Determination of Major Elements in Stream Sediments and Soils by X-ray Fluorescence Spectrometry Using Pressed-superfine Powder Pellets

Li-juan ZHANG; Yi-bo LIU; Xiao-li LI; Tie-min XU

Rock and Mineral Analysis > 2014 > 33(4): 517-522.

Li-juan ZHANG, Yi-bo LIU, Xiao-li LI, Tie-min XU. Determination of Major Elements in Stream Sediments and Soils by X-ray Fluorescence Spectrometry Using Pressed-superfine Powder Pellets[J]. Rock and Mineral Analysis, 2014, 33(4): 517-522.

Citation:

PDF (1611 KB)

Determination of Major Elements in Stream Sediments and Soils by X-ray Fluorescence Spectrometry Using Pressed-superfine Powder Pellets

Tianjin Center of Geological Survey, China Geological Survey, Tianjin 300170, China

More Information

Received Date: May 25, 2013
Revised Date: January 03, 2014
Accepted Date: April 01, 2014
Published Date: June 30, 2014

Abstract

ABSTRACT

The powder pellet compression method for X-ray Fluorescence analysis is an ideal environmentally friendly sample preparation technique with the added advantages of being simple and having high efficiency. However, due to the impact of particle effects and mineral effects, its measurement error is within about 5%, which hinders the application of this technology in the detection of major elements. Powder pellet technology is mainly used in the determination of trace elements as well as the analysis field with less precision. In this study, the stream sediment and soil reference material were crushed to an average particle size about 4-5 μm within a few minutes by ultra-high-speed planetary pressure prototype. The method of ultra-fine pressed powder pellet sample to determine SiO₂, Al₂O₃, Fe₂O₃, CaO, MgO and other major elements was established by using X-ray Fluorescence Spectrometry. Measurement precision (RSD) of the method for most of the major elements is less than 2%, and detection limits are 0.003%-0.021%, which is an improvement on the melting method detection limit (0.006%-0.081%), especially for small atomic sodium with four times improvement on the detection limit. The development of this ultra-fine powder compression method for stream sediment and soil, minimizes the impact of the particle size effect by crushing the sample into several microns. X-ray Diffraction analysis demonstrates that the mineral composition of river sediments and soil preparation is dominated by quartz. Therefore, the mineral composition is simple with negligible mineral effect. Measured data with added LOI normalized processing shows that normalized measurements for each element is consistent with the standard value. The accuracy of the method is a significant over the conventional pellet sampling method.
- stream sediment,
- soil,
- ultrafine powder pellet,
- X-ray Fluorescence Spectrometry

FullText(HTML)

References (26)

References

卓尚军.X射线荧光光谱分析[J].分析试验室,2009,28(7):112-122. http://www.cnki.com.cn/Article/CJFDTOTAL-FXSY200104034.htm

Bertin E P.Principles and Practice of X-ray Spectrometric Analysis (Second Edition) [M].New York: Plenum Press,1975:397-429.

特希昂R,克莱特F,著.高新华,译.X射线荧光定量分析原理[M].北京:冶金部钢铁研究总院,1982:280-302.

张勤,李国会,樊守忠.X射线荧光光谱法测定土壤和水系沉积物等样品中碳、氮、氟、氯、硫、溴等42种主次和痕量元素[J].分析试验室,2008,27(11):51-57. doi: 10.3969/j.issn.1000-0720.2008.11.014

徐海,刘琦,王龙山.X射线荧光光谱法测定土壤样品中碳氮硫氯等31种组分[J].岩矿测试,2007,26(6):490-492. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200706013.htm

刘磊夫,张孟星,曲淑凡.岩石、土壤中23种主次痕量元素的XRF测定[J].现代科学仪器,2008(2):75-77. http://www.cnki.com.cn/Article/CJFDTOTAL-XDYQ200802026.htm

孙芹.熔融法X 射线荧光光谱测定岩石主成分含量[J].化学分析计量,2012,2(3):49-51. http://www.cnki.com.cn/Article/CJFDTOTAL-HXFJ201202016.htm

殷勇. X射线荧光分析在区域地球化学勘查样品分析中的应用[J].中国测试技术,2008,34(6):89-91. http://www.cnki.com.cn/Article/CJFDTOTAL-SYCS200806027.htm

张勤,樊守忠,潘宴山,李国会,李小莉.Minipal 4便携式能量色散X射线荧光光谱仪在勘查地球化学中的应用[J].岩矿测试,2007,26(5):377-380. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200705006.htm

Longerich H P.Analysis of pressed pellets of geological samples using wavelength-dispersive X-ray fluorescence spectrometry[J].X-Ray Spectrometry, 1995, 24:123-126. doi: 10.1002/(ISSN)1097-4539

徐婷婷,张波,张红.X射线荧光光谱法同曲线测定海洋沉积物和陆地地化样品中的29个主次痕量元素[J].海洋地质动态,2007, 23(2):31-33. http://www.cnki.com.cn/Article/CJFDTOTAL-HYDT200702008.htm

徐婷婷,夏宁,张波.熔片制样-X射线荧光光谱法测定海洋沉积物样品中主次量组分[J].岩矿测试,2008,27(1):74-76. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200801021.htm

Xia N, Zhang Q, Yao D, Li G H.Geochemical analysis of marine sediments using fused glass disc by X-ray fluorescence spectrometry[J].Chinese Journal of Oceanology and Limnology, 2008, 26(4):475-479. doi: 10.1007/s00343-008-0475-8

李小莉,张勤.粉末压片-X射线荧光光谱法测定土壤、水系沉积物和岩石样品中15中稀土元素[J].冶金分析,2013,33(7):35-40. http://www.cnki.com.cn/Article/CJFDTOTAL-YJFX201307007.htm

郑荣华,刘建坤.粉末压片-X射线荧光光谱法测定矿石中钨、锡[J].理化检验(化学分册),2013,49(1):66-68. http://www.cnki.com.cn/Article/CJFDTOTAL-LHJH201301023.htm

赵合琴,郑先君,魏丽芳,魏明宝.X射线荧光光谱分析中样品制备方法评述[J].河南化工,2006, 23(10):8-11. doi: 10.3969/j.issn.1003-3467.2006.10.003

王祎亚,詹秀春,樊兴涛,温宏利,李迎春,许祖银,殷绍泉.粉末压片-X射线荧光光谱法测定地质样品中痕量硫的矿物效应佐证实验及其应用[J].冶金分析,2010,30(1):7-11. http://www.cnki.com.cn/Article/CJFDTOTAL-YJFX201001001.htm

刘尚华,陶光仪,吉昂.X射线荧光光谱分析中的粉末压片制样法[J].光谱实验室,1998,15(6):9-15. http://www.cnki.com.cn/Article/CJFDTOTAL-GPSS806.002.htm

王毅民,王晓红,高玉淑.地球科学中的现代分析技术地球科学进展[J].地球科学进展,2003,18(3):476-482. http://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ200303022.htm

吴淑琪,王晓红,屈文俊.南非"Geoanalysis 2009"——第七届国际地质与环境材料分析大会[J].岩矿测试, 2009,28(6):600-601. http://www.cnki.com.cn/Article/CJFDTOTAL-YKCS200906023.htm

王晓红,何红蓼,王毅民,孙德忠,樊兴涛,高玉淑,温宏利,夏月莲.超细样品的地质分析应用[J].分析测试学报,2010,29(6):578-583. http://www.cnki.com.cn/Article/CJFDTOTAL-TEST201006011.htm

王晓红,高玉淑,王毅民.超细地质标准物质及其应用[J].自然科学进展,2006,16(3):309-315. http://www.cnki.com.cn/Article/CJFDTOTAL-ZKJZ200603011.htm

National Institute of Standards & Technology.Certificate of Analysis Standard Reference Materials 2703-Sediment for Solid Sampling (Small Sample) Analytical Techniques[S].2005:1-9.

Wang X H, Wang Y M, Gao Y S, Huang Y Y, Wang Z Y, Shi X F.Preparation of five China sea and continental shelf sediment reference materials (MSCS-1~5) with ultra-fine particle size distributions[J]. Geostandards and Geoanalytical Research, 2009, 33(3):357-368. doi: 10.1111/ggr.2009.33.issue-3

王毅民,高玉淑,王晓红,黄永样,王振宇,石学法.中国海大陆架沉积物超细标准物质系列研制[J].分析化学,2009,37(11):1700-1705. doi: 10.3321/j.issn:0253-3820.2009.11.028

侯运丰,刘雨.气流粉碎技术的发展[J].中国非金属矿工业导刊,2007,63(5):39-42. http://cdmd.cnki.com.cn/Article/CDMD-10674-2002101957.htm

[1]	WANG Di. Corrected Method for Interference of Iron on P₂O₅ during Complete Silicate Analysis in Uranium-producing Ore[J]. Rock and Mineral Analysis, 2021, 40(5): 783-792. DOI: 10.15898/j.cnki.11-2131/td.202007170104
[2]	ZHANG Long, CHEN Zhen-yu, TIAN Ze-jin, HUANG Guo-long. EPMA Study on Characteristics of Uranium Minerals in Uranium-bearing and Uranium-barren Granites in Northern Guangdong and Its Prospecting Significance[J]. Rock and Mineral Analysis, 2016, 35(3): 310-319. DOI: 10.15898/j.cnki.11-2131/td.2016.03.015
[3]	Le ZENG, Zheng-hui CHEN, Feng-yue SUN, Jia-huan WANG, Ying-chao SUN, Zhen-yu CHEN. U-Pb Dating of Zircons and Ore-bearing Potential of Zhulanbu Intrusions in the Southern Jiangxi Province[J]. Rock and Mineral Analysis, 2016, 35(2): 199-207. DOI: 10.15898/j.cnki.11-2131/td.2016.02.013
[4]	Liu-chao ZHU, Tong-xing WANG, Yong-gang ZHAO, Chang-kun XU, Li-fei ZHAO, Xiao-yan JIANG, Xing-hong ZHAO. Determination of Nine Impurities in Uranium Products by Inductively Coupled Plasma-Mass Spectrometry after UTEVA Extraction Chromatographic Separation[J]. Rock and Mineral Analysis, 2015, 34(4): 414-419. DOI: 10.15898/j.cnki.11-2131/td.2015.04.006
[5]	YU Yang, CHEN Zhen-yu, CHEN Zheng-hui, HOU Ke-jun, ZHAO Zheng, XU Jian-xiang, ZHANG Jia-jing, ZENG Zai-lin. Zircon U-Pb Dating and Ore-bearing Properties Evaluation of Yanshanian Shuitou Pluton in Southern Jiangxi Province[J]. Rock and Mineral Analysis, 2012, 31(4): 736-744.
[6]	LIU Shan-bao, LI Peng, CHEN Zhen-yu, CHEN Zheng-hui, HOU Ke-jun, ZHAO Zheng, WANG Cheng-hui. Wantian Granite, Yudu of Southern Jiangxi: Zircon U-Pb Dating and Its Revelation[J]. Rock and Mineral Analysis, 2012, 31(4): 724-729.
[7]	HUANG Fan, HOU Ke-jun, CHEN Zheng-hui, CHEN Zhen-yu, ZHAO Zheng. Zircon U-Pb Age, Tectonic Setting and Ore Potentiality of the Dafuzu Uranium-bearing Rock Mass in the Southeastern Jiangxi Province[J]. Rock and Mineral Analysis, 2012, 31(3): 518-524.
[8]	MA Qiang, FENG Zhi-gang, SUN Jing, XIE Er-ju, LI Xiao-jun. Study on Chemical Speciation of Uranium in Samples from in-situ Leaching Sandstone-type Uranium Deposit in Xinjiang[J]. Rock and Mineral Analysis, 2012, 31(3): 501-506.
[9]	WANG Jun, WANG Di, ZHAO Jian-xin. Experimental Study on the Relationship between Uranium(Ⅵ) and Total Uranium in Uranium Ores and Uranium-bearing Rocks[J]. Rock and Mineral Analysis, 2010, 29(3): 316-318.
[10]	Measurement of the Cation Exchange Capacity of Vermiculite by Ammonium Chloride-Ethanol Method[J]. Rock and Mineral Analysis, 2008, 27(3): 204-206.

Supplements (0)

Cited By

Cited by

Periodical cited type(3)

1.	安燕飞，陈凯鑫，王亚乔，程硕，黄楗，何舒扬，王胜建. 天然焦内炭微球显微光学特征、成因及其意义. 煤田地质与勘探. 2024(05): 25-36 .
2.	于志金，晋策，汤旭，张志鹏，文虎. 岩浆侵入与接触距离对煤低温氧化过程热效应的影响. 煤炭学报. 2024(12): 4873-4882 .
3.	卢杰林，傅雪海，康俊强，张宝鑫，程鸣. 不同变质作用类型的煤级梯度对比. 煤炭科学技术. 2024(12): 180-192 .

Other cited types(0)

Get Citation

PDF

XML

Article views (3012) PDF downloads (35) Cited by(3)

Turn off MathJax

Article Contents

ABSTRACT

References

Determination of Major Elements in Stream Sediments and Soils by X-ray Fluorescence Spectrometry Using Pressed-superfine Powder Pellets