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YANG Zai-ming. The Comparison of Three Sample Pretreatment Methods in Determination of Gallium in Bauxite Ores by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(3): 315-317.
Citation: YANG Zai-ming. The Comparison of Three Sample Pretreatment Methods in Determination of Gallium in Bauxite Ores by Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(3): 315-317.

The Comparison of Three Sample Pretreatment Methods in Determination of Gallium in Bauxite Ores by Inductively Coupled Plasma-Atomic Emission Spectrometry

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  • Received Date: May 08, 2010
  • Revised Date: September 05, 2010
  • The bauxite ores were digested by three different pretreatments as HCl-HNO3-HF-HClO4 mixed acids, HF-HNO3-H2SO4 mixed acids and alkali fusion. The Ga was measured by Inductively Coupled Plasma-Atomic Emission Spectrometry(ICP-AES). The HCl-HNO3-HF-HClO4 mixed acids incompletely dissolved the bauxite ores with a large amount of residues. Due to the Ga reacts with HCl to form GaCl3 which is easy to volatilize from the solution system, the measured Ga concentration is much lower than the certified value. The bauxite ores also were incompletely dissolved by HF-HNO3-H2SO4 mixed acids with lower concentration for Ga. Nevertheless, the bauxite ores were completely digested by alkali fusion with clear solution. The NaCl in solution can protect Ga lossing by volatilization to obtain accurate result. The method of alkali fusion, HCl extraction and measurement by ICP-AES produces high precision and accurate result for Ga with detection limit of 3.21 μg/g and less than 5% RSD (n=11). The obtained result is generally consistent with certified value of both first and second grade national standard reference materials.
  • 岩石矿物分析编写组.岩石矿物分析(第一分册)[M].3版.北京:地质出版社, 1991: 716-717.
    地质矿产部科学技术司实验管理处.岩石和矿石分析规程(第三分册)[S].西安:陕西科学技术出版社,1993: 226-231.
    胡宝珍.罗丹明B萃取光度法测定铝土矿中镓的质量保证[J].冶金分析, 2005, 25(2): 95-96.
    辛仁轩.等离子体发射光谱分析[M].北京:化学工业出版社,2004: 3.
    时晓露,刘洪青,孙月婷,章勇,刘文长.电感耦合等离子体质谱法测定岩石样品中的锆铌铪钽两种预处理方法的比较[J].岩矿测试, 2009, 28(5): 427-430.
    徐瑞银,宋存义.Triton X-100增敏光度法测定铝土矿中的微量钪[J].分析试验室, 2005, 24(2): 35-37.
    胡忠贤,杨兆武,程志中,王学求.黑龙江省中部森林沼泽区超低密度深穿透地球化学调查采样介质的确定[J].物探与化探, 2005, 29(2): 105-107.
    华中师范大学,陕西师范大学,东北师范大学.分析化学(下册)[M].3版.北京:高等教育出版社, 2001: 67-91.
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