Citation: | WANG Yanyan, CAO Wengeng, PAN Deng, WANG Shuai, REN Yu, LI Zeyan. Distribution and Origin of High Arsenic and Fluoride in Groundwater of the North Henan Plain[J]. Rock and Mineral Analysis, 2022, 41(6): 1095-1109. DOI: 10.15898/j.cnki.11-2131/td.202110090141 |
The North Henan Plain is located in the middle and lower reaches of the Yellow River, and both high arsenic and fluoride groundwater exist. However, the coexistence mechanism of arsenic and fluoride in this sporadic distribution area is unclear.
To investigate the spatial distribution characteristics and formation mechanism of arsenic and fluoride in shallow groundwater in the North Henan Plain.
332 groups of shallow groundwater samples were collected and analyzed in the North Henan Plain. Atomic fluorescence spectrometry was used to determine arsenic content, and ion chromatography and inductively coupled plasma emission spectroscopy were used to determine the content of fluoride and other cation-anions. Based on the spatial distribution of arsenic and fluoride, combined with hydrochemical diagrams and factor analysis, three main factors affecting the evolution of groundwater in this area were extracted, and the formation mechanism of high arsenic and high fluoride groundwater in this area was discussed.
The concentrations of arsenic and fluoride in groundwater were 0.0001-0.1900mg/L and 0.13-4.94mg/L, respectively. The high-arsenic groundwater was mainly distributed in the vertical depth of 15-80m in the front alluvial-diluvial depression of Taihang Mountain and the Yellow River flood fan. The high-fluoride groundwater was mainly distributed in the vertical depth of 7-100m in the modern channel influence zone of the Yellow River. Evaporation and concentration, mineral dissolution/desorption, and redox environment were the main factors controlling the evolution of groundwater in this area. Fluoride had loads of 0.214 and 0.743 in factor F1 (evaporation and concentration) and F2 (mineral dissolution/desorption), respectively. High concentration of F appeared in groundwater with low concentration of Ca2+, and the concentration of F was positively correlated with
The results clarify the coexistence mechanism of arsenic and fluoride in the North Henan Plain, and enrich the theoretical system of co-contamination of groundwater with high arsenic and fluoride.
(1) The concentration of arsenic in the North Henan Plain was 0.0001-0.1900mg/L, and the reduction and dissolution of arsenic-bearing minerals promoted the enrichment of arsenic.
(2) The fluoride concentration in the North Henan Plain was 0.13-4.94mg/L, and evaporation concentration was helpful to the dissolution of fluorine-containing minerals.
(3) The desorption of arsenate/arsenite/fluoride on the mineral surfaces caused by pH increase was favorable for the coexistence of arsenic and fluoride in this region.
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