• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
Advanced Search
ZHANG Yan, ZHANG Jing-fa, CHEN Yan-mei, MENG Juan, HAN Cui-ying. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2010, 29(5): 491-496.
Citation: ZHANG Yan, ZHANG Jing-fa, CHEN Yan-mei, MENG Juan, HAN Cui-ying. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography with Accelerated Solvent Extraction[J]. Rock and Mineral Analysis, 2010, 29(5): 491-496.
shu

Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Soils by Gas Chromatography with Accelerated Solvent Extraction

  • 1.

    Tianjin Testing and Quality Supervision Center for Geological and Mineral Products, The Ministry of Land and Resources, Tianjin 300191, China

  • 2.

    Tianjin Testing and Quality Supervision Center for Geological and Mineral Products, The Ministry of Land and Resources, Tianjin 300191, China

  • 3.

    Tianjin Testing and Quality Supervision Center for Geological and Mineral Products, The Ministry of Land and Resources, Tianjin 300191, China

  • 4.

    Tianjin Testing and Quality Supervision Center for Geological and Mineral Products, The Ministry of Land and Resources, Tianjin 300191, China

  • 5.

    Tianjin Testing and Quality Supervision Center for Geological and Mineral Products, The Ministry of Land and Resources, Tianjin 300191, China

More Information
  • Received Date: January 20, 2010
  • Revised Date: June 12, 2010
    Abstract
  • The optimum extraction condition was studied for organochlorine pesticides and polychlorinated biphenyls in soils using accelerated solvent extraction (ASE). The sample was extracted with hexane/acetone (1∶ 1, V/V) with extraction temperature of 100℃ and pressure of 10.3 MPa and cleaned up by solid phase extraction with Florisil column, followed by separation on a capillary column. The target organic pollutants were then quantitatively determined by gas chromatography using electron capture detection. The detection limits of the method was 0.69~1.85 ng/g and average recovery was 83.6%~109.0% with precision of 1.11%~5.88% RSD (n=11). The method is simple, efficient, economical and suitable for the analysis of organochlorine pesticides and polychlorinated biphenyls in soil samples.
    • FullText(HTML)
    • References (24)
  • 李国刚,李红莉. 持久性有机污染物在中国的环境监测现状[J].中国环境监测,2004,20(4):53-60.
    徐科峰,李忠,何莼,奚红霞,赵月春.持久性有机污染物(POPs)对人类健康的危害及其治理技术进展[J].四川环境,2003,22(4):29-33.
    李光辉.持久性有机污染物(POPs)对动物健康的危害及其对策[J].乳液科学与技术,2005,5(1):229-231.
    刘志伟.食物中的PCBs及其对健康的损害[J].武汉工业学院学报,2000,4(1):12-13.
    刘静.戴安公司ASE快速溶剂萃取技术——解决化学实验样品前处理的最新技术[J].检验检疫科学,2003,13(2):58.
    申中兰,蔡继宝,高芸.基质固相分散-加速溶剂萃取-气相色谱法测土壤中有机氯农药残留[J].分析化学,2005,33(9):1318-1320.
    佟玲,黄园英,张玲金,吴淑琪.土壤中持久性有机污染物分析的前处理方法[J].岩矿测试,2008,27(2):81-86.
    黄园英,佟玲,张玲金,吴淑琪,汪雨.用ASE提取和GPC净化气相色谱法快速测定土壤中痕量有机氯代化合物[J].生态环境,2008,17(1):184-189.
    江奎,汪雨,支辛辛,杨永亮,张玲金.加速溶剂萃取/GC-ECD分析土壤中多氯联苯的研究[J].青岛大学学报,2006,21(1):18-22.
    张景明,胡冠九,周春宏,穆肃.多氯联苯的气相色谱/质谱/质谱(GC/MS/MS)法测定[J].中国环境监测,2003,19(3):5-8.
    Yang Y, Hofmann T. Aqueous accelerated solvent extraction of native polycyclic aromatichydrocarbons (PAHs) from carbonaceous river floodplain soils[J]. Environmental Pollution,2009,157(10):2604-2609.

    Yang Y, Hofmann T. Aqueous accelerated solvent extraction of native polycyclic aromatichydrocarbons (PAHs) from carbonaceous river floodplain soils[J]. Environmental Pollution,2009,157(10):2604-2609.
    Frost S P, Dean J R, Evans K P, Harradine K, Cary C,Comber M H I. Extraction of hexaconazole from weathered soils: A comparison between Soxhlet extraction, microwave-assited extraction, supercritical fluid extraction and accelerated solvent extraction [J]. Analyst,1997,122:895-898.

    Frost S P, Dean J R, Evans K P, Harradine K, Cary C,Comber M H I. Extraction of hexaconazole from weathered soils: A comparison between Soxhlet extraction, microwave-assited extraction, supercritical fluid extraction and accelerated solvent extraction [J]. Analyst,1997,122:895-898.
    Li K, Landriault M, Fingas M, Llompart M. Accelerated solvent extraction (ASE) of environmental organic compounds in soils using a modified supercritical fluid extractor [J].Journal of Hazardous Materials,2003,102:93-104.

    Li K, Landriault M, Fingas M, Llompart M. Accelerated solvent extraction (ASE) of environmental organic compounds in soils using a modified supercritical fluid extractor [J].Journal of Hazardous Materials,2003,102:93-104.
    Wang W T, Meng B J, Lu X X, Liu Y, Tao S. Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils: A comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques[J]. Analytica Chimica Acta,2007,602:211-222.

    Wang W T, Meng B J, Lu X X, Liu Y, Tao S. Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils: A comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques[J]. Analytica Chimica Acta,2007,602:211-222.
    杨云,张卓珉,李攻科.加速溶剂萃取-气相色谱法测定土壤中的有机磷农药残留[J].色谱,2002,20(5):390-393.
    陆华,俞华明. ASE萃取-SPE净化-气相色谱法测定土壤中有机氯农药[J].环境监测管理与技术,2008,5(20):19-22.
    van der Hoff G R, van Zoonen P. Trace analysis of pesticides by gas chromatography [J].Journal of Chromatography A,1999(843):301-322.

    van der Hoff G R, van Zoonen P. Trace analysis of pesticides by gas chromatography [J].Journal of Chromatography A,1999(843):301-322.
    谢湘云,沈爱斯,叶红雷.固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留[J].环境化学,2006,25(3):347-350.
    李琴,黄云,唐琴秀.快速溶剂提取-气相色谱法测定土壤中19种多氯联苯单体[J].环境监测管理与技术,2008,20(6):37-39.
    朱雪梅,崔艳丽,郭丽青.用加速溶剂提取仪提取污染土壤中的有机氯农药[J].环境科学,2002,23(5):113-116.
    余益军,沈敏,于红霞.沉积物中多氯联苯分析的纯化条件优化研究[J].环境监测管理与技术,2006,18(5):11-14.
    Gan J,Papiernik S K,Koskinen W C,Yates S R. Evaluation of accelerated solvent extraction (ASE) for analysis of pesticide residues in soil [J].Environmental Science and Technology,1999(33):3249-3253.

    Gan J,Papiernik S K,Koskinen W C,Yates S R. Evaluation of accelerated solvent extraction (ASE) for analysis of pesticide residues in soil [J].Environmental Science and Technology,1999(33):3249-3253.
    Abrha Y, Raghavan D. Polychlorinated biphenyl (PCB) recovery from spiked organic matrix using accelerated solvent extraction (ASE) and Soxhlet extraction[J]. Journal of Hazardous Materials,2000(B80):147-157.

    Abrha Y, Raghavan D. Polychlorinated biphenyl (PCB) recovery from spiked organic matrix using accelerated solvent extraction (ASE) and Soxhlet extraction[J]. Journal of Hazardous Materials,2000(B80):147-157.
    Wang P, Zhang Q H, Wang Y W, Wang T, Li X M, Ding L, Jiang G B. Evaluation of Soxhlet extraction, accelerated solvent extraction and microwave-assisted extraction for the determination of polychlorinated biphenyls and polybro-minated diphenyl ethers in soil and fish samples[J]. Analytica Chimica Acta, 2010(663):43-48.

    Wang P, Zhang Q H, Wang Y W, Wang T, Li X M, Ding L, Jiang G B. Evaluation of Soxhlet extraction, accelerated solvent extraction and microwave-assisted extraction for the determination of polychlorinated biphenyls and polybro-minated diphenyl ethers in soil and fish samples[J]. Analytica Chimica Acta, 2010(663):43-48.
    • Related Articles
  • Supplements (0)

Catalog

    Get Citation
    PDF
    XML
    Article views (1783) PDF downloads (1470) Cited by()
    Turn off MathJax
    Article Contents
    ABSTRACT
    References

    Competent Authorities：China Association for Science and Technology

    Sponsored by：Geological Society of China; National Research Center for Geoanalysis

    Address：No. 26 Baiwanzhuang Road, Xicheng District, Beijing 100037, China Email：ykcs_zazhi@163.com Tel：010-68999562

    京公网安备 11010202008159号 京ICP备2022024991号

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return