• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
LIU Jin-wei, WANG Lei, AN Cai-xiu, XIAO Fan, ZHA Xiao-kang, GAO Xi-juan. Gas Chromatographic Determination of Polychlorinated Biphenyls in Drinking Water Samples with Solid Phase Extraction[J]. Rock and Mineral Analysis, 2011, 30(5): 611-616.
Citation: LIU Jin-wei, WANG Lei, AN Cai-xiu, XIAO Fan, ZHA Xiao-kang, GAO Xi-juan. Gas Chromatographic Determination of Polychlorinated Biphenyls in Drinking Water Samples with Solid Phase Extraction[J]. Rock and Mineral Analysis, 2011, 30(5): 611-616.

Gas Chromatographic Determination of Polychlorinated Biphenyls in Drinking Water Samples with Solid Phase Extraction

More Information
  • Received Date: June 02, 2010
  • Revised Date: January 03, 2011
  • A method for the determination of Polychlorinated Biphenyls (PCBs) in drinking water by gas chromatography was established. Determination parameters, such as elution curves, pH, effect of methanol, dosage of NaCl and flow rate are discussed and optimized in this paper. The method is compared to the classical liquid-liquid extraction method. By the new method, 84 PCBs were extracted from drinking water under pH=3 and flow rate of 5 mL/min by large volume sampler-solid phase extraction, eluted by 7 mL acetone and 5 mL acetonitrile. The eluate was concentrated and the solvent exchanged with hexane as 1.0 mL by nitrogen blowing, then an internal standard added. The target compounds were determined by gas chromatography with μ-electron capture detector, verified by mass spectrometry in the selected ion method, under the same conditions as chromatography. The detection limits of the method for 84 PCBs ranged from 1.2 to 15.0 ng/L, and the average recoveries ranged from 74.8% to 126.8% with relative standard deviation (RSD) of 1.1%-14.8%. This method can be applied to the routine analysis of PCBs in water samples and has the advantages of simultaneous extraction for multi samples, is a rapid process, and produces less pollution with more cost effectiveness.
  • 杨佳佳,吴淑琪,佟玲.多氯联苯的环境特性及分析测试进展[J].岩矿测试,2009,28(5):444-451.
    何淼,饶竹.圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药[J].岩矿测试, 2008,27(1):12-16.
    佟玲,吴淑琪,杨佳佳,张玲金.土壤中25种有机氯农药和多氯联苯的气相色谱分析方法研究[J].岩矿测试,2010,29(3):277-281.
    汪雨,支辛辛,张玲金,杨永亮. C18固相膜萃取-气相色谱法测定饮用水中12种有机氯农药[J].岩矿测试,2006,25(4):301-305.
    彭艳超,黄根华,孙敏.多氯联苯对人体危害的研究[J].中国新技术新产品,2010(3):23-24.
    樊祥科,魏爱泓,花卫华,矫新明.超声萃取-佛罗里土净化-气相色谱法测定沉积物中的多氯联苯[J].海洋环境科学,2008,27(A01):95-97.
    赵宝中,李银艳,郝向荣,韩天熙,付强,陈亚光,李秀.多氯联苯辛醇/水分配系数的计算[J].东北师大学报:自然科学版,2004,36(2):41-44.
    李霜.多氯联苯与人体健康[J].中国劳动卫生职业病杂志,2005,23(4):316-319.
    顾海东,秦宏兵,尹燕敏,朱剑禾,陶冠红.SBSE-GC/MS法测定饮用水源水中7种多氯联苯单体[J].环境监测管理与技术,2010(2):44-47.
    Conka K, Drobna B, Kocan A, Petrik J. Simple solid phase extraction method for determination of polychlorinated biphenyls and selected organchlorine pesticides in human serum[J]. Journal of Chromatography A,2005,1084(1-2):33-38.

    Conka K, Drobna B, Kocan A, Petrik J. Simple solid phase extraction method for determination of polychlorinated biphenyls and selected organchlorine pesticides in human serum[J]. Journal of Chromatography A,2005,1084(1-2):33-38.
    张烃,董亮,史双昕,周丽,张利飞,邵丁丁,黄业茹.土壤样品多氯联苯的GC/ECD双柱测定方法的优化[J].环境科学研究,2010,23(9):1204-1209.
    胡恩宇,杨丽莉,王美飞,母应锋.气相色谱法同时测定水中28种多氯联苯单体[J].环境监测管理与技术,2010(1):44-48.
    李金花,宋兴良,陈兆鹏,陈令新.顶空固相微萃取-气相色谱/质谱法测定富含腐殖质海水中的多氯联苯[J].分析化学,2009,37(A02):152.
    闻胜,龚艳,史廷明,沈更新,刘家发,陈明,邵生文,徐盈.二噁英、多溴联苯醚和多氯联苯同时测定方法的研究[J].分析科学学报,2009,25(6):629-633.
    EPA Method 3510C,Separatory funnel liquid-liquid extrac-tion [S].

    EPA Method 3510C,Separatory funnel liquid-liquid extrac-tion [S].
    魏爱泓,樊祥科,袁广旺,方南娟.毛细管柱气相色谱法测定海水中的多氯联苯[J].海洋环境科学,2007,26(6):580-582.
    顾海东,秦宏兵,尹燕敏,朱剑禾,陶冠红.SBSE-GC/MS法测定饮用水源水中7种多氯联苯单体[J].环境监测管理与技术,2010,22(2):44-47.
    曹玉廷,王丹丽,高丽娟.基于前处理的色谱联动检测多氯联苯的技术研究[J].宁波大学学报:理工版,2010,23(4):87-91.
    刘静,崔兆杰,许宏宇,谭凤训.类二噁英类多氯联苯的双柱气相色谱分析方法研究[J].山东大学学报:工学版,2008,38(4):116-122.
    黄业茹,施钧慧,唐莉. GC/MS分析环境样品中的多氯联苯(PCBs)[J].质谱学报,2000,21(4):45-46.
    Mydlová-Memersheimerová J, Tienpont B, David F, Krupcík J, Sandra P.Gas chromatography of 209 polychlorinated biphenyl congeners on an extremely efficient nonselective capillary column[J].Journal of Chromatography A,2009,1216(32):6043-6062.

    Mydlová-Memersheimerová J, Tienpont B, David F, Krupcík J, Sandra P.Gas chromatography of 209 polychlorinated biphenyl congeners on an extremely efficient nonselective capillary column[J].Journal of Chromatography A,2009,1216(32):6043-6062.
    Mullin M D, Pochini C M, McCrindle S, Romkes M, Safe S H, Safe L M. High-resolution PCB Analysis: Synthesis and chromatographic properties of All 209 PCB congeners[J]. Environmental Science & Technology,1984,18(6):468-476.

    Mullin M D, Pochini C M, McCrindle S, Romkes M, Safe S H, Safe L M. High-resolution PCB Analysis: Synthesis and chromatographic properties of All 209 PCB congeners[J]. Environmental Science & Technology,1984,18(6):468-476.
    吴瞻英,饶竹,李夏,曹亚萍.微波萃取/气相色谱-质谱测定土壤中的多氯联苯[J].分析试验室,2008,27(6):61-63.
    谭建华,李慧勇,郑艳明,王继才,陈乔华,沈聪文,郭长虹,席绍峰,李伟盛.食品纸包装材料中指示性多氯联苯的固相萃取/气相色谱-质谱联用法测定[J].分析测试学报,2009,28(3):46-46.
  • Related Articles

    [1]QIN Xiao-li, TIAN Gui, LI Chao-chang, JIANG Zhi-lin. Determination of Thorium and Potassium Oxide in Geological Samples by Inductively Coupled Plasma-Optical Emission Spectrometry[J]. Rock and Mineral Analysis, 2019, 38(6): 741-746. DOI: 10.15898/j.cnki.11-2131/td.201812290142
    [2]Jun WANG, Di WANG, Chang-sheng DENG, Jian-mei ZHANG, Dong YANG, Bin-tang WANG, Su-xia ZHU. Determination of Thorium in Geochemical Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2014, 33(4): 501-505.
    [3]WANG Xue-wei, PENG Nan-lan, TANG Qi-ping, JIN Ting-ting. Determination of Sc in Geological Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry with Four-Acid Digestion[J]. Rock and Mineral Analysis, 2014, 33(2): 212-217.
    [4]ZHAO Qing-ling, LI Qing-cai, PU Jun, WU Dian-xi. Simultaneous Determination of 31 Elements in Soil Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2010, 29(4): 455-457.
    [5]ZHAO Qing-ling, LI Qing-cai, SUN Ning, MA Qiang, CAI Wei. Determination of 25 Elements in Soil Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2009, 28(2): 191-193.
    [6]Determination of Total Boron in Foods by Inductively Coupled Plasma-Optical Emission Spectrometry with Microwave Digestion Sample Preparation[J]. Rock and Mineral Analysis, 2008, 27(1): 21-24.
    [7]Determination of Tantalum in Geological Samples by Inductively Coupled Plasma Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2005, (2): 151-153.
    [8]Determination of Boron, Arsenic and Sulfur in Geological Samples by Inductively Coupled Plasma Atomic Emission Spectrometry with Sample Treatment by Pressurized Decomposition[J]. Rock and Mineral Analysis, 2003, (4): 241-247.
    [9]Indirect Determination of Chlorine Content in Coal by Inductively Coupled Plasma Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2003, (1): 64-66.
    [10]Determination of Uranium in Geological Samples by ICP_AES[J]. Rock and Mineral Analysis, 1997, (4): 296-298302.

Catalog

    Article views (1624) PDF downloads (862) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return