Effect and Mechanism of Biomass Carbon and Steel Slag as Ameliorants on Soil Selenium Availability in a Typical Se-rich Area of Fengcheng City, Jiangxi Province

KUANG Qin; WU Shan; HUANG Ting; WU Dai-she; XIANG Jing

doi:10.15898/j.cnki.11-2131/td.201901190014

Rock and Mineral Analysis > 2019 > 38(6): 705-714. > DOI: 10.15898/j.cnki.11-2131/td.201901190014

KUANG Qin, WU Shan, HUANG Ting, WU Dai-she, XIANG Jing. Effect and Mechanism of Biomass Carbon and Steel Slag as Ameliorants on Soil Selenium Availability in a Typical Se-rich Area of Fengcheng City, Jiangxi Province[J]. Rock and Mineral Analysis, 2019, 38(6): 705-714. DOI: 10.15898/j.cnki.11-2131/td.201901190014

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Effect and Mechanism of Biomass Carbon and Steel Slag as Ameliorants on Soil Selenium Availability in a Typical Se-rich Area of Fengcheng City, Jiangxi Province

1.
Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education; School of Resource, Environment and Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
Wuhan Zongdy Green Environmental Protection Technology Co., LTD, Wuhan 430074, China

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Received Date: January 18, 2019
Revised Date: April 07, 2019
Accepted Date: July 15, 2019
Published Date: October 31, 2019

Abstract

HIGHLIGHTS
(1) The effect of physical and chemical properties of soil (pH, organic and cation exchange capacity) on soil selenium availability was revealed

(2) The effects of two modifiers on the selenium availability in selenium-rich red soils were compared.

(3) Steel slag can effectively improve the availability of selenium in soils in the study area, while biochar was not suitable as a adjusting material for selenium availability in soils in the region.

ABSTRACT

BACKGROUNDThe total selenium content in the selenium-rich red soils in Fengcheng City of Jiangxi Province was relatively high, but the available selenium content directly absorbed and utilized by plants was low. The bioavailability of selenium in soils is a key factor affecting selenium in crops.
OBJECTIVESTo find safe and effective ameliorants for improving the availability of selenium in selenium-rich soils.
METHODSBiomass carbon and steel slag were used as modifiers, and 8 different experiments were set up. Through indoor soil test and pot experiment, the content of available selenium in the selenium-rich red soils in Fengcheng was determined by atomic fluorescence spectrometry, and the regulation effect of two kinds of ameliorants on available selenium under different treatment levels was investigated.
RESULTSThe results of the soil tests showed that different amounts of biomass carbon and steel slag can increase the soil pH in the study area by 0.1-3.79 units. The results of elemental speciation analysis indicated that the ameliorant mainly controlled the soil available selenium by affecting the organically bound selenium. The soil organic matter content increased significantly after the application of biochar in the soil, but the organic matter showed a fixed effect on selenium. The available selenium content decreased by 8.4%-15.1%, resulted in the overall lower available selenium content in soils. The significant effect of steel slag on soil pH was beneficial to the activation of selenium in soils, and the soil available selenium content can be increased by 1.4 to 2.0 times. The results of the pot experiment showed that the selenium content of Chinese cabbage increased by more than 30% after treatment with steel slag, while the selenium content of Chinese cabbage decreased by 7.14%-42.8% after treatment with biochar.
CONCLUSIONSThis study shows that biochar is not suitable for regulating the availability of selenium in the soil of the study area. Steel slag can be used as a control material for soil selenium availability in the study area, which not only realizes solid waste recycling, but also improves the availability of selenium in soil.
- selenium-rich soil,
- available selenium,
- atomic fluorescence spectrometry,
- soil ameliorant,
- biomass carbon,
- steel slag

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References (32)

References

李杰, 刘久臣, 汤奇峰, 等.川西高原地区水体中硒含量及分布特征研究[J].岩矿测试, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

Li J, Liu J C, Tang Q F, et al.Study of the content and distribution of selenium in water samples from the Western Sichuan Plateau and the incidence of Kaschin Beck disease[J].Rock and Mineral Analysis, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

王锐, 余涛, 杨忠芳, 等.富硒土壤硒生物有效性及影响因素研究[J].长江流域资源与环境, 2018, 27(7):1647-1654. http://d.old.wanfangdata.com.cn/Periodical/cjlyzyyhj201807024

Wang R, Yu T, Yang Z F, et al.Bioavailability of soil selenium and its influencing factors in selenium-enriched soil[J].Resources and Environment in the Yangtze Basin, 2018, 27(7):1647-1654. http://d.old.wanfangdata.com.cn/Periodical/cjlyzyyhj201807024

曹容浩.福建省龙海市表层土壤硒含量及影响因素研究[J].岩矿测试, 2017, 36(3):282-288. doi: 10.15898/j.cnki.11-2131/td.201606130084

Cao R H.Study on selenium content of surface soils in Longhai, Fujian and its influencing factors[J].Rock and Mineral Analysis, 2017, 36(3):282-288. doi: 10.15898/j.cnki.11-2131/td.201606130084

杨琼, 侯青叶, 顾秋蓓, 等.广西武鸣县典型土壤剖面Se的地球化学特征及其影响因素研究[J].现代地质, 2016, 30(2):455-462. doi: 10.3969/j.issn.1000-8527.2016.02.022

Yang Q, Hou Q Y, Gu Q B, et al.Study of geochemical characteristics and influencing factors of soil selenium[J].Geoscience, 2016, 30(2):455-462. doi: 10.3969/j.issn.1000-8527.2016.02.022

Rayman M P, Sargent M, Infante H G.Food-chain selenium and human health:Emphasis on intake[J].The British Journal of Nutrition, 2008, 100(2).DOI: 10.1017/S0007114508922522.

郭文慧, 刘庆, 史衍玺, 等.施硒对紫甘薯硒素累积及产量和品质的影响研究[J].中国粮油学报, 2016, 31(9):31-37. doi: 10.3969/j.issn.1003-0174.2016.09.006

Guo W H, Liu Q, Shi Y X, et al.Effects of applying selenium on the accumulation of selenium, yield, and quality of purple sweetpotato[J].Journal of the Chinese Cereals and Oils Association, 2016, 31(9):31-37. doi: 10.3969/j.issn.1003-0174.2016.09.006

穆婷婷, 杜慧玲, 景小兰, 等.外源硒对谷子产量因子及硒含量的影响[J].作物杂志, 2017, 14(1):73-78. http://d.old.wanfangdata.com.cn/Periodical/zwzz201701014

Mu T T, Du H L, Jing X L, et al.Effects of exogenous selenium on yield components and selenium content in grain of foxtail millet[J].Crops, 2017, 14(1):73-78. http://d.old.wanfangdata.com.cn/Periodical/zwzz201701014

谢邦廷, 贺灵, 江官军, 等.中国南方典型富硒区土壤硒有效性调控与评价[J].岩矿测试, 2017, 36(3):273-281. doi: 10.15898/j.cnki.11-2131/td.201610100152

Xie B T, He L, Jiang G J, et al.Regulation and evaluation of selenium availability in Se-rich soils in Southern China[J].Rock and Mineral Analysis, 2017, 36(3):273-281. doi: 10.15898/j.cnki.11-2131/td.201610100152

谢珊妮, 宗良纲, 张琪惠, 等.3种改良剂对强酸性高硒茶园土壤硒有效性调控效果与机理[J].茶叶科学, 2017, 37(3):299-307. doi: 10.3969/j.issn.1000-369X.2017.03.010

Xie S N, Zong L G, Zhang Q H, et al.Effects of three amendments on selenium availability of highly acidic and Se-rich soil in tea garden and their relative mechanisms[J].Journal of Tea Science, 2017, 37(3):299-307. doi: 10.3969/j.issn.1000-369X.2017.03.010

廖桥, 彭博, 李碧雄.炉渣建材资源化利用现状[J].重庆建筑, 2018, 17(3):53-57. doi: 10.3969/j.issn.1671-9107.2018.03.53

Liao Q, Peng B, Li B X.A review of resource utilization of slag building material[J].Chongqing Architecture, 2018, 17(3):53-57. doi: 10.3969/j.issn.1671-9107.2018.03.53

杨慧, 刘立晶, 刘忠军, 等.我国农田化肥施用现状分析及建议[J].农机化研究, 2014, 36(9):260-264. doi: 10.3969/j.issn.1003-188X.2014.09.059

Yang H, Liu L J, Liu Z J, et al.Analysis and suggestions of agricultural fertilizer application in China[J].Agricultural Mechanization Research, 2014, 36(9):260-264. doi: 10.3969/j.issn.1003-188X.2014.09.059

王怀臣, 冯雷雨, 陈银广.废物资源化制备生物质炭及其应用的研究进展[J].化工进展, 2012, 31(4):907-914. http://d.old.wanfangdata.com.cn/Periodical/hgjz201204041

Wang H C, Feng L Y, Chen Y G.Advances in biochar production from wastes and its applications[J].Chemical Industry and Engineering Progress, 2012, 31(4):907-914. http://d.old.wanfangdata.com.cn/Periodical/hgjz201204041

王晨晔, 陈艳, 郭占成, 等.以钢渣为原料合成Ca-Mg-Al-Fe层状双金属氢氧化物及其对甲基橙的吸附[J].过程工程学报, 2018, 18(3):570-574. http://www.cnki.com.cn/Article/CJFDTotal-HGYJ201803021.htm

Wang C Y, Chen Y, Guo Z C, et al.Preparation of Ca-Mg-Al-Fe layered double hydroxides using steel-making slag as raw material and its adsorption to methyl orange[J].The Chinese Journal of Process Engineering, 2018, 18(3):570-574. http://www.cnki.com.cn/Article/CJFDTotal-HGYJ201803021.htm

邓腾灏博, 谷海红, 仇荣亮.钢渣施用对多金属复合污染土壤的改良效果及水稻吸收重金属的影响[J].农业环境科学学报, 2011, 30(3):455-460. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh201103008

Deng Teng H B, Gu H H, Qiu R L.Ameliorative effects of steel slag application on multi-metal contaminated soil and heavy metal uptake of rice[J].Journal of Agro-Environment Science, 2011, 30(3):455-460. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh201103008

韩笑, 周越, 吴文良, 等.富硒土壤硒含量及其与土壤理化性状的关系——以江西丰城为例[J].农业环境科学学报, 2018, 37(6):1177-1183. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=nyhjbh201806018

Han X, Zhou Y, Wu W L, et al.Selenium content of farmland soils and their relationship with main soil properties in Fengcheng, Jiangxi[J].Journal of Agro-Environment Science, 2018, 37(6):1177-1183. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=nyhjbh201806018

李家熙, 张光弟.人体硒缺乏与过剩的地球化学环境特征及其预测[M].北京:地质出版社, 2000.

Li J X, Zhang G D.Characteristics and Prediction of Human Selenium Deficiency and Excess Geochemical Environment[M].Beijing:Geological Publishing House, 2000.

诸旭东, 宗良纲, 马迅, 等.内源调控与外源补硒对红壤中硒有效性及水稻产量的影响[J].土壤通报, 2016, 47(2):398-404. http://d.old.wanfangdata.com.cn/Periodical/trtb201602022

Zhu X D, Zong L G, Ma X, et al.Effects of endogenous and exogenous regulation on effectiveness of selenium and rice yield in selenium enriched soil[J].Chinese Journal of Soil Science, 2016, 47(2):398-404. http://d.old.wanfangdata.com.cn/Periodical/trtb201602022

瞿建国, 徐伯兴, 龚书椿.连续浸提技术测定土壤和沉积物中硒的形态[J].环境化学, 1997, 16(3):277-283.

Qu J G, Xu B X, Gong S C.Sequential extraction techniques for determination of selenium speciation in soils and sediments[J].Environmental Chemistry, 1997, 16(3):277-283.

贺攀红, 杨珍, 荣耀, 等.氢化物发生-电感耦合等离子体发射光谱法测定铀矿地质样品中痕量硒[J].岩矿测试, 2016, 35(2):139-144. doi: 10.15898/j.cnki.11-2131/td.2016.02.005

He P H, Yang Z, Rong Y, et al.Determination of trace selenium in uranium-bearing geological samples by hydride generation-inductively coupled plasma-optimal emission spectrometry[J].Rock and Mineral Analysis, 2016, 35(2):139-144. doi: 10.15898/j.cnki.11-2131/td.2016.02.005

陈再明, 陈宝梁, 周丹丹.水稻秸秆生物碳的结构特征及其对有机污染物的吸附性能[J].环境科学学报, 2013, 33(1):9-19. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201301002

Chen Z M, Chen B L, Zhou D D.Composition and sorption properties of rice-straw derived biochars[J].Acta Scientiae Circumstantiae, 2013, 33(1):9-19. http://d.old.wanfangdata.com.cn/Periodical/hjkxxb201301002

赵世翔, 于小玲, 李忠徽, 等.不同温度制备的生物质炭对土壤有机碳及其组分的影响:对土壤活性有机碳的影响[J].环境科学, 2017, 38(1):333-342. http://d.old.wanfangdata.com.cn/Periodical/hjkx201701040

Zhao S X, Yu X L, Li Z H, et al.Effects of biochar pyrolyzed at varying temperatures on soil organic carbon and its components:Influence on the soil active organic carbon[J].Environmental Science, 2017, 38(1):333-342. http://d.old.wanfangdata.com.cn/Periodical/hjkx201701040

赵世翔, 于小玲, 李忠徽, 等.不同温度制备的生物质炭对土壤有机碳及其组分的影响:对土壤腐殖物质组成及性质的影响[J].环境科学, 2017, 38(2):769-782. http://d.old.wanfangdata.com.cn/Periodical/hjkx201701040

Zhao S X, Yu X L, Li Z H, et al.Effects of biochar pyrolyzed at varying temperatures on soil organic carbon and its components:Influence on the composition and properties of humic substances[J].Environmental Science, 2017, 38(2):769-782. http://d.old.wanfangdata.com.cn/Periodical/hjkx201701040

Wang D, Xue M Y, Wang Y K, et al.Effects of straw amendment on selenium aging in soils mechanism and influential factors[J].Science of the Total Environment, 2019, 657(20):871-881. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=9c8ab45a28fe8ac8e91135305107c72d

袁金华, 徐仁扣.生物质炭对酸性土壤改良作用的研究进展[J].土壤, 2012, 44(4):541-547. doi: 10.3969/j.issn.0253-9829.2012.04.003

Yuan J H, Xu R K.Research progress of amelioration effects of biochars on acid soils[J].Soil, 2012, 44(4):541-547. doi: 10.3969/j.issn.0253-9829.2012.04.003

韩学博.不同生物质炭对植烟土壤理化性状、重金属生物有效性及烤烟生长的影响[D].临安: 浙江农林大学, 2017. http://cdmd.cnki.com.cn/Article/CDMD-10341-1017273810.htm

Han X B.Effect of Different Biochars on Soil Physical and Chemical Properties, Heavy Metal Bioavailability and Tobacco Growth[D].Lin'an: Zhejiang Agriculture & Forestry University, 2017. http://cdmd.cnki.com.cn/Article/CDMD-10341-1017273810.htm

朱李俊, 刘国威, 王磊, 等.钢渣对稀土矿区酸性土壤的改良效果[J].安徽农业科学, 2016, 44(6):159-162. doi: 10.3969/j.issn.0517-6611.2016.06.054

Zhu L J, Liu G W, Wang L, et al.Improvement effect of steel slag on acid soil in rare earth mining area[J].Journal of Anhui Agricultural Sciences, 2016, 44(6):159-162. doi: 10.3969/j.issn.0517-6611.2016.06.054

Kamei-Ishikawa N, Tagami K, Uchida S.Sorption kinetics of selenium on humic acid[J].Journal of Radioanalytical and Nuclear Chemistry, 2007, 274(3):555-561. doi: 10.1007/s10967-006-6951-8

卢再亮, 李九玉, 徐仁扣.钢渣与生物质炭配合施用对红壤酸度的改良效果[J].土壤, 2013, 45(4):722-726. http://d.old.wanfangdata.com.cn/Periodical/tr201304025

Lu Z L, Li J Y, Xu R K.Amelioration effects of steel slag combined with biochar on red soil acidity[J].Soil, 2013, 45(4):722-726. http://d.old.wanfangdata.com.cn/Periodical/tr201304025

花莉, 金素素, 唐志刚.生物质炭输入对土壤CO₂释放影响的研究[J].安徽农业科学, 2012, 40(11):6501-6503. doi: 10.3969/j.issn.0517-6611.2012.11.061

Hua L, Jin S S, Tang Z G.Effect of bio-charcoal on release of carbon dioxide in soil[J].Journal of Anhui Agricultural Sciences, 2012, 40(11):6501-6503. doi: 10.3969/j.issn.0517-6611.2012.11.061

何振立, 杨肖娥, 祝军, 等.中国几种土壤中的有机态硒及其分布特征[J].环境科学学报, 1993, 13(3):281-287. http://www.cqvip.com/Main/Detail.aspx?id=1080278

He Z L, Yang X E, Zhu J, et al.Organic selenium and its distribution in soils[J].Journal of Environmental Science, 1993, 13(3):281-287. http://www.cqvip.com/Main/Detail.aspx?id=1080278

章海波, 骆永明, 吴龙华, 等.香港土壤研究Ⅱ.土壤硒的含量、分布及其影响因素[J].土壤学报, 2005, 42(3):404-410. doi: 10.3321/j.issn:0564-3929.2005.03.009

Zhang H B, Luo Y M, Wu L H, et al.Hong Kong soil researches Ⅱ.Distribution and content of selenium in soils[J].Acta Pedologica Sinica, 2005, 42(3):404-410. doi: 10.3321/j.issn:0564-3929.2005.03.009

王文艳, 张丽萍, 刘俏.黄土高原小流域土壤阳离子交换量分布特征及影响因子[J].水土保持学报, 2012, 26(5):123-127. http://d.old.wanfangdata.com.cn/Periodical/trqsystbcxb201205025

Wang W Y, Zhang L P, Liu Q.Distribution and affecting factors of soil cation exchange capacity in watershed of the Loess Plateau[J].Journal of Soil and Water Conservation, 2012, 26(5):123-127. http://d.old.wanfangdata.com.cn/Periodical/trqsystbcxb201205025

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Effect and Mechanism of Biomass Carbon and Steel Slag as Ameliorants on Soil Selenium Availability in a Typical Se-rich Area of Fengcheng City, Jiangxi Province

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