• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
Advanced Search
LI Xue-gang, SONG Jin-ming, YUAN Hua-mao, LI Ning. Determination of Ammonia-Nitrogen in Marine Sediments by Hypo-bromate Oxidation with Hydrochloric Acid Extraction[J]. Rock and Mineral Analysis, 2011, 30(5): 550-554.
Citation: LI Xue-gang, SONG Jin-ming, YUAN Hua-mao, LI Ning. Determination of Ammonia-Nitrogen in Marine Sediments by Hypo-bromate Oxidation with Hydrochloric Acid Extraction[J]. Rock and Mineral Analysis, 2011, 30(5): 550-554.
shu

Determination of Ammonia-Nitrogen in Marine Sediments by Hypo-bromate Oxidation with Hydrochloric Acid Extraction

  • 1.

    Key Laboratory of Marine Geology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China

  • 2.

    Key Laboratory of Marine Geology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China

  • 3.

    Key Laboratory of Marine Geology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China

  • 4.

    Key Laboratory of Marine Geology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China

More Information
  • Received Date: December 16, 2010
  • Revised Date: March 03, 2011
    Abstract
  • Ammonia-N is one of the important compositions of marine sediment and the most active component at the sediment-water interface. The routine method uses NaCl, MgCl or KCl and other neutral solvents as extractants. However, only part of ammonia-N in sediments can be determined by this method. A new method to determine ammonia-N in sediment is presented in this paper. Ammonia-N in sediment was extracted by the 0.1 mol/L HCl, then determined by hypo-bromate oxidation. Based on a large number of experiments, the optimal measurement conditions were selected, which included hypo-bromic acid concentration, NaOH concentration in hypo-bromic acid solution, acidity for chromogenic reaction and dosage for sulfanilamide. Almost all of the ammonia-N in marine sediments can be extracted by this new method with better precision and accuracy than alternative methods.
    • FullText(HTML)
    • References (25)
  • 宋金明.中国近海沉积物-海水界面化学[M].北京:海洋出版社,1997: 1-222.
    宋金明.中国近海生物地球化学[M].济南:山东科技出版社,2004: 1-222.
    Li X G, Song J M, Yuan H M, Dai J C, Li N. Biogeochemical characteristics of nitrogen and phosphorus in Jiaozhou Bay sediments[J]. Chinese Journal of Oceanology and Limnology, 2007, 25(2): 157-165.

    Li X G, Song J M, Yuan H M, Dai J C, Li N. Biogeochemical characteristics of nitrogen and phosphorus in Jiaozhou Bay sediments[J]. Chinese Journal of Oceanology and Limnology, 2007, 25(2): 157-165.
    宋金明,马红波,李学刚,袁华茂,李宁.渤海南部海域沉积物中吸附态无机氮的地球化学特征[J].海洋与湖沼,2004,35(4): 315-322.
    宋金明, 李学刚, 邵君波, 贺志鹏, 张乃星.南黄海沉积物中氮、磷的生物地球化学行为[J].海洋与湖沼, 2006, 37(4): 370-376.
    Laursen A E, Seitzinger S P. The role of denitrification in nitrogen removal and carbon mineralization in Mid-Atlantic Bight sediments[J]. Continental Shelf Research, 2002, 22: 1397-1416.

    Laursen A E, Seitzinger S P. The role of denitrification in nitrogen removal and carbon mineralization in Mid-Atlantic Bight sediments[J]. Continental Shelf Research, 2002, 22: 1397-1416.
    Friedrich J, Dinkel F C, Friedl G. Benthic nutrient cycling and diagenetic pathways in the North-Western Black Sea[J]. Estuarine, Coastal and Shelf Science, 2002, 54: 369-383.

    Friedrich J, Dinkel F C, Friedl G. Benthic nutrient cycling and diagenetic pathways in the North-Western Black Sea[J]. Estuarine, Coastal and Shelf Science, 2002, 54: 369-383.
    Brunnegard J, Grandel S, Stahl H. Nitrogen cycling in deep-sea sediments of the Porcupine Abyssal Plain, NE Atlantic[J].Progress in Oceanography, 2004, 63: 159-181.

    Brunnegard J, Grandel S, Stahl H. Nitrogen cycling in deep-sea sediments of the Porcupine Abyssal Plain, NE Atlantic[J].Progress in Oceanography, 2004, 63: 159-181.
    孙云明,宋金明.海洋沉积物-海水界面附近氮、磷、硅的生物地球化学[J].地质论评,2001,47(5): 527-534.
    Bolaek J, Graca B. Ammonia Nitrogen at the water-sedi- ment interface in Puck Bay (Baltic Sea)[J]. Estuarine, Coastal and Shelf Science,1996,43(6):767-779.

    Bolaek J, Graca B. Ammonia Nitrogen at the water-sedi- ment interface in Puck Bay (Baltic Sea)[J]. Estuarine, Coastal and Shelf Science,1996,43(6):767-779.
    Konovalov S K, Ivanov L I, Samodurov A S. Fluxes and budget of sulphide and ammonia in the Black Sea anoxic layer[J]. Journal of Marine Systems, 2001, 31(1-3): 203-216.

    Konovalov S K, Ivanov L I, Samodurov A S. Fluxes and budget of sulphide and ammonia in the Black Sea anoxic layer[J]. Journal of Marine Systems, 2001, 31(1-3): 203-216.
    Kemp W M, Boynton W R. Benthic-pelagic interactions: Nutrients and oxygen dynamics[M]//Oxygen dynamics in the Cheseapeake Bay: A synthesis of recent research. Smith D E, Leffler M, Mackiernan G, Eds. College Park, 1992: 149-222.

    Kemp W M, Boynton W R. Benthic-pelagic interactions: Nutrients and oxygen dynamics[M]//Oxygen dynamics in the Cheseapeake Bay: A synthesis of recent research. Smith D E, Leffler M, Mackiernan G, Eds. College Park, 1992: 149-222.
    Denis L, Grenz C, Alliot, Rodier M. Temporal variability in dissolved inorganic nitrogen fluxes at the sediment-water interface and related annual budget on a continental shelf (NW Mediterranean)[J]. Oceanologica Acta, 2001, 24: 85-97.

    Denis L, Grenz C, Alliot, Rodier M. Temporal variability in dissolved inorganic nitrogen fluxes at the sediment-water interface and related annual budget on a continental shelf (NW Mediterranean)[J]. Oceanologica Acta, 2001, 24: 85-97.
    马红波,宋金明,吕晓霞,袁华茂.渤海沉积物中氮的形态及其在循环中的作用[J].地球化学,2003, 32(1): 48-54.
    Burgess R M, Pelletier M C, Ho K T, Serbst J R, Ryba S A, Kuhn A, Perron M M, Raczelowski P, Cantwell M G. Removal of ammonia toxicity in marine sediment TIEs: A comparison of Ulva lactuca, zeolite and aeration methods [J].Marine Pollution Bulletin, 2003, 46(5): 607-618.

    Burgess R M, Pelletier M C, Ho K T, Serbst J R, Ryba S A, Kuhn A, Perron M M, Raczelowski P, Cantwell M G. Removal of ammonia toxicity in marine sediment TIEs: A comparison of Ulva lactuca, zeolite and aeration methods [J].Marine Pollution Bulletin, 2003, 46(5): 607-618.
    Phillips B M, Anderson B S, Hunt J W. Measurement and distribution of interstitial and overlying water ammonia and hydrogen sulfide in sediment toxicity tests[J]. Marine Environmental Research, 1997, 44(2): 117-126.

    Phillips B M, Anderson B S, Hunt J W. Measurement and distribution of interstitial and overlying water ammonia and hydrogen sulfide in sediment toxicity tests[J]. Marine Environmental Research, 1997, 44(2): 117-126.
    Losso C, Novelli A A, Picone M, Marchetto D, Pantani C, Ghetti P F, Ghirardini A V. Potential role of sulfide and ammonia as confounding factors in elutriate toxicity bioassays with early life stages of sea urchins and bivalves[J].Ecotoxicology and Environmental Safety,2007,66(2):252-257.

    Losso C, Novelli A A, Picone M, Marchetto D, Pantani C, Ghetti P F, Ghirardini A V. Potential role of sulfide and ammonia as confounding factors in elutriate toxicity bioassays with early life stages of sea urchins and bivalves[J].Ecotoxicology and Environmental Safety,2007,66(2):252-257.
    Miranda-Filho K C, Pinho G L L, Wasielesky W, Bianchini A. Long-term ammonia toxicity to the pink-shrimp Farfantepenaeus paulensis[J].Comparative Biochemistry and Physiology Part C: Toxicology & Pharma-cology,2009,150(3):377-382.

    Miranda-Filho K C, Pinho G L L, Wasielesky W, Bianchini A. Long-term ammonia toxicity to the pink-shrimp Farfantepenaeus paulensis[J].Comparative Biochemistry and Physiology Part C: Toxicology & Pharma-cology,2009,150(3):377-382.
    王文琪,姜令绪,杨宁,李建,王仁杰.氨氮对菲律宾蛤仔免疫力的影响[J].海洋科学,2007, 31(1): 23-27.
    Kramer H A, Moed J R, Haan H. Nitrogen analyses in eutrophic, alkaline and peaty waters: A comparison of different methods to analyse ammonia-nitrogen[J].Water Research, 1990, 24(2): 221-224.

    Kramer H A, Moed J R, Haan H. Nitrogen analyses in eutrophic, alkaline and peaty waters: A comparison of different methods to analyse ammonia-nitrogen[J].Water Research, 1990, 24(2): 221-224.
    徐青,吴怡,廖梦霞,邓天龙.水环境中氮磷形态分析方法研究进展[J].岩矿测试, 2008, 27(2): 137-140.
    Batley G E, Simpson S L. Development of guidelines for ammonia in estuarine and marine water systems[J]. Marine Pollution Bulletin, 2009, 58(10): 1472-1476.

    Batley G E, Simpson S L. Development of guidelines for ammonia in estuarine and marine water systems[J]. Marine Pollution Bulletin, 2009, 58(10): 1472-1476.
    Song J M. Biogeochemical processes of biogenic elements in the China marginal seas[M]. Hangzhou: Springer-Verlag GmbH & Zhejiang University Press, 2009:1-662.

    Song J M. Biogeochemical processes of biogenic elements in the China marginal seas[M]. Hangzhou: Springer-Verlag GmbH & Zhejiang University Press, 2009:1-662.
    骆少勇,刘星,亓春英.滇池现代沉积物氨氮及磁化率研究[J].昆明理工大学学报:理工版,2005,30(5):1-5.
    李学刚,宋金明,牛丽凤,袁华茂,李宁,戴纪翠.近海沉积物中氮磷的同时测定及其在胶州湾沉积物中的应用[J].岩矿测试,2007, 26(2): 87-92.
    • Related Articles

  • Related Articles

    [1]Bing WANG, Feng-lei GAO, Pei-hua YANG, Cheng-jun SUN, Bin HAN. Feasibility Study on the Application of Automatic Potentiometric Titrator in the Measurement of Organic Carbon in Marine Sediments[J]. Rock and Mineral Analysis, 2016, 35(4): 402-408. DOI: 10.15898/j.cnki.11-2131/td.2016.04.011
    [2]Yu-man CAI, Ming LI, Li-jun LU, Pei-xin ZHANG. Determination of Arsenic in Tungsten and Molybdenum Ores by Hydride Generation-Atomic Fluorescence Spectrometry with Hydrochloric Acid-Nitric Acid Water-bath Digestion[J]. Rock and Mineral Analysis, 2015, 34(3): 325-329. DOI: 10.15898/j.cnki.11-2131/td.2015.03.011
    [3]Na WANG, Xin-hua TENG, Yan-tao WU, Jiang-ping ZENG, Liang-ying WU, Feng CHEN. Determination of Low-content Iron Carbonate in Stream Sediments by Flame Atomic Absorption Spectrometry with Aluminum Chloride Extraction[J]. Rock and Mineral Analysis, 2015, 34(2): 229-233. DOI: 10.15898/j.cnki.11-2131/td.2015.02.013
    [4]YIMANHAZI Jia-li-sen, Hai-ou QIU, Ao WANG, Da-bo WANG, Shao-zhan TANG, Zhi-yong TANG. Method for the Determination of Trace Elements in the Carbonate Fraction of Marine Sediments[J]. Rock and Mineral Analysis, 2013, 32(4): 627-631.
    [5]Sheng-feng MA, Hong-li WEN, Huai-ying ZHAO, Hong-bin SUN, Ai-hua GONG. Determination of Chlorine in Marine Sediment by Inductively Coupled Plasma-Atomic Emission Spectrometry with Ammonia Extraction[J]. Rock and Mineral Analysis, 2013, 32(1): 40-43.
    [6]ZHANG Bao-ke, WEN Hong-li, WANG Lei, MA Sheng-feng, GONG Ai-hua. Quantification of Multi Elements in Geological Samples by Inductively Coupled Plasma-Mass Spectrometry with Pressurized Decomposition-Hydrochloric Acid Extraction[J]. Rock and Mineral Analysis, 2011, 30(6): 737-744.
    [7]CHENG Si-hai, CHEN Dao-hua, LEI Zhi-sheng. Determination of Sulfide in Marine Sediments by Elemental Analyzer[J]. Rock and Mineral Analysis, 2011, 30(1): 63-66.
    [8]Rapid Determination of Organic Carbon in Marine Sediment Samples by Potassium Dichromate Oxidation-Ferrous Sulphate Titrimetry[J]. Rock and Mineral Analysis, 2007, 26(3): 205-208.
    [9]Techniques for Marine Sediment Pore-water Sampling[J]. Rock and Mineral Analysis, 2005, (2): 102-104.
    [10]Determination of Ferrous Oxide in Sea Sediments[J]. Rock and Mineral Analysis, 1999, (3): 198-200.
    • Supplements (0)

Catalog

    Get Citation
    PDF
    XML
    Article views (1604) PDF downloads (1193) Cited by()
    Turn off MathJax
    Article Contents
    ABSTRACT
    References
    Related Articles

    Competent Authorities：China Association for Science and Technology

    Sponsored by：Geological Society of China; National Research Center for Geoanalysis

    Address：No. 26 Baiwanzhuang Road, Xicheng District, Beijing 100037, China Email：ykcs_zazhi@163.com Tel：010-68999562

    京公网安备 11010202008159号 京ICP备2022024991号

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return