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BAI Jin-feng, BO Wei, ZHANG Qin, WANG Hai-ying. Determination of 36 Elements in Geochemical Samples by High Resolution Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(5): 814-819.
Citation: BAI Jin-feng, BO Wei, ZHANG Qin, WANG Hai-ying. Determination of 36 Elements in Geochemical Samples by High Resolution Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(5): 814-819.
shu

Determination of 36 Elements in Geochemical Samples by High Resolution Inductively Coupled Plasma-Mass Spectrometry

  • 1.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 2.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 3.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 4.

    Institute of Inner Mongolia Mineral Experiment, Hohhot 010031, China

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  • Received Date: December 18, 2011
    Abstract
  • An analytical method for the simultaneous determination of Li, Be, P, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Rb, Sr, Nb, Mo, Cd, In, Sb, Cs, Ba, Hf, Ta, W, Tl, Pb, Bi, Th, U, Na2O, MgO, Al2O3, K2O, CaO and TFe2O3 in geochemical samples by High Resolution-Inductively Coupled Plasma-Mass Spectrometry (HR-ICP-MS) has been developed. Samples were decomposed using HF-HNO3-HClO4, and the residue was dissolved with aqua regia. The 36 elements in the solution were then determined directly by HR-ICP-MS. The optimal determination isotope and appropriate resolution for the 36 elements were selected to avoid the main spectra interferences from polyatomic ions and double charged ions. The detection limits (6σ) of the method were 0.002-2.031 μg/g for trace elements, and 10.0-100 μg/g for major elements (DF=1000). The relative standard deviation (RSD) was less than 10% (n=12). The method has been applied to the determination of 36 elements in national geochemical standard reference materials and the analytical results were in agreement with certified values.
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    • References (19)
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