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SONG Shu-ling, RAO Zhu, ZHAO Wei, LI Song. Problems and Solutions in the Determination of Organochlorine Pesticides in Geological Survey Samples[J]. Rock and Mineral Analysis, 2010, 29(3): 271-276.
Citation: SONG Shu-ling, RAO Zhu, ZHAO Wei, LI Song. Problems and Solutions in the Determination of Organochlorine Pesticides in Geological Survey Samples[J]. Rock and Mineral Analysis, 2010, 29(3): 271-276.
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Problems and Solutions in the Determination of Organochlorine Pesticides in Geological Survey Samples

  • 1.

    National Research Center for Geoanalysis, Beijing 100037, China

  • 2.

    National Research Center for Geoanalysis, Beijing 100037, China

  • 3.

    National Research Center for Geoanalysis, Beijing 100037, China

  • 4.

    National Research Center for Geoanalysis, Beijing 100037, China

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  • Received Date: September 29, 2009
  • Revised Date: January 26, 2010
    Abstract
  • Nine organochlorine pesticides(HCB, α-HCH, β-HCH, γ-HCH, δ-HCH, p,p'-DDE, p,p'-DDD, o,p'-DDT and p,p'-DDT)in water and soil samples are the priority pollutants to be determined in geological survey project. There are some analytical problems from complex sample matrix and some special properties of these pollutants when gas chromatography with electron capture detector was used. Based on the experiences in analysis of thousands of survey samples, how to diagnose and solve the problems were discussed from following four aspects:1) the relationship between solvent and analyte response, 2) sample matrix effect, 3) sample pretreatment, 4) instrument measurement. These experiences will help analysts to solve the analytical problems and obtain reliable analytical data.
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    • References (21)
  • Bordajandi L R, Ramos1 J J, Sanz J, González M J, Ramos L.Comprehensive two-dimensional gas chromatography in the screening of persistent organohalogenated pollutants in environmental samples [J].Journal of Chromatography A,2008,1186:312-324.

    Bordajandi L R, Ramos1 J J, Sanz J, González M J, Ramos L.Comprehensive two-dimensional gas chromatography in the screening of persistent organohalogenated pollutants in environmental samples [J].Journal of Chromatography A,2008,1186:312-324.
    Lourencetti C, Navickiene S, Ribeiro M L, Santiago M. Determination of organochlorine pesticides and polychlori-nated biphenyls residues in municipal solid waste compost by gas chromatography with electron capture detection [J]. Chromatographia,2004,59:769-773.

    Lourencetti C, Navickiene S, Ribeiro M L, Santiago M. Determination of organochlorine pesticides and polychlori-nated biphenyls residues in municipal solid waste compost by gas chromatography with electron capture detection [J]. Chromatographia,2004,59:769-773.
    Wang W T, Meng B J, Lu X X, Liu Y, Tao S. Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils:A comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques[J].Analytica Chimica Acta,2007,602:211-222.

    Wang W T, Meng B J, Lu X X, Liu Y, Tao S. Extraction of polycyclic aromatic hydrocarbons and organochlorine pesticides from soils:A comparison between Soxhlet extraction, microwave-assisted extraction and accelerated solvent extraction techniques[J].Analytica Chimica Acta,2007,602:211-222.
    饶竹,李松,吴淑琪,黄毅,王苏明,宋淑玲,谢原利,贾静,田芹. 地质调查中有机物分析方法研究及应用[J]. 地球学报,2009,30 (3):291-300.
    US EPA Method 8081A.Organochlorine pesticides by gas chromatography[S].

    US EPA Method 8081A.Organochlorine pesticides by gas chromatography[S].
    US EPA Method 8270C. Semivolatile organic compounds by gas chromatography/mass spectrometry (GC/MS)[S].

    US EPA Method 8270C. Semivolatile organic compounds by gas chromatography/mass spectrometry (GC/MS)[S].
    Schenck F J, Lehotay S J. Does further clean-up reduce the matrix enhancement effect in gas chromatographic analysis of pesticide residues in food? [J].Journal of Chromatography A,2000,868:51-61.

    Schenck F J, Lehotay S J. Does further clean-up reduce the matrix enhancement effect in gas chromatographic analysis of pesticide residues in food? [J].Journal of Chromatography A,2000,868:51-61.
    李松,饶竹,宋淑玲.全国地下水调查中12种半挥发性必测组分的测定[J].岩矿测试,2008,27(2):91-94.
    Matovská K, Lehotay S J. Evaluation of common organic solvents for gas chromatographic analysis and stability of multiclass pesticide residues [J].Journal of Chromatography A,2004,1040:259-272.

    Matovská K, Lehotay S J. Evaluation of common organic solvents for gas chromatographic analysis and stability of multiclass pesticide residues [J].Journal of Chromatography A,2004,1040:259-272.
    Benoit F M, Williams D T. Determination of hexachloro-cyclopentadiene at the nanogram per liter level in drinking water [J].Bulletin of Environment Contamination and Toxicology,1981,27(3):303-308.

    Benoit F M, Williams D T. Determination of hexachloro-cyclopentadiene at the nanogram per liter level in drinking water [J].Bulletin of Environment Contamination and Toxicology,1981,27(3):303-308.
    Anastassiades M, Matovsk K, Lehotay S J. Evaluation of analyte protectants to improve gas chromatographic analysis of pesticides [J].Journal of Chromatography A,2003,1015:163-184.

    Anastassiades M, Matovsk K, Lehotay S J. Evaluation of analyte protectants to improve gas chromatographic analysis of pesticides [J].Journal of Chromatography A,2003,1015:163-184.
    宋淑玲,饶竹,胡蔻蔻.进样溶剂极性和汽化室处理方法对有机氯农药灵敏度的影响[J].岩矿测试,2009,28(1):21-24.
    Erney D R, Gillespie A M, Gilvydis D M, Polle C F. Explanation of the matrix-induced chromatographic response enhancement of organophosphorus pesticides during open tubular column gas chromatography with splitless or hot column injection and flame photometric detection [J].Journal of Chromatographia,638:57-63.

    Erney D R, Gillespie A M, Gilvydis D M, Polle C F. Explanation of the matrix-induced chromatographic response enhancement of organophosphorus pesticides during open tubular column gas chromatography with splitless or hot column injection and flame photometric detection [J].Journal of Chromatographia,638:57-63.
    Hajlov J, Holadov K, Kocourek V, Poustka J, Godula M, Cuhra P, Kempn M. Matrix-induced effects: A critical point in the gas chromatographic analysis of pesticide residues [J].Journal of Chromatography A,1998,800(2):283-295.

    Hajlov J, Holadov K, Kocourek V, Poustka J, Godula M, Cuhra P, Kempn M. Matrix-induced effects: A critical point in the gas chromatographic analysis of pesticide residues [J].Journal of Chromatography A,1998,800(2):283-295.
    Torres M E H, Gonzdlez F J E, Cuadros-Rodrlguez L, Lopez E A, Vidal J L M. Assessment of matrix effects in gas chromatography electron capture pesticide-residue analysis[J].Chromatographia,2003,57:657-664.

    Torres M E H, Gonzdlez F J E, Cuadros-Rodrlguez L, Lopez E A, Vidal J L M. Assessment of matrix effects in gas chromatography electron capture pesticide-residue analysis[J].Chromatographia,2003,57:657-664.
    Schenck F J, Lehotay S J, Victor Vega. Comparison of solid-phase extraction sorbents for cleanup in pesticide residue analysis of fresh fruits and vegetables [J].Journal of Separation Science,2002,25:883-890.

    Schenck F J, Lehotay S J, Victor Vega. Comparison of solid-phase extraction sorbents for cleanup in pesticide residue analysis of fresh fruits and vegetables [J].Journal of Separation Science,2002,25:883-890.
    Stuber M, Reemtsma T. Evaluation of three calibration methods to compensate matrix effects in environmental analysis with LC-ESI-MS [J].Analytical and Bioanalytical Chemistry,2004,378:910-916.

    Stuber M, Reemtsma T. Evaluation of three calibration methods to compensate matrix effects in environmental analysis with LC-ESI-MS [J].Analytical and Bioanalytical Chemistry,2004,378:910-916.
    Bester K, Bordin G, Rodriguez A, Schimmel H, Pauwels J, VanVyncht G. How to overcome matrix effects in the determination of pesticides in fruit by HPLC-ESI-MS-MS [J].Freseniu's Journal of Analy-tical Chemistry,2001,371:550-555.

    Bester K, Bordin G, Rodriguez A, Schimmel H, Pauwels J, VanVyncht G. How to overcome matrix effects in the determination of pesticides in fruit by HPLC-ESI-MS-MS [J].Freseniu's Journal of Analy-tical Chemistry,2001,371:550-555.
    Frenich A G, Martínez Vidal J L, Fernndez Moreno J L, Romero-Gonzlez R. Compensation for matrix effects in gas chromatography tandem mass spectrometry using a single point standard addition [J].Journal of Chromatography A,2009,1216 (23):4798-4808.

    Frenich A G, Martínez Vidal J L, Fernndez Moreno J L, Romero-Gonzlez R. Compensation for matrix effects in gas chromatography tandem mass spectrometry using a single point standard addition [J].Journal of Chromatography A,2009,1216 (23):4798-4808.
    Schantz M M, Parris R M, Kurz J, Ballschmiter K, Wise S A. Comparison of methods for the gas-chromatographic determination of PCB congeners and chlorinated pesticides in marine reference materials [J].Freseniu's Journal of Analytical Chemstry,1993,346:766-778.

    Schantz M M, Parris R M, Kurz J, Ballschmiter K, Wise S A. Comparison of methods for the gas-chromatographic determination of PCB congeners and chlorinated pesticides in marine reference materials [J].Freseniu's Journal of Analytical Chemstry,1993,346:766-778.
    Huang S P, Huang S D. Determination of organochlo-rine pesticides in water using solvent cooling assisted dynamic hollow-fiber-supported headspace liquid-phase microextraction [J].Journal of Chromatography A,2007,1176:19-25.

    Huang S P, Huang S D. Determination of organochlo-rine pesticides in water using solvent cooling assisted dynamic hollow-fiber-supported headspace liquid-phase microextraction [J].Journal of Chromatography A,2007,1176:19-25.
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