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SONG Shu-ling, RAO Zhu. Determination of Chlorothalonil, Propiconazole, Hexaconazole, Azoxystrobin and β-Cypermethrin in Groundwater by Gas Chromatography with Electron Capture Detector[J]. Rock and Mineral Analysis, 2011, 30(2): 174-177.
Citation: SONG Shu-ling, RAO Zhu. Determination of Chlorothalonil, Propiconazole, Hexaconazole, Azoxystrobin and β-Cypermethrin in Groundwater by Gas Chromatography with Electron Capture Detector[J]. Rock and Mineral Analysis, 2011, 30(2): 174-177.
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Determination of Chlorothalonil, Propiconazole, Hexaconazole, Azoxystrobin and β-Cypermethrin in Groundwater by Gas Chromatography with Electron Capture Detector

  • 1.

    National Research Center for Geoanalysis, Beijing 100037, China

  • 2.

    National Research Center for Geoanalysis, Beijing 100037, China

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  • Received Date: April 22, 2010
  • Revised Date: August 30, 2010
    Abstract
  • A Method for the determination of pesticide residues of chlorothalonil, propiconazole, hexaconazole, azoxystrobin, and beta-cypermethrin in groundwater was described in this paper. The sample was extracted by mixture of ethyl acetate and hexane (1∶1, V/V), and after dehydration with anhydrous sodium sulfate, concentration and fixing sample volume to 1.0 mL, the 5 pesticide residues were determined directly by gas chromatography with electron capture detector (GC-μECD). The detection limits of the method for chlorothalonil, propiconazole, hexaconazole, azoxystrobin, and beta-cypermethrin were 0.50 ng/L, 2.0 ng/L, 2.0 ng/L, 2.0 ng/L and 2.0 ng/L, respectively. The recoveries for all the analytes at 2.0 ng/L addition level were above 68.8 % with precision of 14.6 % RSD(n=3). The method has the advantages of high sensitivity and accuracy.
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    • References (10)
  • 安晶晶,刘新刚,董丰收,王旭,郑永权.超高效液相色谱-串联质谱法测定土壤、蔬菜及水果中苯醚甲环唑和丙环唑残留[J].农药,2009,48(7): 506-508.
    王连珠,王登飞,郑俊超,王瑞龙,刘溢娜,梁民,卢声宇.气相色谱-质谱法测定荷兰豆中氟硅唑、丙环唑、苯醚甲环唑残留量[J].理化检验:化学分册,2006,42(12):1025-1031.
    孙洁,薄海波,韩舜愈.果蔬中嘧菌酯残留量的气相色谱分析研究[J].甘肃农业大学学报,2007(2):112-115.
    马庆华,续九如,王贵禧,姚立新,吕兆林.冬枣百菌清、氯氰菊酯和氰戊菊酯残留的研究[J].中国农业通报,2009,25(15):51-54.
    王吉腾,陶万强,张志勇,杨宝东,孙淑玲,王合.梨果实中百菌清的残留降解动态及安全性分析[J].北京农学院学报,2009,29(2):22-26.
    孙福生,董杰.环境水样中百菌清残留的单滴微萃取-反相液相色谱测定[J].分析测试学报,2009,28(7):863-866.
    陈蓓蓓,吴诗剑,周守毅,张欢燕,于臻.气相色谱内标法测定水中百菌清的方法优化[J].环境科学导刊,2009,28(4):101-104.
    李冠华,张占恩.中空纤维膜液相微萃取-气相色谱质谱法测定水中的百菌清[J].分析试验室,2008,27(2):22-25.
    王茜,钟文英,黄山.固相萃取-高效液相色谱法测定水中残留嘧菌酯[J].安徽医药,2009(6):611-612.
    Javier L F, Antonio M D, María L.Determination of azoxystrobin residues in grapes, musts and wines with a multicommuted flow-through optosensor implemented with photochemically induced fluorescence[J].Analytica Chimica Acta,2007,585:185-191.

    Javier L F, Antonio M D, María L.Determination of azoxystrobin residues in grapes, musts and wines with a multicommuted flow-through optosensor implemented with photochemically induced fluorescence[J].Analytica Chimica Acta,2007,585:185-191.
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