Review on Characteristics of Selenium in Soil and Related Analytical Techniques

YI Qin; CHENG Huang; SHANG Wen-yu

doi:10.15898/j.cnki.11-2131/td.202006230095

Rock and Mineral Analysis > 2021 > 40(4): 461-475. > DOI: 10.15898/j.cnki.11-2131/td.202006230095

YI Qin, CHENG Huang, SHANG Wen-yu. Review on Characteristics of Selenium in Soil and Related Analytical Techniques[J]. Rock and Mineral Analysis, 2021, 40(4): 461-475. DOI: 10.15898/j.cnki.11-2131/td.202006230095

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Review on Characteristics of Selenium in Soil and Related Analytical Techniques

1.
National Research Center for Geoanlysis, Beijing 100037, China
2.
Beijing Aerospace WKS Environmental Technology Co., LTD, Beijing 100071, China

More Information

Received Date: June 22, 2020
Revised Date: January 03, 2021
Accepted Date: January 25, 2021
Published Date: July 27, 2021

Abstract

HIGHLIGHTS
(1) The selenium content in most soils in the world is ultra-low and varies with the environment.

(2) Methods with high sensitivity and a low detection limit are a basic requirement.

(3) Reference materials with gradient content and certified speciation content of selenium are urgently needed.

ABSTRACT

BACKGROUNDSelenium is an essential micronutrient for humans. The spatial heterogeneity of selenium in soil is the main cause of various diseases and environmental problems. Selenium in soil is unevenly distributed across the globe, with most soils being low in selenium. Globally, the average selenium content in soil is 0.4mg/kg, while it is 346-2018mg/kg in typical high-selenium areas. Thus, accurate analysis of selenium in soil is of great significance in research on seleniferous soil. The reasonable use of reference materials can aid in the effective monitoring of the quality of analysis.
OBJECTIVESTo summarize the status of research on selenium in soil, and the development of the corresponding analytical methods and reference materials.
METHODSThis article describes the distribution characteristics, speciation, and migration and transformation characteristics of selenium in soil. Furthermore, the methods for extracting selenium speciation in soil, the progress of research on selenium content analysis technology, and the status of the development of soil selenium reference materials in recent years are summarized.
RESULTSBecause of limited advancements in the development of analytical techniques, research on the mechanism of migration and transformation is still incomplete. The emergence of sequential extraction techniques provides a new way to study the distribution, migration, and transformation of soil selenium speciation. However, this method is still under development and has many shortcomings, such as inadequate selectivity and inevitable speciation transformation. Atomic fluorescence spectroscopy is the mainstream approach for the analysis of selenium content in soil, especially in China. Mass spectrometry, with high precision and a low detection limit, and synchrotron radiation X-ray technology, with in-situ speciation analysis capabilities, offer significant advantages in the analysis of trace and ultra-trace elements and speciation analysis. There is a significant gap in the research on reference materials with gradient content and certified speciation content.
CONCLUSIONSMethods with a low detection limit, high sensitivity, and matrix interference resistance are urgently needed. The combined application of sequential extraction, mass spectrometry, and X-ray fluorescence can promote research on selenium in soil. Moreover, related certified reference materials with gradient content and certified speciation content are in short supply.
- soil,
- selenium,
- speciation,
- quantitative analysis,
- reference material

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References (85)

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Review on Characteristics of Selenium in Soil and Related Analytical Techniques

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