Hui XIA, Yong-hua ZHANG, Jing-wen LI, Hui-ling YANG, Qian LIANG, Hua-yun HAN. An Improved Method for Determination of Trace Silver in Geochemical Exploration Samples by Graphite Furnace Atomic Absorption Spectrometry[J]. Rock and Mineral Analysis, 2013, 32(1): 48-52.
Citation: Hui XIA, Yong-hua ZHANG, Jing-wen LI, Hui-ling YANG, Qian LIANG, Hua-yun HAN. An Improved Method for Determination of Trace Silver in Geochemical Exploration Samples by Graphite Furnace Atomic Absorption Spectrometry[J]. Rock and Mineral Analysis, 2013, 32(1): 48-52.

An Improved Method for Determination of Trace Silver in Geochemical Exploration Samples by Graphite Furnace Atomic Absorption Spectrometry

More Information
  • Received Date: March 27, 2012
  • Accepted Date: July 05, 2012
  • Published Date: January 31, 2013
  • The chemical procedure of the HCl-HNO3-HF-HClO4 acids system on the electric heating plate is usually used to determine trace Ag in geochemical exploration samples using the Graphite Furnace Atomic Absorption Spectrometry (GFASS) method. Ir and Pt are usually used as the matrix modifiers. However, the thiourea serving as the medium probably leads to a large amount of precipitation with Cu, which interferes with the measurement results. Also, this dissolution method is time consuming during the analysis process and costly. In this paper it is reported that sample in water bath is dissolved by 50% aqua regia. The 50 g/L thiourea matrix modifier was added as the solution, avoiding the precipitation with Cu. The detection limit was 0.01 μg/g with good accuracy and precision. The qualified rates of internal and external examination were in agreement with the standard values. This new method simplifies the processing steps, saving time and cost, and is suitable for batch samples analyses. Furthermore, the dissolved solution of the samples was applied to determine As, Hg, Bi, Sb and other elements by the hydride generation method.
  • 张志龙.有色地质分析规程[M].北京:中国有色金属工业总公司地质局,1992: 41-49.
    叶家瑜,江宝林.区域地球化学勘查样品分析方法[M].北京:地质出版社,2004: 123,352.
    刘红毅,罗大芳,鲍爱华.GFAAS 法测定地质样品中痕量银[J].云南地质,2011(3): 348-352. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD201103026.htm
    蔡述伟,张飞,谢恩平,黄洁.石墨炉原子吸收法测定地球化学样品中痕量银[J].资源调查与环境,2008,29(4): 257-260. http://www.cnki.com.cn/Article/CJFDTOTAL-WJFX201403013.htm
    黄仁忠.硫脲介质-石墨炉原子吸收光谱法测定化探样品中微量银[J].岩矿测试,2008,27(3): 237 -238. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200803025.htm
    陈立华.原子吸收法测定矿石中银的几种溶矿方法比较[J].有色矿业,2010,26(6): 51-53. http://www.cnki.com.cn/Article/CJFDTOTAL-YSKY201006020.htm
    李建.钴和硝酸镁作为通用基体改进剂的研究[J].理化检测: 化学分册,1997,33(4): 160-163. http://www.cnki.com.cn/Article/CJFDTOTAL-LHJH199704003.htm
    李维,余林成.石墨炉原子化光谱法连续测定饮水中6种金属含量[J].中国卫生检验杂志,2011,21(8): 2094-2095. http://www.cnki.com.cn/Article/CJFDTOTAL-ZWJZ201108107.htm
    牛占海,林焰,和督虎.石墨炉原子吸收法测定化探样品中银和镉[J].冶金分析,2001,21(6): 61-63. http://www.cnki.com.cn/Article/CJFDTOTAL-YJFX200106023.htm
    王新华.以吡咯啶二硫代氨基甲酸铵为基体改进剂的水中银的石墨炉原子吸收测定法[J].环境与健康杂志,2010,27(10): 895-897. http://www.cnki.com.cn/Article/CJFDTOTAL-HJYJ201010020.htm
  • Cited by

    Periodical cited type(5)

    1. 林梵宇,尹希杰,刘建鑫,孙延鑫. 原位高分辨微区元素分布特征检测技术的应用进展. 分析测试技术与仪器. 2023(03): 245-260 .
    2. 黄威,胡邦琦,姜学钧,路晶芳,侯方辉,崔汝勇,李攀峰. 九州-帕劳海脊13°20′N海山铁锰结壳生长过程中Si、Al、Ca的含量变化及对碎屑物质供给的指示. 海洋地质与第四纪地质. 2023(05): 26-35 .
    3. 靳梦琪,李艳广,王鹏,汪双双,黎卫亮. 榍石LA-ICP-MS U-Pb定年中元素分馏的影响及校正研究. 岩矿测试. 2020(02): 274-284 . 本站查看
    4. 胡志中,王坤阳,晏雄,杨波,杜谷. 锆石环氧树脂靶表面形貌特征及对LA-ICP-MS分析影响研究. 岩矿测试. 2020(06): 804-815 . 本站查看
    5. 周文喜,王华建,付勇,叶云涛,王晓梅,苏劲,王富良,葛枝华,梁厚鹏,魏帅超. 基于LA-ICP-MS多元素成像技术的早寒武世磷结核成因研究. 岩矿测试. 2017(02): 97-106 . 本站查看

    Other cited types(3)

Catalog

    Article views (1121) PDF downloads (11) Cited by(8)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return