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SU Ming-yue, CHEN Guang-zhi, WANG Jing, YAO Chuan-gang. Determination of Arsenic and Mercury in Iron Ores by Water-bath Digestion-Hydride Generation-Atomic Fluorescence Spectrometry with a Sequential Injection System[J]. Rock and Mineral Analysis, 2011, 30(2): 210-213.
Citation: SU Ming-yue, CHEN Guang-zhi, WANG Jing, YAO Chuan-gang. Determination of Arsenic and Mercury in Iron Ores by Water-bath Digestion-Hydride Generation-Atomic Fluorescence Spectrometry with a Sequential Injection System[J]. Rock and Mineral Analysis, 2011, 30(2): 210-213.

Determination of Arsenic and Mercury in Iron Ores by Water-bath Digestion-Hydride Generation-Atomic Fluorescence Spectrometry with a Sequential Injection System

  • A convenient method was established to determine arsenic and mercury contents in iron ores. The iron ores were dissolved in HNO3-HCl solution by water-bath digestion at low temperature, and the determinations of arsenic and mercury contents were performed by hydride generation-atomic fluorescence spectrometry with a sequential injection system. The choice of digestion reagents is discussed in this paper. Some important interference factors were studied to obtain the optimum measurement conditions, e.g the concentration of KBH4 solution, the flow rate of carrier gas, the flow rate of coolant gas, acid and acid-base proportion. The linear range was from 0 to 100 g/L for arsenic, and from 0 to 10 g/L for mercury. The detection limit of arsenic and mercury is 0.06 g/L and 0.05 g/L respectively. The method has been applied to determine arsenic and mercury contents in iron ores. Arsenic content is shown to have a RSD less than 3.56% and recovery of 90.0%-110.0%, and mercury content is shown to have a RSD less than 2.87% and recovery of 90.0%-105.5%. The results of actual samples with this method were in good agreement with those obtained by the airproof-microwave digestion method.
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