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lei Wu, jiangping Zeng, yibo Liu, liangying Wu, lijuan Zhang, shuang Hao, jiasong Wang. Determination of Rare Earth Elements in Fluorite Samples by Open Boric Acid Dissolution and Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2014, 33(1): 20-24.
Citation: lei Wu, jiangping Zeng, yibo Liu, liangying Wu, lijuan Zhang, shuang Hao, jiasong Wang. Determination of Rare Earth Elements in Fluorite Samples by Open Boric Acid Dissolution and Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2014, 33(1): 20-24.

Determination of Rare Earth Elements in Fluorite Samples by Open Boric Acid Dissolution and Inductively Coupled Plasma-Mass Spectrometry

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  • Received Date: April 02, 2013
  • Accepted Date: July 17, 2013
  • Published Date: December 31, 2013
  • The research of rare earth elements (REEs) in fluorite has very important significance for determining the source of ore-forming materials, the nature of ore-forming fluid and genesis. The determination of REEs in fluorite can be solved by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) with sodium peroxide fusion, but the sample handling process is complex; sodium peroxide is difficult to purify and matrix interferences derive from high salinity solution, making it unsuitable for processing large numbers of samples. Nitric acid and hydrofluoric acid, which are used for the conventional method, do not react with calcium fluoride, which can be dissolved in sulfuric acid and boric acid. To this end, a method for the determination of 15 rare earth elements in fluorite by ICP-MS has been developed. The fluorite samples were decomposed with boric acid solution (media with 10% H2SO4 and 25% HCl) and hydrofluoric acid in PTFE beakers, and then dissolved with nitric acid. Two internal standards of 103Rh and 185Re were selected to compensate the drift of analytical signals and correct matrix effects by ICP-MS. Compared with the traditional sodium peroxide alkali fusion method, this method adopted the reagents of high purity which can reduce the background effectively. The detection limits were 0.002-0.016 μg/g, which is lower than that by sodium peroxide fusion (0.006-0.058 μg/g), and the precisions were 0.7%-2.7%. The results of this method were consistent with the results by sodium peroxide fusion. The new established method was is simple and had has a low detection limit for processing large numbers of fluorite samples.
  • 袁俊宏.我国萤石资源开发利用情况[J].化工新型材料,2005,33(6): 55-56,75. http://www.cnki.com.cn/Article/CJFDTOTAL-HGXC200506019.htm
    王怀宇.世界萤石(氟石)生产消费及国际贸易[J].中国非金属矿工业导刊,2009(6): 54-58. http://epub.cnki.net/kns/detail/detail.aspx?QueryID=0&CurRec=1&recid=&FileName=LGFK200906018&DbName=CJFD2009&DbCode=CJFQ&pr=
    魏金凤,段香芝,许东利,曾小兰.萤石化学成分分析方法探讨[J].非金属矿,2000,23(2): 17,37. http://www.cnki.com.cn/Article/CJFDTOTAL-FJSK200002006.htm
    王蕾,何红蓼,李冰.碱熔沉淀-等离子体质谱法测定地质样品中的多元素[J].岩矿测试,2003,22(2): 86-92. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20030225&flag=1
    李艳玲,熊采华,黄慧萍,陶德刚,方金东.基体分离-电感耦合等离子体质谱测定重晶石中超痕量稀土元素[J].岩矿测试,2005,24(2): 87-92. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20050225&flag=1
    周国兴,刘玺祥,崔德松.碱熔ICP-MS法测定岩石样品中稀土等28种金属元素[J].质谱学报,2010,31(2): 120-124. http://epub.cnki.net/kns/detail/detail.aspx?QueryID=4&CurRec=1&recid=&FileName=ZPXB201002014&DbName=CJFD2010&DbCode=CJFQ&pr=
    黄一帆,林文业,黄文琦,龙智翔.ICP-MS法测定土壤中十五种稀土元素[J].广东微量元素科学,2008,15(11): 46-49. doi: 10.3969/j.issn.1006-446X.2008.11.011
    陈永欣,黎香荣,韦新红,吕泽厄,谢毓群,蔡维专.微波消解-电感耦合等离子体质谱法测定土壤和沉积物中痕量稀土元素[J].岩矿测试,2011,30(5): 560-565. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20110507&flag=1
    黄凤妹.微波消解-电感耦合等离子体质谱法检测土壤中16种稀土元素[J].中国无机分析化学,2012,2(1): 43-46. http://epub.cnki.net/kns/detail/detail.aspx?QueryID=12&CurRec=1&recid=&FileName=WJFX201201011&DbName=CJFD2012&DbCode=CJFQ&pr=
    何红蓼,李冰,韩丽荣,孙德忠,王淑贤,李松.封闭压力酸溶ICP-MS法分析地质样品中47个元素的评价[J].分析试验室,2002,21(5): 8-12. http://epub.cnki.net/kns/detail/detail.aspx?QueryID=16&CurRec=1&recid=&FileName=FXSY200205003&DbName=CJFD2002&DbCode=CJFQ&pr=
    张保科,温宏利,王蕾,马生凤,巩爱华.封闭压力酸溶-盐酸提取-电感耦合等离子体质谱法测定地质样品中的多元素[J].岩矿测试,2011,30(6): 737-744. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20110615&flag=1
    刘晔,第五春荣,柳小明,袁洪林.密闭高压高温溶样ICP-MS测定56种国家地质标准物质中的36种痕量元素——对部分元素参考值修正和定值的探讨[J].岩矿测试,2013,32(2): 221-228. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20130207&flag=1
    王君玉,吴葆存,李志伟,韩敏,钟莅湘.敞口酸溶-电感耦合等离子体质谱法同时测定地质样品中45个元素[J].岩矿测试,2011,30(4): 440-445. http://www.ykcs.ac.cn/ykcs/ch/reader/view_abstract.aspx?file_no=20110409&flag=1
    岩石矿物分析编委会.岩石矿物分析(第四版 第二分册)[M].北京: 地质出版社,2011: 349-350.
    陈福强,何光涛,李其英.地质样品中微-痕量稀土元素ICP-MS测定[J].广州化工,2011,39(14): 115-117. doi: 10.3969/j.issn.1001-9677.2011.14.042
    Smirnova E V, Fedorova I N, Sandimirova G P, Petrov L L, Balbekina N G, Lozhkin V I. Determination of rare earth elements in black shales by inductively coupled plasma mass spectrometry [J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 2003,58(2): 329-340. doi: 10.1016/S0584-8547(02)00152-0
    王初丹,侯明.电感耦合等离子体质谱法测定地质样品中的稀土、钍元素[J].桂林理工大学学报,2011,31(3): 454-456. http://www.cnki.com.cn/Article/CJFDTOTAL-GLGX201103025.htm
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