Inter-Laboratory Comparison of Analysis for Hydrogen and Oxygen Stable Isotope Ratios in Water Samples by Laser Absorption Spectroscopy

Gao-yong LAN; Xia WU; Hui YANG; Wei TANG; Qi-he YING; Hua WANG

doi:10.15898/j.cnki.11-2131/td.201704060049

Rock and Mineral Analysis > 2017 > 36(5): 460-467. > DOI: 10.15898/j.cnki.11-2131/td.201704060049

Gao-yong LAN, Xia WU, Hui YANG, Wei TANG, Qi-he YING, Hua WANG. Inter-Laboratory Comparison of Analysis for Hydrogen and Oxygen Stable Isotope Ratios in Water Samples by Laser Absorption Spectroscopy[J]. Rock and Mineral Analysis, 2017, 36(5): 460-467. DOI: 10.15898/j.cnki.11-2131/td.201704060049

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Inter-Laboratory Comparison of Analysis for Hydrogen and Oxygen Stable Isotope Ratios in Water Samples by Laser Absorption Spectroscopy

Key Laboratory of Karst Dynamics, Ministry of Land and Resources & Guangxi, Institute of Karst Geology, Chinese Academy of Geological Sciences, Guilin 541004, China

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Received Date: April 05, 2017
Revised Date: July 10, 2017
Accepted Date: July 19, 2017
Published Date: August 31, 2017

Abstract

Highlights
· It is high precision for δD(0.4‰, 1σ) and δ¹⁸O(0.05‰，1σ) in water sample determined by Laser Absorption Spectroscopy.

· The repeatabil ity and reproducibility for measurement of δD and δ¹⁸O in water samples obtained from inter-laboratory analysis are excellent.

· The inter-laboratory analysis data provide a reference for the development the standard method of Laser Absorption Spectroscopy for measurement of δD and δ¹⁸O isotopes in environmental waters.

ABSTRACT

Laser Absorption Spectroscopy technology is a convenient and rapid method for the simultaneous determination of hydrogen and oxygen isotope ratios in environmental water samples. This method has been widely used in the environment, geology, ecology, and energy fields due to its simplicity, high detection efficiency, and portability. However, no national standards are available for this method and thus the analytical results are not traceable effectively. Moreover, the use of this method lacks norms and unity. In order to evaluate the accuracy and precision of the Laser Absorption Spectroscopy method for the determination of δD, δ¹⁸O, D/H and ¹⁸O/¹⁶O values of eight water samples (δD value of within -189.1‰-0.4‰, δ¹⁸O value of within -24.52‰-0.32‰), values were determined by 12 laboratories using optical cavity enhanced absorption spectroscopy. Data from each collaboration laboratory is accurate, stable, and reproducible. The precision value of δD is 0.4‰ (1σ) and δ¹⁸O is 0.05‰ (1σ), comparable to the traditional mass spectrometry method. Therefore, the method is suitable for the on-line and real-time determination of hydrogen and oxygen isotope ratio in the field. This study provides a reference for the development and application of the standard method for determination of δD and δ¹⁸O isotopes in environmental water.
- Laser Absorption Spectroscopy,
- hydrogen isotope,
- oxygen isotope,
- inter-laboratory comparison,
- environmental water sample

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References (23)

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Inter-Laboratory Comparison of Analysis for Hydrogen and Oxygen Stable Isotope Ratios in Water Samples by Laser Absorption Spectroscopy

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