inductively coupled plasma mass spectrometry[J].Journal of Analytical Atomic Spectrometry,1999,14(12):1823-1828.

    Chen Z X. Inter-element fractionation and correction in laser ablation-inductively coupled plasma mass spectrometry[J].Journal of Analytical Atomic Spectrometry,1999,14(12):1823-1828.
    胡圣虹,胡兆初,刘勇胜,罗彦,林守麟,高山.单个流体包裹体元素化学组成分析新技术——激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS) [J].地学前缘,2001,8(4):434-440.
    尹明. 我国地质分析测试技术发展现状及趋势[J]. 岩矿测试,2009,28(1):37-52.
    Eggins S M, Shelley J M G. Compositional heterogeneity in NIST SRM 610-617 glasses [J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,2002,26:269-286.

    Eggins S M, Shelley J M G. Compositional heterogeneity in NIST SRM 610-617 glasses [J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,2002,26:269-286.
    Guillong M, Hametner K, Reusser E, Wilson S A, Günther D. Preliminary characterisation of new glass reference materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by laser ablation-inductively coupled plasma-mass spectro-metry using 193 nm, 213 nm and 266 nm wavelengths[J].Geostandards and Geoanalytical Research,2005,29:315-331.

    Guillong M, Hametner K, Reusser E, Wilson S A, Günther D. Preliminary characterisation of new glass reference materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by laser ablation-inductively coupled plasma-mass spectro-metry using 193 nm, 213 nm and 266 nm wavelengths[J].Geostandards and Geoanalytical Research,2005,29:315-331.
    Jochum K P, Dingwell D B, Rocholl A, Stoll B, Hofmann A W, Becker S, Besmehn A, Bessette D, Dietze H J, Dulski P, Erzinger J, Hellebrand E, Hoppe P, Horn I, Janssens K, Jenner G A, Klein M, McDonough W F, Maetz M, Mezger K, Münker C, Nikogosian I K, Pickhardt C, Raczek I, Rhede D, Seufert H M, Simakin S G, Sobolev A V, Spettel B, Straub S, Vincze L, Wallianos A, Weckwerth G, Weyer S, Wolf D, Zimmer M. The preparation and preliminary characterisation of eight geological MPI-DING reference glasses for in-situ microanalysis[J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,2000,24:87-133.

    Jochum K P, Dingwell D B, Rocholl A, Stoll B, Hofmann A W, Becker S, Besmehn A, Bessette D, Dietze H J, Dulski P, Erzinger J, Hellebrand E, Hoppe P, Horn I, Janssens K, Jenner G A, Klein M, McDonough W F, Maetz M, Mezger K, Münker C, Nikogosian I K, Pickhardt C, Raczek I, Rhede D, Seufert H M, Simakin S G, Sobolev A V, Spettel B, Straub S, Vincze L, Wallianos A, Weckwerth G, Weyer S, Wolf D, Zimmer M. The preparation and preliminary characterisation of eight geological MPI-DING reference glasses for in-situ microanalysis[J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,2000,24:87-133.
    Rocholl A. Major and trace element composition and homogeneity of microbeam reference material: Basalt glass USGS BCR-2G[J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,1998,22:33-45.

    Rocholl A. Major and trace element composition and homogeneity of microbeam reference material: Basalt glass USGS BCR-2G[J].Geostandards Newsletter: The Journal of Geostandards and Geoanalysis,1998,22:33-45.
    Yuan H L, Gao S, Dai M N, Zong C L,Günther D, Fontaine G H, Liu X M, Diwu C L. Simultaneous determinations of U-Pb age, Hf isotopes and trace element compositions of zircon by excimer laser-ablation quadrupole and multiple-collector ICP-MS [J].Chemical Geology,2008,247(1-2):100-118.

    Yuan H L, Gao S, Dai M N, Zong C L,Günther D, Fontaine G H, Liu X M, Diwu C L. Simultaneous determinations of U-Pb age, Hf isotopes and trace element compositions of zircon by excimer laser-ablation quadrupole and multiple-collector ICP-MS [J].Chemical Geology,2008,247(1-2):100-118.
    Liu X M, Gao S, DiWu C R, Yuan H L, Hu Z C. Simultaneous in-situ determination of U-Pb age and trace elements in zircon by LA-ICP-MS in 20μm spot size[J].Chinese Science Bulletin,2007,52(9):1257-1264.

    Liu X M, Gao S, DiWu C R, Yuan H L, Hu Z C. Simultaneous in-situ determination of U-Pb age and trace elements in zircon by LA-ICP-MS in 20μm spot size[J].Chinese Science Bulletin,2007,52(9):1257-1264.
    鄢明才,顾铁新,程志中.地球化学标准物质的研制与应用[J].物探化探计算技术,2007,29(1):257-261.
    王晓红,王毅民,高玉淑,樊兴涛.地质标准物质均匀性检验方法评介与探讨[J].岩矿测试,2010,29(6):735-741.

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