Citation: | WANG Qiao-yun. The International Database for Certified Reference Materials (COMAR)[J]. Rock and Mineral Analysis, 2014, 33(2): 155-167. |
Certified reference materials (CRMs) are standard materials with certified quantity values,playing important roles in development and assessment of analytical methods, qualitative and quantitative analysis, mineral exploration, arbitration inspection, quality supervision and inspection. The Code d′Indexation des Matériaux de Référence (COMAR), founded in the 1980s, is now the largest international database for CRMs. It contains over 10200 CRMs provided by 274 institutions from 25 member countries so as to integrate superior resources. The CRMs′ quantity, classification and development variation, as well as the current research situation of CRMs in member countries such as the European Union, America, China, Japan and Australia are presented in detail. Countries like the United Kingdom, the United States, France, and Germany developed the CRMs research early, and kept ranking international top with high research level. Asian countries like China and Japan started CRMs research late, but developed fast, and now become the top two CRMs providers in COMAR with the respective amount of CRMs up to 1194 and 1456 by August 2013. Since the establishment of COMAR, CRMs in three traditional application fields including industries, non-ferrous, and physical properties have been a large proportion of the total quantity of CRMs in COMAR, which is up to 50%. Among them, the field of industries had the largest quantity of CRMs, accounting for 19%. While the fields of organics-biology and clinic had the least share of CRMs, accounting for only 7% and 3%, respectively. Along with increasing social demand, the fields of biology and medicine, together with quality of life have become the hotspots of current CRMs′ development. This article also highlights that, instead of the traditional fields of ferrous, non-ferrous and physical properties, the development focus of CRMs research will turn to the fields of food safety, environmental protection, climate change, clinical medicine, pharmaceutical industry, and bio-energy in the future. Accordingly, the preparation, characterization, and uncertainty assessment of CRMs will face new technical challenges.
[1] |
ISO Guide 30-1992,Terms and Definitions Used in Connection with Reference Materials[S].Geneva: International Organization for Standardization for Standardization.
|
[2] |
JCGM 200-2012,International Vocabulary of Metrology-Basic and General Concepts and Associated Terms (VIM).3rd edition[S].
|
[3] |
Emons H, Fajgelj A, van der Veen A M H, Watters R.New definitions on reference materials[J].Accreditation and Quality Assurance, 2006, 10(10):576-578. doi: 10.1007/s00769-006-0089-9
|
[4] |
Emons H.The 'RM family'-Identification of all of its members[J].Accreditation and Quality Assurance, 2006, 10(12):690-691. doi: 10.1007/s00769-005-0046-z
|
[5] |
Wenclawiak B W, Koch M, Hadjicosts E.Quality Assurance in Analytical Chemistry[M].Verlag Berlin Heidelberg, 2010:289-302.
|
[6] |
Venelinov T, Sahuquillo A.Optimizing the uses and the costs of reference materials in analytical laboratories[J].TrAC Trends in Analytical Chemistry, 2006, 25(5):528-533. doi: 10.1016/j.trac.2006.02.006
|
[7] |
NIST.National Institute of Standards and Technology of the United States.Standard reference materials[DB/OL].https://www-s.nist.gov/srmors/.
|
[8] |
Joint Research Centre, Institute for Reference Materials and Measurements (JRC-IRMM).IRMM reference materials[DB/OL].http://irmm.jrc.ec.europa.eu/Pages/rmcatalogue.aspx.
|
[9] |
LGC.Laboratory of the Government Chemist of the United Kingdom.Analytical reference materials, standards and high purity solvents[DB/OL].http://www.lgcstandards.com/epages/LGC.sf/en_GB /?ObjectPath=/Shops/LGC/Categories/AboutLGCStandards.
|
[10] |
国家标准物质资源共享平台.国家质量监督检验检疫总局/中国计量科学研究院[DB/OL].http://www.ncrm.org.cn/.
|
[11] |
RMinfo.Reference materials total information service of Japan[DB/OL].http://www.rminfo.nite.go.jp/.
|
[12] |
Jochum K P, Nohl U, Herwig K, Lammel E, Stoll, B, Hofmann A W.GeoReM: A new geochemical database for reference materials and isotopic standards[J].Geostandards and Geoanalytical Research, 2005, 29(3):333-338. doi: 10.1111/ggr.2005.29.issue-3
|
[13] |
Jochum K P, Nohl U.Reference materials in geochem-istry and environmental research and the GeoReM database[J].Chemical Geology, 2008, 253(1-2):50-53. doi: 10.1016/j.chemgeo.2008.04.002
|
[14] |
GeoReM, geological and environmental reference mater-ials[DB/OL].http://georem.mpch-mainz.gwdg.de/.
|
[15] |
Jochum K P, 王晓红.地球化学与环境样品分析标准物质和GeoReM数据库[J].岩矿测试, 2009,28(4):311-315. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200904002.htm
|
[16] |
IAEA reference materials[DB/OL].http://nucleus.iaea.org/rpst/ReferenceProducts/About/index.htm.
|
[17] |
Klich H, Pradel R.Overview about biological and envir-onmental certified reference materials in the database COMAR[J].Fresenius Journal of Analytical Chemistry, 1995, 352(1-2):23-27. doi: 10.1007/BF00322289
|
[18] |
Pradel R, Steiger T, Klich H.Availability of reference materials: COMAR the database for certified reference materials[J].Accreditation and Quality Assurance, 2003, 8(7-8):317-318. doi: 10.1007/s00769-002-0562-z
|
[19] |
Steiger T, Pradel R.COMAR2-The international data-base for certified reference materials[J].Analytical and Bioanalytical Chemistry, 2004, 378(5):1145-1146. doi: 10.1007/s00216-003-2281-7
|
[20] |
Steiger T, Pradel R.Update on COMAR: The interna-tional database for certified reference materials[J].Accreditation and Quality Assurance, 2007, 12(5):265-268. doi: 10.1007/s00769-006-0234-5
|
[21] |
COMAR.International database for certified reference materials[DB/OL].http://www.comar.bam.de/en/.
|
[22] |
Van R R, Chapman M D, Ferreira F, Vieths S, Bryan D, Cromwell O, Villalba M, Durham S R, Becker W M, Aalbers M, André C, Barber D, Bahima A C, Custovic A, Didierlaurent A, Dolman C, Dorpema J W, Felice G D, Eberhardt F, Caldas E F, Rivas M F, Fiebig H, Focke M, F tisch K, Gadermaier G, Das R G, Mancebo E G, Himly M, Kinaciyan T, Knulst A C, Kroon A M, Lepp U, Marco F M, Mari A, Moingeon P, Monsalve R, Neubauer A, Notten S, Ooievaar-de Heer P, Pauli G, Pini C, Purohit A, Quiralte J, Rak S, Raulf-Heimsoth M, Moncin M M S M, Simpson B, Tsay A, Vailes L, Wallner M, Weber B.EU Forum: The CREATE Project: Development of certified reference materials for allergenic products and validation of methods for their quantification[J].Allergy, 2008, 63:310-326. doi: 10.1111/j.1398-9995.2007.01612.x
|
[23] |
Sander L C, Sharpless K E, Satterfield M B, Ihara T, Phinney K W, Yen J H, Wise S A, Gay M L, Lam J W, McCooeye M, Gardner G, Fraser C, Sturgeon R, Roman M.Determination of ephedrine alkaloids in dietary supplement standard reference materials[J].Analytical Chemistry, 2005, 77(10):3101-3112. doi: 10.1021/ac0484530
|
[24] |
Barker P E, Wagner P D, Stein S E, Bunk D M, Srivastava S, Omenn G S.Standards for plasma and serum proteomics in early cancer detection: A needs assessment report from the national institute of standards and technology-national cancer institute standards, methods, assays, reagents and technologies workshop, august 18-19, 2005[J].Clinical Chemistry, 2006, 52(9):1669-1674. doi: 10.1373/clinchem.2006.067249
|
[25] |
Kunioka M, Ninomiya F, Funabashi M.Biodegradation of poly (lactic acid) powders proposed as the reference test materials for the international standard of biodegradation evaluation methods[J].Polymer Degradation and Stability, 2006, 91(9):1919-1928. doi: 10.1016/j.polymdegradstab.2006.03.003
|
[26] |
Quan C, Su F H, Wang H F, Li H M. Development of anabolic-androgenic steroids purity certified reference materials for anti-doping[J].Steroids, 2011, 76(14):1527-1534. doi: 10.1016/j.steroids.2011.09.001
|
[27] |
苏福海,全灿,王海峰,李红梅.美雄酮甲醇溶液标准物质的定值及不确定度评定[J].化学通报,2011, 74(1):67-71. http://www.cnki.com.cn/Article/CJFDTOTAL-HXTB201101011.htm
|
[28] |
苏福海,全灿,王海峰, 李红梅.睾酮甲醇溶液标准物质的定值及不确定度评定[J].分析测试学报,2010, 29(11):1211-1215. http://www.cnki.com.cn/Article/CJFDTOTAL-TEST201011024.htm
|
[29] |
Millar R G.Matrix reference materials-provision in Australia[J].Accreditation and Quality Assurance, 1999, 4(8):371-374. doi: 10.1007/s007690050387
|
[30] |
Munton E, Liu F H, Murby E J, Hibbert D B.Certification of steroid carbon isotope ratios in a freeze-dried human urine reference material[J].Drug Testing and Analysis, 2012, 4(12):928-933. doi: 10.1002/dta.v4.12
|
[31] |
Sloth J J, Larsen E H, Julshamn K.Survey of inorganic arsenic in marine animals and marine certified reference materials by anion exchange high-performance liquid chromatography inductively coupled plasma mass spectrometry[J].Journal of Agricultural and Food Chemistry, 2005, 53(15):6011-6018. doi: 10.1021/jf047950e
|
[32] |
Zhang L, Liu F L, Jia Y K, Zhang X Y.New Chinese national reference materials for hydrogen and oxygen isotopes in water[J].Geostandards and Geoanalytical Research, 2013, 37(2):189-195. doi: 10.1111/j.1751-908X.2012.00196.x
|
[33] |
王毅民, 王晓红, 高玉淑,樊兴涛.中国与世界铂族元素地球化学标准物质评介[J].地质论评, 2010, 56(2):261-268. http://www.cnki.com.cn/Article/CJFDTOTAL-DZLP201002013.htm
|
[34] |
Zhu Y B, Narukawa T, Inagaki K, Kuroiwa T, Chiba K.Development of a Certified Reference Material (NMIJ CRM 7505-a) for the determination of trace elements in tea leaves[J].Analytical Sciences, 2011, 27(11):1149-1155. doi: 10.2116/analsci.27.1149
|
[35] |
Ulberth F.Certified reference materials for inorganic and organic contaminants in environmental matrices[J].Analytical and Bioanalytical Chemistry, 2006, 386(4):1121-1136. doi: 10.1007/s00216-006-0660-6
|
[36] |
Yoshinaga J, Nakama A, Morita M, Edmonds J S.Fish otolith reference material for quality assurance of chemical analyses[J].Marine Chemistry,2000,69(1-2):91-97. doi: 10.1016/S0304-4203(99)00098-5
|
[37] |
Bamford H A, Bezabeh D Z, Schantz M M, Wise S A, Baker J E.Determination and comparison of nitrated-polycyclic aromatic hydrocarbons measured in air and diesel particulate reference materials[J].Chemosphere, 2003, 50(5):575-587. doi: 10.1016/S0045-6535(02)00667-7
|
[38] |
van Leeuwen S P J.New certified and candidate certified reference materials for the analysis of PCBs, PCDD/Fs, OCPs and BFRs in the environment and food[J].TrAC Trends in Analytical Chemistry, 2006, 25(4):397-409. doi: 10.1016/j.trac.2006.01.011
|
[39] |
卢宪波,陈吉平, 王淑秋,邹黎黎,田玉增,倪余文,苏凡.贻贝中有机氯农药和多氯联苯标准物质的研制及同位素稀释高分辨质谱法定值[J].色谱, 2012, 30(9):915-921. http://www.cnki.com.cn/Article/CJFDTOTAL-SPZZ201209011.htm
|
[40] |
杨方,余孔捷,李耀平,储晓刚,张峰,陈国南.用于农、兽药残留分析的基体标准物质研究进展[J].化学分析计量, 2009, 18(3):82-85. http://www.cnki.com.cn/Article/CJFDTOTAL-HXFJ200903079.htm
|
[41] |
Otake T, Yarita T, Aoyagi Y, Kuroda Y, Numata M, Iwata H, Watai M, Mitsuda H, Fujikawa T, Ota H. Development of apple certified reference material for quantification of organophosphorus and pyrethroid pesticides[J].Food Chemistry, 2013, 138(2-3):1243-1249. doi: 10.1016/j.foodchem.2012.11.125
|
[42] |
Armishaw P, Millar R.A natural matrix (pureed tomato) candidate reference materialcontaining residue concentrations of pesticide chemicals[J].Fresenius Journal of Analytical Chemistry, 2001, 370(2-3):291-296. doi: 10.1007/s002160100779
|
[43] |
Hanari N, Itoh N, Ishikawa K, Iwasawa R, Aoyagi Y, Yarita T, Numata M.Certified calibration solution reference material for the determination of perfluorooctane sulfonate from the National Metrology Institute of Japan (NMIJ)[J].International Journal of Environmental Analytical Chemistry, 2013, 93(6):692-705. doi: 10.1080/03067319.2012.684048
|
[44] |
Sharpless K E, Thomas J B, Christopher S J, Greenberg R R, Sander L C, Schantz M M, Welch M J, Wise S A.Standard reference materials for foods and dietary supplements[J].Analytical and Bioanalytical Chemistry, 2007, 389(1):171-178. doi: 10.1007/s00216-007-1315-y
|
[45] |
Narukawa T, Inagaki K, Zhu Y B, Kuroiwa T, Narushima I, Chiba K, Hioki A.Preparation and certification of Hijiki reference material, NMIJ CRM 7405-a, from the edible marine algae hijiki (Hizikia fusiforme)[J].Analytical and Bioanalytical Chemistry, 2012, 402(4):1713-1722. doi: 10.1007/s00216-011-5584-0
|
[46] |
洪涛,刘媛.新版国际标准物质数据库(COMAR)的进展及应用[J].中国计量, 2004, 109(12):65-66. doi: 10.3969/j.issn.1006-9364.2004.12.041
|
[47] |
汪斌,卢晓华,孟凡敏.2001年以来我国标准物质发展状况概述[J].中国计量, 2009, 166(9):71-72. http://www.cnki.com.cn/Article/CJFDTOTAL-JILA200909035.htm
|
[48] |
王浩堃. 建立国家标准物质信息系统及其与COMAR的国际多边合作[J].现代计量测试,1994(5):37-42. http://www.cnki.com.cn/Article/CJFDTOTAL-XDJL405.008.htm
|
[49] |
万志平. 从国际标准物质信息库看中国的标准物质及其发展[J].中国计量,2001,68(7):49-50. http://www.cnki.com.cn/Article/CJFDTOTAL-JILA200107045.htm
|
[50] |
BAM.The federal institute for materials research and testing of Germany reference materials[DB/OL].http://www.bam.de/en/fachthemen/referenzmaterialien/.
|
[51] |
Vogl J.Characterisation of reference materials by isotope dilution mass spectrometry[J].Journal of Analytical Atomic Spectrometry, 2007, 22(5), 475-492. doi: 10.1039/b614612k
|
[52] |
韩卓珍.基于标准物质数据库探讨我国标准物质的发展现状及趋势[J].化学分析计量,2009,18(4):4-8. http://www.cnki.com.cn/Article/CJFDTOTAL-HXFJ200904003.htm
|
[53] |
Wolf W R, Goldschmidt R J.Selenomethionine contents of NIST wheat reference materials[J].Analytical and Bioanalytical Chemistry, 2004, 378(5):1175-1181. doi: 10.1007/s00216-003-2393-0
|
[54] |
卢晓华,李红梅,郭敬.标准物质领域总体发展趋势[J].中国计量, 2010, 176(7):75-76. http://www.cnki.com.cn/Article/CJFDTOTAL-JILA201007043.htm
|
[55] |
Orji N G, Dixson R G, Martinez A, Bunday B D, Allgair J A, Vorburger H V.Progress on implementation of a reference measurement system based on a critical-dimension atomic force microscope[J].Journal of Micro/Nanolithography, MEMS, and MOEMS, 2007, 6(2):023002-1~023002-10.doi: 10.1117/1.2728742.
|
[56] |
全国化工标准物质委员会.分析测试质量保证[M].沈阳:辽宁大学出版社, 2004.
|
[57] |
王亚平,袁建,许春雪.2010年北京标准物质国际研讨会综述[J].岩矿测试, 2011, 30(4):514-520. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS201104033.htm
|
[58] |
张庆合,卢晓华,阚莹,李红梅.化学测量相关领域标准物质现状与趋势[J].化学试剂, 2013, 35(10):865-870. http://www.cnki.com.cn/Article/CJFDTOTAL-HXSJ201310002.htm
|
[59] |
任玲玲,卢晓华,李红梅,王海.纳米计量领域中标准物质调查分析[J].中国计量, 2007, (7):71-73. http://www.cnki.com.cn/Article/CJFDTOTAL-JILA200907050.htm
|
[60] |
金秉慧.地质标准物质十年回顾[J]. 岩矿测试, 2003, 22(3):188-200. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200303007.htm
|
[61] |
王毅民,王晓红,高玉淑,樊兴涛.中国地质标准物质文献(1980~2010)综述[J].地质通报,2011,30(9):1450-1461. http://www.cnki.com.cn/Article/CJFDTOTAL-ZQYD201109015.htm
|
[62] |
Imai H, Tago S, Yamauchi Y.The present situation of Japanese certified reference materials registered in the COMAR database[J].Accreditation and Quality Assurance, 1997, 2(3):115-119. doi: 10.1007/s007690050115
|
[63] |
Mackay L G, Kazlauskas R.The importance of reference materials in doping-control analysis[J].Analytical and Bioanalytical Chemistry, 2011, 401(2): 483-492. doi: 10.1007/s00216-011-5049-5
|
[64] |
NMI.National Measurement Institute of Australian gover-nment.Chemical reference materials[DB/OL].http://www.measurement.gov.au/Services/Pages/ChemicalReferenceMaterials.aspx .
|