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Dan QU, Shi-zhong JIANG, Zhen-wu TANG, Jie HE, Jia-li CHENG. Distribution and Diffusion of Organochlorine Pesticides in Soils from an Abandoned Manufacturing Site[J]. Rock and Mineral Analysis, 2013, 32(4): 649-658.
Citation: Dan QU, Shi-zhong JIANG, Zhen-wu TANG, Jie HE, Jia-li CHENG. Distribution and Diffusion of Organochlorine Pesticides in Soils from an Abandoned Manufacturing Site[J]. Rock and Mineral Analysis, 2013, 32(4): 649-658.

Distribution and Diffusion of Organochlorine Pesticides in Soils from an Abandoned Manufacturing Site

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  • Received Date: November 24, 2012
  • Accepted Date: April 01, 2013
  • Published Date: July 31, 2013
  • In past decades, large amounts of organochlorine pesticides (OCPs) were produced and used in China. These abandoned OCPs manufacturer sites have become high-risk areas. Previous studies have investigated the contamination status of OCPs in these sites. However, most of the available data focused only on the inside of the factory and few studies consider the pollutions and risks of OCPs in the surrounding area. Levels and distributions of hexachlorocylohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs) and DDT metabolites were investigated in surface soils from an abandoned manufacturing site, in Chongqing, southwest China, in order to better understand the contamination status and environmental impact on the surrounding area. In this study, the potential human health risks were also assessed from within the factory and from the surrounding area. Concentrations of ΣHCHs ranged from 3.89 to 13385.78 ng/g in surface soils from inside the factory, which were generally lower than those reported in other contaminated sites. Levels of ΣDDTs ranged from 22.74 ng/g to 11186.10 ng/g in surface soils, which were consistent with previous observations in contaminated sites located in Zhangjiakou and Yangzhou city, but lower than those in Xingtai, Taiyuan and Qingdao city. The results of health risk assessment showed that the carcinogenic risk of OCP contaminants exceeded the acceptable risk in soils from inside the factory, which contributed to the heavily-polluted area. Within 400 meters from the manufacturing facility, the levels of OCPs in soils were also high although they were lower than those inside the factory. To children, the carcinogenic risk of HCHs and DDTs in surface soils is still higher than the standard recommended by some research institutions. With the distance increasing to the site, levels of HCHs and DDTs decreased with the trend of the power function, which indicated that the pollution of OCPs only occurred in a certain region outside the factory. Therefore, the OCP pollutions and risks should be considered from not only inside contaminated sites but also certain regions outside sites.
  • 朱晓华,杨永亮,路国慧,吴学丽,何俊,罗松光.广州市珠海区有机氯农药污染状况及其土-气交换[J].岩矿测试, 2010, 29(2): 91-96. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201002004.htm
    何俊,杨永亮,潘静,路国慧,吴学丽,朱晓华,武振艳.广州市公园表层土壤中有机氯农药的分布特征[J].岩矿测试, 2009, 28(5): 401-406. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200905004.htm
    万奎元,杨永亮,薛源,武振艳,朱晓华,吴学丽,王晓春,罗松光.长白山表层土壤中有机氯农药和多氯联苯醚的海拔高度分布特征[J].岩矿测试,2011,30(2): 150-154. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201102007.htm
    Xu D D, Zhong W K, Deng L L, Chai Z F, Mao X Y. Regional distribution of organochlorinated pesticides in pine needles and its indication for socioeconomic development[J].Chemosphere, 2004, 54(6): 743-752. doi: 10.1016/j.chemosphere.2003.08.022
    荣素英,王茜,李君.唐山地区人体内有机氯农药蓄积水平调查[J].现代预防医学, 2012,39(10): 2420-2430. http://www.cnki.com.cn/Article/CJFDTOTAL-XDYF201210012.htm
    华小梅,单正军.我国农药的生产,使用状况及其污染环境因子分析[J].环境科学进展,1996,4(2): 33-45. http://www.cnki.com.cn/Article/CJFDTOTAL-HJJZ199602003.htm
    余刚,牛军峰,黄俊.持久性有机污染物--新的全球性环境问题[M].北京:科学出版社,2005.
    Wu Y, Zhang J, Zhou Q. Persistent organochlorine residues in sediments from Chinese river/estuary systems[J]. Environmental Pollution, 1999, 105(1): 143-150. doi: 10.1016/S0269-7491(98)00160-2
    Li J, Zhang G, Qi S H, Li X D, Peng X Z. Concen-trations, enantiomeric compositions, and sources of HCH, DDT and chlordane in soils from the Pearl River Delta, South China[J].Science of the Total Environment, 2006, 372(1): 215-224. doi: 10.1016/j.scitotenv.2006.09.023
    Guan Y F, Wang J Z, Ni H G, Zeng E Y. Organochlorine pesticides and polychlorinated biphenyls in riverine runoff of the Pearl River Delta, China: Assessment of mass loading, input source and environmental fate[J].Environmental Pollution,2009, 157(2): 618-624. doi: 10.1016/j.envpol.2008.08.011
    赵沁娜.城市土地置换过程中土壤污染研究进展评述[J].土壤, 2009, 41(3): 350-355. http://www.cnki.com.cn/Article/CJFDTOTAL-TURA200903005.htm
    李常亮,刘文彬,汪莉,巴特,高丽荣,张利飞,郑明辉.典型污染场地六六六残留特征分析[J].环境科学, 2008, 29(3): 809-813. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ200803045.htm
    马运,黄启飞,王琪,杨子良.六六六在典型污染场地中空间分布研究[J].农业环境科学学报,2009,28(8): 1562-1566. http://www.cnki.com.cn/Article/CJFDTOTAL-NHBH200908005.htm
    易爱华.DDT在污染场地中的迁移分布规律研究[D].杨凌:西北农林科技大学,2007.
    余世清,唐伟,卢滨.某农药厂废弃场地六六六和滴滴涕污染分布特征及风险评价[J].环境科学,2011, 32(9): 2645-2653. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201109026.htm
    姜林,王岩,王军玲,韩玉花.场地环境评价导则[R].北京:北京市环境保护局,北京市环境保护科学研究院, 2007.
    US EPA. Risk Assessment Guidance for Superfund (RAGS) Part A[R]. EPA/540/1289/002, 1989.
    刘敏,马运.典型污染场地中滴滴涕浓度空间变异性研究[J].环境污染与防治, 2010, 32(11): 12-17. doi: 10.3969/j.issn.1001-3865.2010.11.004
    Zhang L F, Dong L, Shi S X, Zhou L, Zhang T, Huang Y.Organochlorine pesticides contamination in surface soils from two pesticide factories in Southeast China[J].Chemosphere, 2009, 77(5): 628-633. doi: 10.1016/j.chemosphere.2009.08.055
    Wang X J, Piao X Y, Chen J, Hu J D, Xu F L, Tao S.Organochlorine pesticides in soil profiles from Tianjin, China[J].Chemosphere, 2006, 64(9): 1514-1520. doi: 10.1016/j.chemosphere.2005.12.052
    Chen L G, Ran Y, Xing B S, Mai B X, He J H, Wei X G, Fu J M, Sheng G Y.Contents and sources of polycyclic aromatic hydrocarbons and organochlorine pesticides in vegetable soils of Guangzhou, China[J]. Chemosphere, 2005, 60(7): 879-890. doi: 10.1016/j.chemosphere.2005.01.011
    陈瑶.湖南省农田土壤中HCH和DDT残留状况研究[J].中国环境监测, 2012,28(5): 44-47. http://www.cnki.com.cn/Article/CJFDTOTAL-IAOB201205011.htm
    张凌云,谢振伟,任朝辉.南充农村土壤中有机氯农药残留现状分析[J].四川环境, 2012,31(6): 9-12. http://www.cnki.com.cn/Article/CJFDTOTAL-SCHJ201206004.htm
    赵柄梓,张佳宝,朱安宁,夏敏,卢信,蒋其鳌.黄淮海地区典型农业土壤中六六六(HCH)和滴滴涕(DDT)的残留量研究Ⅱ.空间分布及垂直分布特征[J].土壤学报, 2005, 42(6): 916-922. doi: 10.11766/trxb200501250606
    Zhu Y F, Liu F, Xi Z Q, Cheng H X, Xu X B.Organochlorine pesticides (DDTs and HCHs) in soils from the outskirts of Beijing, China[J].Chemosphere, 2005, 60(6): 770-778. doi: 10.1016/j.chemosphere.2005.04.018
    史冰洁,李小娜,帅琴,庞绪贵,代杰瑞,胡圣虹.山东烟台地区苹果果园土壤中DDTs和HCHs残留分布特征与来源分析[J].岩矿测试,2012,31(2): 318-324. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201202025.htm
    Walker K, Vallero D A, Lewis R G. Factors influencing the distribution of linden and other hexachloro-cyclohexanes in the environment[J].Environmental Science and Technology, 1999, 33(24): 4373-4378. doi: 10.1021/es990647n
    阳文锐,王如松,李锋.废弃工业场地有机氯农药分布及生态风险评价[J].生态学报,2008, 28(11): 5454-5460. doi: 10.3321/j.issn:1000-0933.2008.11.029
    Yang R Q, LV A H, Shi J B, Jiang G B. The levels and distribution of organochlorine pesticides (OCPs) in sediments from the Haihe River, China[J].Chemosphere, 2005, 61(3): 347-354. doi: 10.1016/j.chemosphere.2005.02.091
    Harner T, Wideman J L, Jantunen L M M, Bidleman T F, Parkhurst W J.Residues of organochlorine pesticides in Alabama soils[J].Pollution, 1999, 106(3): 323-332. doi: 10.1016/S0269-7491(99)00110-4
    马子龙,毛潇萱,丁中原,高宏,黄韬,田慧,郭强.新疆哈密地区有机氯农药大气、土壤残留特征、气-土交换及潜在生态风险[J].环境科学, 2013,34(3): 1120-1128. http://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201303046.htm
    Lichetenstein E P. Absorption of some chlorinated hydrocarbon insecticides from soils into various crops[J].Journal of Agriculture Food and Chemistry, 1958, 7(6): 430-433.
    Zohair A, Salim A B, Soyibo A A, Beck A J.Residues of polycyclic aromatic hydrocarbons (PAHs), polychlo-rinated biphenyls (PCBs) and organochlorine pesticides in organically-farmed vegetables[J].Chemosphere, 2006, 63(4): 541-553. doi: 10.1016/j.chemosphere.2005.09.012
    Chen S H, Xu F L, Dawson R, Jiao X C, Tao S.Adsorption and absorption of dichlorodiphenyl-trichloroethane (DDT) and metabolites (DDD and DDE) by rice roots[J].Environmental Pollution, 2007, 147(1): 256-261. doi: 10.1016/j.envpol.2006.08.034
    Rafat A, Nida M S, Hussein E. Occurrence of organochlorine pesticide residues in eggs, chicken and meat in Jordan[J].Chemosphere, 2010, 78(6): 667-671. doi: 10.1016/j.chemosphere.2009.12.012
    Leyla K, Ihsan A, Abdurrahman A. Some organochlorine pesticide residues in fish species in Konya, Turkey[J].Chemosphere, 2009, 74(7): 885-889. doi: 10.1016/j.chemosphere.2008.11.020
    Kampire E, Kiremier B T, Nyanzi S A, Kishimba M. Organochlorine pesticide in fresh and pasteurized cow's milk from Kampala markets[J].Chemosphere, 2011, 84(7): 923-927. doi: 10.1016/j.chemosphere.2011.06.011
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