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WANG Na, WANG Hai-jiao, WANG Yin-fu, LI Li-jun. Determination of 9 Organochlorine Pesticides in Water Samples by Liquid-liquid Extraction-Gas Chromatography[J]. Rock and Mineral Analysis, 2010, 29(5): 497-502.
Citation: WANG Na, WANG Hai-jiao, WANG Yin-fu, LI Li-jun. Determination of 9 Organochlorine Pesticides in Water Samples by Liquid-liquid Extraction-Gas Chromatography[J]. Rock and Mineral Analysis, 2010, 29(5): 497-502.
shu

Determination of 9 Organochlorine Pesticides in Water Samples by Liquid-liquid Extraction-Gas Chromatography

  • 1.

    Shenyang Institute of Geology and Mineral Resources, Shenyang 110032, China

  • 2.

    Shenyang Institute of Geology and Mineral Resources, Shenyang 110032, China

  • 3.

    Shenyang Institute of Geology and Mineral Resources, Shenyang 110032, China

  • 4.

    Shenyang Institute of Geology and Mineral Resources, Shenyang 110032, China

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  • Received Date: January 17, 2010
  • Revised Date: June 19, 2010
    Abstract
  • Nine organochlorine pesticides were determined by gas chromatography with electron capture detector (ECD) after samples pre-treatment by liquid-liquid extraction with n-hexane and purified with concentrated sulfuric acid. The double capillary columns of Rtx-5MS and Rtx-1701 were used for identifying the target compounds. The experimental conditions were optimized and two surrogates were chosen for quality control. The detection limits of the method for 9 organochlorine pesticides were in the range of 0.0017~0.0079 μg/L with linear ranges of 0.5~100 μg/L. The recoveries were 74.7%~105.1% with the precision of 4.2%~9.3% RSD (n＝7). The method provides the advantages of low detection limits, good accuracy and precision, simple operation and is suitable for routine analysis of organochlorine pesticides in water samples.
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