• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
Advanced Search
CHEN Wei-ming, LI Qing-xia, ZHANG Fang, HE Xiao-hui, ZHANG Qin. Determination of 7 Polychlorinated Biphenyls in Soil Samples by Accelerated Solvent Extraction-Gas Chromatography/ Gas Chromatography-Mass Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(1): 33-39.
Citation: CHEN Wei-ming, LI Qing-xia, ZHANG Fang, HE Xiao-hui, ZHANG Qin. Determination of 7 Polychlorinated Biphenyls in Soil Samples by Accelerated Solvent Extraction-Gas Chromatography/ Gas Chromatography-Mass Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(1): 33-39.
shu

Determination of 7 Polychlorinated Biphenyls in Soil Samples by Accelerated Solvent Extraction-Gas Chromatography/ Gas Chromatography-Mass Spectrometry

  • 1.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 2.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 3.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 4.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

  • 5.

    Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China

More Information
  • Received Date: March 14, 2010
  • Revised Date: August 02, 2010
    Abstract
  • A method for the determination 7 polychlorinated biphenyls (PCB 28, PCB 52, PCB 101, PCB 118, PCB 138, PCB 153 and PCB 180) in soil samples was developed. Solid samples were pretreated with accelerated solvent extraction and purified with sulfonation combining with Florisil solid phase extraction (SPE) and the concentrations of PCBs in soil samples were quantified by gas chromatograph with electron capture detector (GC-ECD) and further confirmed by gas chromatography-mass spectrometry (GC-MS). The detection limits of method (LMD) for PCBs were 0.15~0.50 μg/kg and the recoveries were 80.06%~100.28% with the precisions of 1.01%~6.28% RSD. The method has been applied to the determination of PCBs in complex matrix soil sample with characters of high efficiency, good purification effect, high precision and accuracy and environment friendly.
    • FullText(HTML)
    • References (21)
  • Ross G. The public health implications of polychlorinated biphenyls (PCBs) in the environment [J].Ecotoxicology and Environmental Safety,2004,59(3):275-291.

    Ross G. The public health implications of polychlorinated biphenyls (PCBs) in the environment [J].Ecotoxicology and Environmental Safety,2004,59(3):275-291.
    Popp P,Kalbitz K,Oppermann G. Application of solid-phase microextraction and gas chromatography with electron-capture and mass spectrometric detection for the determination of hexachlorocyclohexanes in soil solutions [J].Journal of Chromatography A,1994,687(1):133-140.

    Popp P,Kalbitz K,Oppermann G. Application of solid-phase microextraction and gas chromatography with electron-capture and mass spectrometric detection for the determination of hexachlorocyclohexanes in soil solutions [J].Journal of Chromatography A,1994,687(1):133-140.
    Bernhard R, Jean D B. High sensitivity of ortho-substituted polychlorobiphenyls in negative ion mass spectrometry (NCI-MS): A comparison with El-MS and ECD for the determination of regulatory PCBs in soils [J]. Chemosphere,1999,38(7):1517-1532.

    Bernhard R, Jean D B. High sensitivity of ortho-substituted polychlorobiphenyls in negative ion mass spectrometry (NCI-MS): A comparison with El-MS and ECD for the determination of regulatory PCBs in soils [J]. Chemosphere,1999,38(7):1517-1532.
    Sarah J, Rikard W, Lennart M, Erland B. Evaluation of PLE exhaustiveness for the extraction of PCBs from sediments and the influence of sediment characteristics [J].Analytica Chimica Acta,2006,560(1-2):94-102.

    Sarah J, Rikard W, Lennart M, Erland B. Evaluation of PLE exhaustiveness for the extraction of PCBs from sediments and the influence of sediment characteristics [J].Analytica Chimica Acta,2006,560(1-2):94-102.
    Dilip L D, Edward J A, Wang J S . A pilot-plant study for destruction of PCBs in contaminated soils using fluidized bed combustion technology [J]. Journal of Environmental Management,2007,84(3):299-304.

    Dilip L D, Edward J A, Wang J S . A pilot-plant study for destruction of PCBs in contaminated soils using fluidized bed combustion technology [J]. Journal of Environmental Management,2007,84(3):299-304.
    Giuliana B, Giuseppe N, Dominga B, Giuseppe A, Achille P, Tommaso R I C. Polychlorinated biphenyls in contaminated soil samples evaluated by GC-ECD with dual- column and GC-HRMS [J]. Chemosphere,2008,73(1):104-112.

    Giuliana B, Giuseppe N, Dominga B, Giuseppe A, Achille P, Tommaso R I C. Polychlorinated biphenyls in contaminated soil samples evaluated by GC-ECD with dual- column and GC-HRMS [J]. Chemosphere,2008,73(1):104-112.
    Takashi M, Ayato K, Katsuhisa H. Development of supercritical carbon dioxide extraction with a solid phase trap for dioxins in soils and sediments[J]. Chemosphere,2008,70(4):648-655.

    Takashi M, Ayato K, Katsuhisa H. Development of supercritical carbon dioxide extraction with a solid phase trap for dioxins in soils and sediments[J]. Chemosphere,2008,70(4):648-655.
    Kazuyuki O, Masaki T, Sin-ichiro K, Nobuo T, Hideki K, Hisao M, Tadao M, Shinsuke M. Extraction of PCBs and water from river sediment using liquefied dimethyl ether as an extractant [J]. Chemosphere,2010,78(9):1148-1154.

    Kazuyuki O, Masaki T, Sin-ichiro K, Nobuo T, Hideki K, Hisao M, Tadao M, Shinsuke M. Extraction of PCBs and water from river sediment using liquefied dimethyl ether as an extractant [J]. Chemosphere,2010,78(9):1148-1154.
    Ken L, Michael L, Merv F, Maria L. Accelerated solvent extraction (ASE) of environmental organic compounds in soils using a modified supercritical fluid extractor [J]. Journal of Hazardous Materials,2003,102(1):93-104.

    Ken L, Michael L, Merv F, Maria L. Accelerated solvent extraction (ASE) of environmental organic compounds in soils using a modified supercritical fluid extractor [J]. Journal of Hazardous Materials,2003,102(1):93-104.
    Yirgaalem A, Raghavan D. Polychlorinated biphenyl (PCB) recovery from spiked organic matrix using accelerated solvent extraction (ASE) and Soxhlet extraction [J]. Journal of Hazardous Materials,2000,80(1-3):147-157.

    Yirgaalem A, Raghavan D. Polychlorinated biphenyl (PCB) recovery from spiked organic matrix using accelerated solvent extraction (ASE) and Soxhlet extraction [J]. Journal of Hazardous Materials,2000,80(1-3):147-157.
    李琴,黄云,唐琴秀.快速溶剂提取-气相色谱法测定土壤中19种多氯联苯单体[J].环境监测管理与技术,2008,20(6):37-39.
    俞是聃,曾子安,林达.快速溶剂萃取、色质联机法及气相色谱法测定土壤中多氯联苯[J].干旱环境监测,2009,23(1):1-5.
    江奎,汪雨,支辛辛,杨永亮,张玲金.加速溶剂萃取/GC -ECD分析土壤中多氯联苯的研究[J].青岛大学学报:工程技术版,2006,21(1):18-22.
    佟玲,黄园英,张玲金,吴淑琪.气相色谱-质谱法测定土壤中有机氯农药及多氯联苯[J].理化检验:化学分册,2009,45(7):858-861.
    王立,汪正范.色谱分析样品处理[M].北京:化学工业出版社,2001.
    刘文长,陶文靖,程丽亚,余兴,田旻,黄勤,李胜生.超声提取-固相萃取小柱净化-气相色谱法测定土壤中14种有机氯农药[J].岩矿测试,2009,28(6):541-544.
    佟玲,黄园英,张玲金,吴淑琪.土壤中持久性有机污染物分析的前处理方法[J].岩矿测试,2008,27(2):81-86.
    Jasna D, Siu C C, Sylvia H Y C.Analysis of pesticides and PCB congeners in serum by GC/MS with SPE sample cleanup[J].Toxicology Letters,2002,134(1-3):253-258.

    Jasna D, Siu C C, Sylvia H Y C.Analysis of pesticides and PCB congeners in serum by GC/MS with SPE sample cleanup[J].Toxicology Letters,2002,134(1-3):253-258.
    李庆霞,刘亚轩,陈卫明,张勤.微波萃取-气相色谱/气相色谱-质谱法测定土壤中18种有机氯农药[J].岩矿测试,2010,29(2):118-122.
    中国地质调查局.多目标区域地球化学调查规范(1∶250000)[Z].2005.
    US EPA Method 3540C,Sediment Extraction Procedures for PCB Analysis [S]. 2002.

    US EPA Method 3540C,Sediment Extraction Procedures for PCB Analysis [S]. 2002.
    • Related Articles
  • Supplements (0)

Catalog

    Get Citation
    PDF
    XML
    Article views (1678) PDF downloads (1362) Cited by()
    Turn off MathJax
    Article Contents
    ABSTRACT
    References

    Competent Authorities：China Association for Science and Technology

    Sponsored by：Geological Society of China; National Research Center for Geoanalysis

    Address：No. 26 Baiwanzhuang Road, Xicheng District, Beijing 100037, China Email：ykcs_zazhi@163.com Tel：010-68999562

    京公网安备 11010202008159号 京ICP备2022024991号

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return