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ZHENG Song, KUANG Yun-suo, ZHAO Ping. Simplification Application of Two-error Regression Model in the Uncertainty Evaluation on Inductively Coupled Plasma-Mass Spectrometric Determination of Sr in Drinking Waters[J]. Rock and Mineral Analysis, 2012, 31(3): 484-488.
Citation: ZHENG Song, KUANG Yun-suo, ZHAO Ping. Simplification Application of Two-error Regression Model in the Uncertainty Evaluation on Inductively Coupled Plasma-Mass Spectrometric Determination of Sr in Drinking Waters[J]. Rock and Mineral Analysis, 2012, 31(3): 484-488.

Simplification Application of Two-error Regression Model in the Uncertainty Evaluation on Inductively Coupled Plasma-Mass Spectrometric Determination of Sr in Drinking Waters

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  • Received Date: October 07, 2011
  • Revised Date: April 17, 2012
  • This paper introduces the method of double-error regression in the course of standard curve fitting was introduced. The uncertainties of standard solutions and signal shift of the instrument were propagated into the final analytical results of Sr in drinking water by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) and by using a continuous propagation model. The fitting results obtained by one time and multi-time linear regression models did not reflect the true result and two different sources of uncertainty. The double-error regression model was applied to the standard work curve reported in this paper. The uncertainty calculation for the standard work curve was derived from the double-error regression equations, which built the relationship among detection limits, parameters for curve regression and associated uncertainties. The equation for total uncertainty was simplified by a continuous propagation model and calculation equations for the uncertainty components. The results indicate that the relative uncertainty of the measurement results is greater when the Sr concentration is lower. It also shows that the value of the detection limit increases and the sensitivity is reduced with the rougher processing for the preparation of a standard series. Both issues above prove that the test result matches the practical situation well.
  • ISO/TAG4/WG3. Guide to the Expression on Uncer-tainty in Measurement [S]. ISO-OIML-CIPM,1992.

    ISO/TAG4/WG3. Guide to the Expression on Uncer-tainty in Measurement [S]. ISO-OIML-CIPM,1992.
    中国实验室国家认可委员会.化学分析中不确定度的评估指南[M].北京: 中国计量出版社,2002: 1-3.
    代阿芳,鲁立强,潘河,王苏明,王亚平,许春雪,袁建.电感耦合等离子体质谱法测定地下水中锑的不确定度评定[J].岩矿测试,2010,29(4): 431-437.
    朱家平,王亚平,刘建坤,王苏明,许春雪.不确定度连续传递模型及其在化学测量中的应用[J].地质通报,2009,28(10): 1481-1485.
    刘建坤,朱家平,郑荣华.分光光度法测定地下水中亚硝酸根的不确定度评定[J].分析试验室,2009,28(Z1): 113-117.
    路远发,朱家平,汪群英.基于不确定度连续传递模型的标准曲线双误差拟合程序[J].岩矿测试,2011,30(2): 238-243.

    [ZK)]
    史彭,王占民.一元线性回归的不确定度评定方法[J].西安建筑科技大学学报:自然科学版,2000,32(1): 82-85.
    王晓男.土壤重金属含量测量不确定度研究[D].北京:中国农业科学院研究生院,2007: 60.
    何建练,赵平,吴靖,杨刚.ICP-OES法测定地质样品中钒的不确定度分析[J].贵州地质,2007,24(4): 325-328.
    李金英,姚继军.分析评定测量不确定度的表达与实践[J].岩矿测试,2001,20(2): 152-156.
    王东平,徐立明,姜莉,贾林.电感耦合等离子体发射光谱仪的测量不确定度[J].检验检疫科学,2000,10(5): 1-4.

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