• DOAJ
  • Scopus
  • Core Journal of China
  • Chinese Science Citation Database (CSCD)
  • Chinese Scientific and Technical Paper and Citation Database (CSTPCD)
XIAO Gang. Determination of Organochlorines and Organophosphorus in Soil by Accelerated Solvent Extraction-Gas Chromatography[J]. Rock and Mineral Analysis, 2012, 31(6): 1033-1036.
Citation: XIAO Gang. Determination of Organochlorines and Organophosphorus in Soil by Accelerated Solvent Extraction-Gas Chromatography[J]. Rock and Mineral Analysis, 2012, 31(6): 1033-1036.

Determination of Organochlorines and Organophosphorus in Soil by Accelerated Solvent Extraction-Gas Chromatography

More Information
  • Received Date: July 13, 2012
  • Revised Date: August 29, 2012
  • Published Date: November 09, 2012
  • A large number of measurement work on organochlorine and organophosphorus pesticide residue in soil was carried out in China's environmental pollution survey evaluation and test project. The simultaneous measurements of a variety of organic pollutants were a new research hotspot. In this study, the pesticide residues of 9 kinds of organochlorine such as hexachlorobenzene and 13 kinds of organophosphorus such as dichlorvos were simultaneously measured by Gas Chromatography with n-hexane-acetone (volume ratio 1:1) for extracting agent, the accelerated solvent extraction and capillary column. The recoveries were from 79.1% to 107.7%, relative standard deviations were from 3.62% to 9.94% (n=7) and detection limits were from 0.02 to 0.45 μg/kg. This method simultaneously extracted the two kinds of pesticides and completely separated the various components, which extended the application field. Comparing with the traditional ultrasonic extraction and Soxhlet extraction method, extracting time of this method was reduced to 20 min and extraction solvent volume was down to 50 mL, which saved the analytical time and reduced the cost. Meanwhile, the precisions and recoveries met the requirements of the national environmental pollution survey and assessment.
  • Stanh J, Goebel H. Evaluation of automated splitless and manual on-column injection techniques using capillary gas chromatography for pesticide residue analysis [J]. Journal of Chromatography A, 1984, 314: 413-420.

    Stanh J, Goebel H. Evaluation of automated splitless and manual on-column injection techniques using capillary gas chromatography for pesticide residue analysis [J]. Journal of Chromatography A, 1984, 314: 413-420.
    陈卫明,邓天龙,张勤.土壤中有机氯农药残留的分析技术研究进展[J].岩矿测试,2009,28(4):151-156.
    吴宇峰,李利荣,时庭锐.土壤和沉积物中17种有机氯农药残留量的测定[J].环境科学与技术,2007,30(1): 37-38.
    何淼,饶竹.圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药[J].岩矿测试,2008,27(1): 12-16.
    王祎亚,饶竹.大口径毛细管柱气相色谱法测定水中15种有机磷农药[J].岩矿测试,2007,26(1): 17-20.
    杨旭,汤佳峰,巢文军.基质效应对有机磷农药测定的影响及其解决方法[J].分析测试学报,2009,28(12): 1368-1372.
    牟一萍.持久性有机污染物(POPs)全球性环境新课题[J].中国标准化,2003(1): 55-59.
    EPA 8081A, Organochlorine Pesticides by Gas Chroma-tography [S].

    EPA 8081A, Organochlorine Pesticides by Gas Chroma-tography [S].
    EPA 8141B, Gas Chromatographic Analysis of Organo-phosphate Compounds[S].

    EPA 8141B, Gas Chromatographic Analysis of Organo-phosphate Compounds[S].
    国家环境保护总局水和废水监测分析方法编委会.水和废水监测分析方法[M].4版.北京:中国环境科学出版社,2002.
    中国地质调查局.DD 2008-01,地下水污染地质调查评价规范[S].
  • Related Articles

    [1]PAN Meng, TONG Ling, TIAN Qin, SONG Shuling. Determination of 15 Organophosphate Ester Flame Retardants in Soils and Sediments by Gas Chromatography-Mass Spectrometry with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2023, 42(6): 1165-1176. DOI: 10.15898/j.ykcs.202305110065
    [2]ZHAO Jiang-hua, WANG Peng, LI Wei-liang, LI Zhong-yu. Determination of the Petroleum Substances in Samples of Reclaimed Land by Fluorescence Spectrophotometry with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2021, 40(3): 375-383. DOI: 10.15898/j.cnki.11-2131/td.202011200150
    [3]TONG Ling, TIAN Qin, YANG Zhi-peng, PAN Meng. Research on the Determination of 14 Synthetic Musks in Sediment Samples by Gas Chromatography-Tandem Mass Spectrometry with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2020, 39(4): 587-596. DOI: 10.15898/j.cnki.11-2131/td.201906240089
    [4]TONG Ling, YANG Jia-jia, YAN Ni, WU Shu-qi. Simultaneous Analysis of Organochlorinated Pesticides and Polychlorinated Biphenyls from Animal Tissue using Gas Chromatography-Mass Spectrometry Combined with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2014, 33(2): 262-269.
    [5]Jia-jia YANG, Ling TONG, Shu-Qi WU, Ni YAN. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Grains Using Gas Chromatography with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2013, 32(3): 487-494.
    [6]CHEN Wei-ming, LI Qing-xia, ZHANG Fang, HE Xiao-hui, ZHANG Qin. Determination of 7 Polychlorinated Biphenyls in Soil Samples by Accelerated Solvent Extraction-Gas Chromatography/ Gas Chromatography-Mass Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(1): 33-39.
    [7]RAO Zhu, HE Miao, CHEN Wei, LI Song, LIU Yan. Determination of Organophosphate Pesticides in Soil Samples by Accelerated Solvent Extraction-Gas Chromatography[J]. Rock and Mineral Analysis, 2010, 29(5): 503-507.
    [8]ZHANG Yan, ZHANG Jing-fa, CHEN Yan-mei, MENG Juan, HAN Cui-ying. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2010, 29(5): 491-496.
    [9]WANG Jin-yan, TANG Hua, CHEN Da-zhou, WU Xue, FENG Jie, WU Xue-li, LI Lei. Simultaneous Determination of Polycyclic Aromatic Hydrocarbons and Organochlorine Pesticides in River Sediments by Gas Chromatography-Mass Spectrometry[J]. Rock and Mineral Analysis, 2010, 29(3): 225-230.
    [10]Pre-treatment Methods for Analysis of Persistent Organic Pollutants in Soil Samples[J]. Rock and Mineral Analysis, 2008, 27(2): 81-86.

Catalog

    Article views (1347) PDF downloads (1506) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return