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ZHANG Zhuo, SHAO Chao-ying, WEN Xiao-hua, HE Zhong-fa. Simultaneous Determination of Calcium and Magnesium in Groundwater Samples by Ion Chromatography[J]. Rock and Mineral Analysis, 2010, 29(5): 621-624.
Citation: ZHANG Zhuo, SHAO Chao-ying, WEN Xiao-hua, HE Zhong-fa. Simultaneous Determination of Calcium and Magnesium in Groundwater Samples by Ion Chromatography[J]. Rock and Mineral Analysis, 2010, 29(5): 621-624.
shu

Simultaneous Determination of Calcium and Magnesium in Groundwater Samples by Ion Chromatography

  • 1.

    Shanghai Supervision and Inspection Center for Resources and Environment, Ministry of Land and Resources, Shanghai 200072, China

  • 2.

    College of Chemistry, Chemical Engineering and Biotechnology, Shanghai 201620, China

  • 3.

    Shanghai Supervision and Inspection Center for Resources and Environment, Ministry of Land and Resources, Shanghai 200072, China

  • 4.

    Shanghai Supervision and Inspection Center for Resources and Environment, Ministry of Land and Resources, Shanghai 200072, China

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  • Received Date: April 28, 2010
  • Revised Date: August 04, 2010
    Abstract
  • A method for simultaneous determination of calcium, magnesium and other alkali metal ions in groundwater samples has been perfected by using ion chromatography with IonPac CS12A separation column and 16.8 mmol/L of HCl as eluent. The detection limits (3σ) of the method were 1.5 μg/L and 0.89 μg/L with linear ranges of 0~500 mg/L and 0~250 mg/L for calcium and magnesium, respectively. The reliability of the method was tested by determination of calcium, magnesium and other alkali metal ions in standard samples. The results were satisfactory with precision of 0.19%~1.89% RSD (n=8). No remarkable matrix effect and interference were observed in analysis of the practical samples with the different dilutions. The method is sensitive, rapid, accurate and suitable for the determination of calcium, magnesium and other alkali metal ions in groundwater samples.
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