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JIAO Xing-chun, LU Guo-hui, WANG Xiao-chun, YANG Yong-liang. The Levels and Analytical Developments of Brominated Flame Retardant Hexabromocyclododecanes from Various Environmental Media[J]. Rock and Mineral Analysis, 2012, 31(2): 210-217.
Citation: JIAO Xing-chun, LU Guo-hui, WANG Xiao-chun, YANG Yong-liang. The Levels and Analytical Developments of Brominated Flame Retardant Hexabromocyclododecanes from Various Environmental Media[J]. Rock and Mineral Analysis, 2012, 31(2): 210-217.
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The Levels and Analytical Developments of Brominated Flame Retardant Hexabromocyclododecanes from Various Environmental Media

  • 1.

    Key Laboratory of Eco-Geochemistry, Chinese Academy of Geological Sciences, National Research Center for Geoanalysis, Beijing 100037, China

  • 2.

    Key Laboratory of Eco-Geochemistry, Chinese Academy of Geological Sciences, National Research Center for Geoanalysis, Beijing 100037, China

  • 3.

    Key Laboratory of Eco-Geochemistry, Chinese Academy of Geological Sciences, National Research Center for Geoanalysis, Beijing 100037, China

  • 4.

    Key Laboratory of Eco-Geochemistry, Chinese Academy of Geological Sciences, National Research Center for Geoanalysis, Beijing 100037, China

More Information
  • Received Date: July 25, 2011
    Abstract
  • Hexabromocyclododecanes (HBCDs) are used as flame retardants primarily in thermal insulation building materials, upholstery textiles, and a little in electronics. During 2006, the production and use of penta- and octa-bromodiphenyl ethers was restricted in Europe, and therefore HBCDs may be used as an alternative for polybrominated diphenyl ethers (PBDEs) in some applications. The atmosphere and bodies of water are the two main persistent reservoirs. The high content of HBCDs was detected in the environmental medium adjacent to the point source, which was much higher than that in the region without any point source. According to the different compound structure, environmental condition and biological metabolism processing, synthetic HBCDs were mainly γ-HBCD and the biotic HBCDs were α-HBCD. Although the Gas Chromatography-Mass Spectrometry (GC-MS) technique has high sensitive detection for HBCDs, it is restricted to isomer analysis of compounds by thermal recomposition and thermal degradation of HBCDs. LC-MS overcame these restrictions and was applied to distinguish enantiomer and diastereomer. The detection limit was improved by the coupling technique of MS/MS. This review summarizes the levels and analytical developments of HBCDs. HBCD stereoisomers transform and degrade during production, which is a potential avenue for future research work. Further study on the environmental behaviour of HBCDs, their evolvement trend, control measures and alternative development are suggested in order to to build a larger HBCD database to meet the convention and to prepare more efficient risk management.
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  • Sellström U, Kierkegaard A, de Wit C, Jansson B. Polybrominated diphenyl ethers and hexabromo-cyclododecane in sediment and fish from a swedish river [J]. Environment Toxicological Chemistry,1998, 17: 1065-1072.

    Sellström U, Kierkegaard A, de Wit C, Jansson B. Polybrominated diphenyl ethers and hexabromo-cyclododecane in sediment and fish from a swedish river [J]. Environment Toxicological Chemistry,1998, 17: 1065-1072.
    Law R J, Allchin C R, de Boer J, Covaci A, Herzke D, Lepom P, Morris S, Tronczynski J, de Wit C. Levels and trends of brominated flame retardants in the European environment [J].Chemosphere,2006, 64(2):187-208.

    Law R J, Allchin C R, de Boer J, Covaci A, Herzke D, Lepom P, Morris S, Tronczynski J, de Wit C. Levels and trends of brominated flame retardants in the European environment [J].Chemosphere,2006, 64(2):187-208.
    李永东,云霞,那广水,高会.环境中六溴环十二烷的研究进展 [J].环境与健康杂志,2010,27(10): 933-936.
    Law R J, Kohler M, Heeb N V, Gerecke A C, Schmid P, Voorspols S, Covaci A, Becher G, Janak K, Thomsen C. Hexabromocyclododecane challenges scien-tists and regulators [J]. Environmental Science & Technology, 2005, 39(13): 281A-287A.

    Law R J, Kohler M, Heeb N V, Gerecke A C, Schmid P, Voorspols S, Covaci A, Becher G, Janak K, Thomsen C. Hexabromocyclododecane challenges scien-tists and regulators [J]. Environmental Science & Technology, 2005, 39(13): 281A-287A.
    Covaci A, Gerecke A C, Law R J, Voorspoels S, Kohler M, Heeb N V, Leslie H, Allchin C R, de Boer J. Hexabromocyclododecanes (HBCDs) in the environment and humans: A review [J]. Environmental Science & Technology, 2006, 40 (12): 3679-3688.

    Covaci A, Gerecke A C, Law R J, Voorspoels S, Kohler M, Heeb N V, Leslie H, Allchin C R, de Boer J. Hexabromocyclododecanes (HBCDs) in the environment and humans: A review [J]. Environmental Science & Technology, 2006, 40 (12): 3679-3688.
    王亚韡,蔡亚岐,江桂斌.斯德哥尔摩公约新增持久性有机污染物的一些研究进展 [J].中国科学,2010,40 (2): 99-123.
    Report of the persistent organic pollutants review commi-ttee on the work of its sixth meeting, UNEP/POPS/POPRC.6/13 //Stockholm Convention on Persistent Organic Pollutants.

    Report of the persistent organic pollutants review commi-ttee on the work of its sixth meeting, UNEP/POPS/POPRC.6/13 //Stockholm Convention on Persistent Organic Pollutants.
    Alaee M, Arias P, Sjodin A, Bergman A. An overview of commercially used brominated flame retardants, their applications, their use patterns in different countries/regions and possible modes of release [J]. Environment International,2003, 29: 683-689.

    Alaee M, Arias P, Sjodin A, Bergman A. An overview of commercially used brominated flame retardants, their applications, their use patterns in different countries/regions and possible modes of release [J]. Environment International,2003, 29: 683-689.
    Managaki S, Miyake Y, Yokoyama Y, Hondo H, Masunaga S, Nakai S, Kobayashi T, Kameya T, Kimura A, Nakarai T, Oka Y, Otani H, Miyake A. Emission load of hexabromocyclododecane in Japan based on the substance flow analysis [J]. Organohalogen Compounds, 2009, 71: 2471-2476.

    Managaki S, Miyake Y, Yokoyama Y, Hondo H, Masunaga S, Nakai S, Kobayashi T, Kameya T, Kimura A, Nakarai T, Oka Y, Otani H, Miyake A. Emission load of hexabromocyclododecane in Japan based on the substance flow analysis [J]. Organohalogen Compounds, 2009, 71: 2471-2476.
    Morf L, Buser A, Taverna R, Bader H P, Scheidegger R. Dynamic substance flow analysis as a valuable tool: A case study for brominated flame retardants as an example of potential endocrine disruptors [J]. CHIMIA International Journal for Chemistry, 2008: 62(5):424-431.

    Morf L, Buser A, Taverna R, Bader H P, Scheidegger R. Dynamic substance flow analysis as a valuable tool: A case study for brominated flame retardants as an example of potential endocrine disruptors [J]. CHIMIA International Journal for Chemistry, 2008: 62(5):424-431.
    Arnot J, McCarty L, Armitage J, Toose-Reid L, Wania F, Cousins I. An evaluation of hexabromocyclododecane (HBCD) for persistent organic pollutant (POP) properties and the potential for adverse effects in the environment. European Brominated Flame Retardant Industry Panel (EBFRIP). 2009: 214.

    Arnot J, McCarty L, Armitage J, Toose-Reid L, Wania F, Cousins I. An evaluation of hexabromocyclododecane (HBCD) for persistent organic pollutant (POP) properties and the potential for adverse effects in the environment. European Brominated Flame Retardant Industry Panel (EBFRIP). 2009: 214.
    Remberger M, Sternbeck J, Palm A, Kaj L, Stromberg K, Brorstrom-Lundén E. The environmental occurrence of hexabromocyclododecane in Sweden [J]. Chemosphere, 2004, 54: 9-21.

    Remberger M, Sternbeck J, Palm A, Kaj L, Stromberg K, Brorstrom-Lundén E. The environmental occurrence of hexabromocyclododecane in Sweden [J]. Chemosphere, 2004, 54: 9-21.
    Yu Z, Chen L, Mai B, Wu M, Sheng G, Fu J, Peng P A. Diastereoisomer- and enantiomer-specific profiles of hexabromocyclododecane in the atmosphere of an urban city in South China [J]. Environmental Science & Technology, 2008, 42: 3996-4001.

    Yu Z, Chen L, Mai B, Wu M, Sheng G, Fu J, Peng P A. Diastereoisomer- and enantiomer-specific profiles of hexabromocyclododecane in the atmosphere of an urban city in South China [J]. Environmental Science & Technology, 2008, 42: 3996-4001.
    Hoh E, Hites R A. Brominated flame retardants in the atmosphere of the East-Central United States [J].Environmental Science & Technology, 2005, 39: 7794-7802.

    Hoh E, Hites R A. Brominated flame retardants in the atmosphere of the East-Central United States [J].Environmental Science & Technology, 2005, 39: 7794-7802.
    Covaci A, Harrad S, Abdallah M A, Ali N, Law R J, Herzke D, de Wit C. Novel brominated flame retardants: A review of their analysis, environmental fate and behavior [J]. Environmental International, 2011, 37:532-556.

    Covaci A, Harrad S, Abdallah M A, Ali N, Law R J, Herzke D, de Wit C. Novel brominated flame retardants: A review of their analysis, environmental fate and behavior [J]. Environmental International, 2011, 37:532-556.
    Wania F. Assessing the long-range transport potential of tetrabromobisphenol A and hexabromocyclododecane using several multimedia transport models. WECC Wania Environmental Chemists Corporation, 2003.

    Wania F. Assessing the long-range transport potential of tetrabromobisphenol A and hexabromocyclododecane using several multimedia transport models. WECC Wania Environmental Chemists Corporation, 2003.
    de Wit C, Alaee M, Muir D. Brominated flame retardants in the Arctican overview of spatial and temporal trends [J]. Organohalogen Compound, 2004, 66: 3811-3816.

    de Wit C, Alaee M, Muir D. Brominated flame retardants in the Arctican overview of spatial and temporal trends [J]. Organohalogen Compound, 2004, 66: 3811-3816.
    Muir D C G, Backus S, Derocher A E. Brominated flame retardants in polar bears (Ursus maritimus) from Alaska, the Canadian Arctic, East Greenland, and Svalbard [J]. Environmental Science & Technology, 2006,40:449-455.

    Muir D C G, Backus S, Derocher A E. Brominated flame retardants in polar bears (Ursus maritimus) from Alaska, the Canadian Arctic, East Greenland, and Svalbard [J]. Environmental Science & Technology, 2006,40:449-455.
    Jenssen B M, Sørmo E G, Baek K, Bytingsvik J, Gaustad H, Ruus A, Skaare J U. Brominated flame retardants in North-East Atlantic marine ecosystems [J]. Environmental Health Perspective, 2007, 115(1): 35-41.

    Jenssen B M, Sørmo E G, Baek K, Bytingsvik J, Gaustad H, Ruus A, Skaare J U. Brominated flame retardants in North-East Atlantic marine ecosystems [J]. Environmental Health Perspective, 2007, 115(1): 35-41.
    Petersen M, Hamm S, Schaer A, Esser U. Comparative GC/MS and LC/MS detection of hexabromocyclo-dodecane (HBCD) in soil and water samples [J]. Organohalogen Compound, 2004, 66: 224-231.

    Petersen M, Hamm S, Schaer A, Esser U. Comparative GC/MS and LC/MS detection of hexabromocyclo-dodecane (HBCD) in soil and water samples [J]. Organohalogen Compound, 2004, 66: 224-231.
    Meng X Z, DuanY P, Yang C, Pan Z Y, Wen Z H, Chen L. Occurrence, sources, and inventory of hexabromocyclododecanes (HBCDs) in soils from Chongming Island, the Yangtze River Delta (YRD) [J]. Chemosphere, 2011, 82: 725-731.

    Meng X Z, DuanY P, Yang C, Pan Z Y, Wen Z H, Chen L. Occurrence, sources, and inventory of hexabromocyclododecanes (HBCDs) in soils from Chongming Island, the Yangtze River Delta (YRD) [J]. Chemosphere, 2011, 82: 725-731.
    Law R J, Bersuder P, Barry J, Wilford B H, Allchin C R, Jepson P D. A significant downturn in levels of hexabromocyclododecane in the blubber of harbour porpoises (Phocoena phocoena) stranded or bycaught in the UK: An update to 2006 [J]. Environmental Science & Technology, 2008, 42: 9104-9109.

    Law R J, Bersuder P, Barry J, Wilford B H, Allchin C R, Jepson P D. A significant downturn in levels of hexabromocyclododecane in the blubber of harbour porpoises (Phocoena phocoena) stranded or bycaught in the UK: An update to 2006 [J]. Environmental Science & Technology, 2008, 42: 9104-9109.
    Law R J, Herzke D, Harrad S, Morris S, Bersuder P, Allchin C R. Levels and trends of HBCD and BDEs in the European and Asian environments, with some information for other BFRs [J]. Chemosphere, 2008, 73(2): 223-241.

    Law R J, Herzke D, Harrad S, Morris S, Bersuder P, Allchin C R. Levels and trends of HBCD and BDEs in the European and Asian environments, with some information for other BFRs [J]. Chemosphere, 2008, 73(2): 223-241.
    Tomy G T, Pleskach K, Ferguson S H, Hare J, Stern G, Macinnis G, Marvin C H, Loseto L. Trophodynamics of some PFCs and BFRs in a Western Canadian Arctic marine food web [J]. Environmental Science & Technology, 2009,43(11):4076-4081.

    Tomy G T, Pleskach K, Ferguson S H, Hare J, Stern G, Macinnis G, Marvin C H, Loseto L. Trophodynamics of some PFCs and BFRs in a Western Canadian Arctic marine food web [J]. Environmental Science & Technology, 2009,43(11):4076-4081.
    Heeb N V, Schweizer W B, Kohler M, Gerecke A C. Structure elucidation of hexabromocyclododecanes, a class of compounds with a complex stereochemistry [J].Chemosphere, 2005, 61: 65-73.

    Heeb N V, Schweizer W B, Kohler M, Gerecke A C. Structure elucidation of hexabromocyclododecanes, a class of compounds with a complex stereochemistry [J].Chemosphere, 2005, 61: 65-73.
    Janák K, Covaci A, Voorspoels S, Becher G. Hexabro-mocyclododecane (HBCD) in marine species from the western Scheldt estuary: Diastereomer- and enantiomer-specific accumulation [J]. Environmental Science & Technology, 2005, 39: 1987-1994.

    Janák K, Covaci A, Voorspoels S, Becher G. Hexabro-mocyclododecane (HBCD) in marine species from the western Scheldt estuary: Diastereomer- and enantiomer-specific accumulation [J]. Environmental Science & Technology, 2005, 39: 1987-1994.
    Knudsen L B, Borg K, Jørgensen E H, van Bavel B, Schlabach M, Verreault J, Gabrielsen G W. Halogenated organic contaminants and mercury in northern fulmars (Fulmarus glacialis): Levels, relationships to dietary descriptors and blood to liver comparison [J].Environmental Pollution, 2007, 146: 25-33.

    Knudsen L B, Borg K, Jørgensen E H, van Bavel B, Schlabach M, Verreault J, Gabrielsen G W. Halogenated organic contaminants and mercury in northern fulmars (Fulmarus glacialis): Levels, relationships to dietary descriptors and blood to liver comparison [J].Environmental Pollution, 2007, 146: 25-33.
    Thomsen C, Molander P, Daae H L, Janak K, Froshaug M, Liane V H, Thorud S, Becher G, Dybing E G. Occupational exposure to hexabromocyclododecane at an industrial plant [J]. Environmental Science & Technology, 2007, 41: 5210-5216.

    Thomsen C, Molander P, Daae H L, Janak K, Froshaug M, Liane V H, Thorud S, Becher G, Dybing E G. Occupational exposure to hexabromocyclododecane at an industrial plant [J]. Environmental Science & Technology, 2007, 41: 5210-5216.
    Poldera A, Gabrielsenb G W, Odlandc J , Savinovad T N, Tkacheve A, Løken K B, Skaare J U. Spatial and temporal changes of chlorinated pesticides, PCBs, dioxins (PCDDs/PCDFs) and brominated flame retardants in human breast milk from Northern Russia [J]. Science of the Total Environment, 2008, 391(1):41-54.

    Poldera A, Gabrielsenb G W, Odlandc J , Savinovad T N, Tkacheve A, Løken K B, Skaare J U. Spatial and temporal changes of chlorinated pesticides, PCBs, dioxins (PCDDs/PCDFs) and brominated flame retardants in human breast milk from Northern Russia [J]. Science of the Total Environment, 2008, 391(1):41-54.
    Polder A, Thomsen C, Lindström G, Løken K B, Skaare J U. Levels and temporal trends of chlorinated pesticides, polychlorinated biphenyls and brominated flame retardants in individual human breast milk samples from Northern and Southern Norway [J]. Chemosphere, 2008, 73(1):14-23.

    Polder A, Thomsen C, Lindström G, Løken K B, Skaare J U. Levels and temporal trends of chlorinated pesticides, polychlorinated biphenyls and brominated flame retardants in individual human breast milk samples from Northern and Southern Norway [J]. Chemosphere, 2008, 73(1):14-23.
    Eljarrat E, Guerra P, Martinez E, Farre M, Alvarez J G, Lopez-Teijon M, Barcelo D. Hexabromocyclo-dodecane in human breast milk: Levels and enantiomeric patterns [J]. Environmental Science & Technology, 2009, 43: 1940-1946.

    Eljarrat E, Guerra P, Martinez E, Farre M, Alvarez J G, Lopez-Teijon M, Barcelo D. Hexabromocyclo-dodecane in human breast milk: Levels and enantiomeric patterns [J]. Environmental Science & Technology, 2009, 43: 1940-1946.
    Kalantzi O I, Geens T, Covaci A, Siskos P A. Distribution of polybrominated diphenyl ethers (PBDEs) and other persistent organic pollutants in human serum from Greece [J]. Environment International, 2011, 37:349-353.

    Kalantzi O I, Geens T, Covaci A, Siskos P A. Distribution of polybrominated diphenyl ethers (PBDEs) and other persistent organic pollutants in human serum from Greece [J]. Environment International, 2011, 37:349-353.
    Goscinny S, Vandevijvere S, Maleki M, Overmeire I V, Windal I, Hanot V, Blaude M N, Vleminckx C, Loco J V. Dietary intake of hexabromocyclododecane diastereoi-somers (a-, b-, and c-HBCD) in the Belgian adult population [J]. Chemosphere, 2011hen S J, Chen D, Mai B X. Tetrabromobisphenol-A and hexabromocyclododecane in birds from an e-waste region in South China: Influence of diet on diastereoisomer- and enantiomer-specific distribution and trophodynamics [J]. Environmental Science & Technology, 2010, 44: 5748-5754.

    Goscinny S, Vandevijvere S, Maleki M, Overmeire I V, Windal I, Hanot V, Blaude M N, Vleminckx C, Loco J V. Dietary intake of hexabromocyclododecane diastereoi-somers (a-, b-, and c-HBCD) in the Belgian adult population [J]. Chemosphere, 2011hen S J, Chen D, Mai B X. Tetrabromobisphenol-A and hexabromocyclododecane in birds from an e-waste region in South China: Influence of diet on diastereoisomer- and enantiomer-specific distribution and trophodynamics [J]. Environmental Science & Technology, 2010, 44: 5748-5754.
    Eljarrat E, Barcelo D. Brominated Flame Retardants (The Handbook of Environment Chemistry) [M]. New York: Springer Press, 2011: 19-53.

    Eljarrat E, Barcelo D. Brominated Flame Retardants (The Handbook of Environment Chemistry) [M]. New York: Springer Press, 2011: 19-53.
    Lindberg P, Sellström U, Häggberg L, de Wit C. Higher brominated diphenyl ethers and hexabromo-cyclododecane found in eggs of peregrine falcons (Falco peregrinus) breeding in Sweden [J]. Environmental Science & Technology, 2004, 38: 93-96.

    Lindberg P, Sellström U, Häggberg L, de Wit C. Higher brominated diphenyl ethers and hexabromo-cyclododecane found in eggs of peregrine falcons (Falco peregrinus) breeding in Sweden [J]. Environmental Science & Technology, 2004, 38: 93-96.
    Abdallah M A, Harrad S, Covaci A. Hexabromocyclo-dodecanes and tetrabromobisphenol-A in indoor air and dust in Birmingham, U.K: Implications for human exposure [J]. Environmental Science & Technology, 2008, 42(18):6855-6861.

    Abdallah M A, Harrad S, Covaci A. Hexabromocyclo-dodecanes and tetrabromobisphenol-A in indoor air and dust in Birmingham, U.K: Implications for human exposure [J]. Environmental Science & Technology, 2008, 42(18):6855-6861.
    Roosens L, Abdallah M A, Harrad S, Neels H, Covaci A. Exposure to hexabromocyclododecanes (HBCDs) via dust ingestion, but not diet, correlates with concentrations in human serum: Preliminary results [J]. Environment Health Perspective, 2009, 117(11):1707-1712.

    Roosens L, Abdallah M A, Harrad S, Neels H, Covaci A. Exposure to hexabromocyclododecanes (HBCDs) via dust ingestion, but not diet, correlates with concentrations in human serum: Preliminary results [J]. Environment Health Perspective, 2009, 117(11):1707-1712.
    Covaci A, Voorspoels S, de Boer J. Determination of brominated flame retardants, with emphasis on polybrominated diphenyl ethers (PBDEs) in environmental and human samples: A review [J]. Environment International, 2003, 29: 735-756.

    Covaci A, Voorspoels S, de Boer J. Determination of brominated flame retardants, with emphasis on polybrominated diphenyl ethers (PBDEs) in environmental and human samples: A review [J]. Environment International, 2003, 29: 735-756.
    Guerra P, Covaci A, Eljarrat E, Barcelo D. Recent methodologies for brominated flame retardant determinations by means of liquid chromatography mass spectrometry [M]//Eljarrat E, Barcelo D, eds. Brominated Flame Retardants, Handbook of Environmental Chemistry. 2011: 95-122.

    Guerra P, Covaci A, Eljarrat E, Barcelo D. Recent methodologies for brominated flame retardant determinations by means of liquid chromatography mass spectrometry [M]//Eljarrat E, Barcelo D, eds. Brominated Flame Retardants, Handbook of Environmental Chemistry. 2011: 95-122.
    Suzuki S, Hasegawa A. Determination of hexabromo- cyclododecane diastereoisomers and tetrabromobisphenol A in water and sediment by liquid chromatography/mass spectrometry [J]. Analytical Science, 2006, 22(3):469-474.

    Suzuki S, Hasegawa A. Determination of hexabromo- cyclododecane diastereoisomers and tetrabromobisphenol A in water and sediment by liquid chromatography/mass spectrometry [J]. Analytical Science, 2006, 22(3):469-474.
    Zhao R S, Wang X, Zhang L L, Wang X X, Yuan J P. Ionic liquid/ionic liquid dispersive liquid liquid microextraction, a new sample enrichment procedure for the determination of hexabromocyclododecane diastereo-mers in environmental water samples [J]. Analytical Methods, 2011, 3: 831-836.

    Zhao R S, Wang X, Zhang L L, Wang X X, Yuan J P. Ionic liquid/ionic liquid dispersive liquid liquid microextraction, a new sample enrichment procedure for the determination of hexabromocyclododecane diastereo-mers in environmental water samples [J]. Analytical Methods, 2011, 3: 831-836.
    Stapleton H M, Brazil B, Holbrook R D, Mitchelmore C L, Benedict R, Konstantinov A P. In vivo and in vitro debromination of decabromodiphenyl ether (BDE 209) by Juvenile Rainbow Trout and Common Carp [J]. Environmental Science & Technology, 2006, 40 (15): 4653-4658.

    Stapleton H M, Brazil B, Holbrook R D, Mitchelmore C L, Benedict R, Konstantinov A P. In vivo and in vitro debromination of decabromodiphenyl ether (BDE 209) by Juvenile Rainbow Trout and Common Carp [J]. Environmental Science & Technology, 2006, 40 (15): 4653-4658.
    Abdallah M A, Ibarra C, Batty L C, Covaci A. Com-parative evaluation of liquid chromatography-mass spectrometry versus gas chromatography-mass spectro-metry for the determination of hexabromocyclododecanes and their degradation products in indoor dust [J]. Journal of Chromatography A, 2008, 1190: 333-341.

    Abdallah M A, Ibarra C, Batty L C, Covaci A. Com-parative evaluation of liquid chromatography-mass spectrometry versus gas chromatography-mass spectro-metry for the determination of hexabromocyclododecanes and their degradation products in indoor dust [J]. Journal of Chromatography A, 2008, 1190: 333-341.
    周丽,史双昕,董亮,张烃,邵丁丁,黄业茹.高效液相色谱-质谱法测定土壤中溴代阻燃剂的方法 [J].环境化学, 2007, 27(5): 688-689.
    He M J, Luo X J, Yu L H, Liu J, Zhang X L, C

    He M J, Luo X J, Yu L H, Liu J, Zhang X L, C
    Xia C H, Lam J C W, Wu X G, Sun L, Xie Z, Lam P K S. Hexabromocyclododecanes (HBCDs) in marine fishes along the Chinese coastline [J]. Chemosphere, 2011, 82:1662-1668.

    Xia C H, Lam J C W, Wu X G, Sun L, Xie Z, Lam P K S. Hexabromocyclododecanes (HBCDs) in marine fishes along the Chinese coastline [J]. Chemosphere, 2011, 82:1662-1668.
    Hu J, Jin J, Wang Y, Ma Z, Zheng W. Levels of polybrominated diphenyl ethers and hexabromo-cyclododecane in the atmosphere and tree bark from Beijing, China [J]. Chemosphere,2011,84: 355-360.

    Hu J, Jin J, Wang Y, Ma Z, Zheng W. Levels of polybrominated diphenyl ethers and hexabromo-cyclododecane in the atmosphere and tree bark from Beijing, China [J]. Chemosphere,2011,84: 355-360.
    de Boer J, Wells D E. Pitfalls in the analysis of brominated flame retardants in environmental, human and food samples including results of three international interlaboratory studies [J]. Trends in Analytical Chemistry, 2006,25(4):364-372. in foods and human milk [J]. Environmental Science & Technology, 2009, 43(12):4314-4322.

    de Boer J, Wells D E. Pitfalls in the analysis of brominated flame retardants in environmental, human and food samples including results of three international interlaboratory studies [J]. Trends in Analytical Chemistry, 2006,25(4):364-372. in foods and human milk [J]. Environmental Science & Technology, 2009, 43(12):4314-4322.
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