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LI Xiao-ya, GUI Jian-ye, ZHANG Li, ZHANG Yong-tao, LI Ke. Simultaneous Determination of Chlorinated Acidic Herbicides in Waters by Ion-pair Chromatography[J]. Rock and Mineral Analysis, 2011, 30(3): 349-352.
Citation: LI Xiao-ya, GUI Jian-ye, ZHANG Li, ZHANG Yong-tao, LI Ke. Simultaneous Determination of Chlorinated Acidic Herbicides in Waters by Ion-pair Chromatography[J]. Rock and Mineral Analysis, 2011, 30(3): 349-352.
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Simultaneous Determination of Chlorinated Acidic Herbicides in Waters by Ion-pair Chromatography

  • 1.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China

  • 2.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China

  • 3.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China

  • 4.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China

  • 5.

    Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China

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  • Received Date: August 23, 2010
  • Revised Date: January 16, 2011
    Abstract
  • A method for the simultaneous detection of several chlorinated acid herbicides such as dicamba and bentazon etc by ion-pair chromatography was developed. Several strongly polar and weak reserve chlorinated acid herbicides can be separated simultaneously from reversed-phase chromatography column by adding ion-pair reagent. Shim-pack VP-ODS column was used for analyte separation with ion-pair solution and the mobile phase was at a constant flow rate of 1.8 mL/min. Extraction condition, ion-pair and the mobile phase were selected and optimized. The detection limit ranges of the method for different herbicides were 0.03 to 0.15 μg/L with RSD less than 10%. Comparing with high performance liquid chromatography and gas chromatography-mass spectrometry, the established method completely separates the 9 sorts of herbicides with advantages of simple operation, high separating effect, high recoveries and less interferences, which meet the requirements of all kind of water.
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  • 张永涛,张莉,左海英,桂建业,李晓亚,李桂香.重氮甲烷衍生气相色谱-质谱法检测地下水中17种酸性除草剂[J].岩矿测试,2010,29(4):345-349.
    张彤晴,蒋丽娟,葛家春,周刚,林海.五氯苯酚对渔业环境的危害与对策研究进展[J].江苏农业科学,2007(4): 256-259.
    Rowe V K, Hymas T A. Summary of toxicological infor-mation on 2,4-D and 2,4,5-T type herbicides and an evaluation of the hazards to livestock associated with their use [J].American Journal of Veterinary Research, 1954, 15(57): 622-629.

    Rowe V K, Hymas T A. Summary of toxicological infor-mation on 2,4-D and 2,4,5-T type herbicides and an evaluation of the hazards to livestock associated with their use [J].American Journal of Veterinary Research, 1954, 15(57): 622-629.
    周林军,刘济宁,石利利,单正军,陈国松,吕凤兰.液液微萃取-甲基衍生化/气相色谱法对水中氯代酸除草剂的测定[J].分析测试学报,2009,28(7):829-833.
    苏允兰,莫汉宏,安凤春.土壤中结合态苯氧羧酸类除草剂的测定[J].环境化学,2001,20(6):577-581.
    徐晓琴.SPME-GC/MS法测定饮用水中除草剂[J].质量技术监督研究,2009(4):34-38.
    刘娟,朱昱,齐宝坤,谭家镒.固相萃取-气质联用法检测植物叶中4种苯氧羧酸类类除草剂[J].分析试验室,2009,28(5):152-155.
    颜鸿飞,黄志强,张莹,李拥军,王美玲.气相色谱-质谱法测定茶叶中29种酸性除草剂的残留量[J].色谱,2009,27(3):288-293.
    匡华,侯玉霞,储晓刚,胥传来.气相色谱-质谱法同时测定大豆中14种苯氧羧酸类除草剂[J].分析化学,2006,34(12):1733-1736.
    Takayasu T, Hayashi T, Ishida Y, Nosaka M, Mizunuma S, Miyashita T, Kawaguchi M, Kimura A ,Kondo T.A fatal intoxication from ingestion of 2-methyl-4-chlorophen-oxyacetic acid(MCPA)[J].Journal of Analytical Toxicology, 2008, 32(2): 187-191.

    Takayasu T, Hayashi T, Ishida Y, Nosaka M, Mizunuma S, Miyashita T, Kawaguchi M, Kimura A ,Kondo T.A fatal intoxication from ingestion of 2-methyl-4-chlorophen-oxyacetic acid(MCPA)[J].Journal of Analytical Toxicology, 2008, 32(2): 187-191.
    傅得锋,徐豫青. 用五氟苄基溴对五氯酚进行衍生化的方法[J].刑事技术,2002(6):15-16.
    赵守成,董振霖,卫锋,蒋景阳,姜文凤,谢波.甲基化处理气相色谱-质谱法同时检测大米中12 种酸性除草剂[J].质谱学报,2005,26(4):206-210.
    US EPA. Method 8151A, Chlorinated herbicides by GC using methylation or pentfluorobenzylation derivatization[S].Revision 1, 1994.

    US EPA. Method 8151A, Chlorinated herbicides by GC using methylation or pentfluorobenzylation derivatization[S].Revision 1, 1994.
    Allan J. The determination of residues of 2,4-D in post-emergence-treated triticale[J].Pesticide Science,1990,30:141-147.

    Allan J. The determination of residues of 2,4-D in post-emergence-treated triticale[J].Pesticide Science,1990,30:141-147.
    张莉,张永涛,桂建业,左海英,李桂香.衍生气相色谱-质谱法测定水中氯代酸性除草剂[J].分析试验室,2010,29(3):19-22.
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