Citation: | CHEN Feifei,JIN Bin,YANG Mengna,et al. Determination of Trace Ti in High Calcium Carbonate Rocks by ICP-MS[J]. Rock and Mineral Analysis,2024,43(4):558−567. DOI: 10.15898/j.ykcs.202402280023 |
The content of Ti in carbonate rocks is generally lower than 3.5mg/g, and most of it is below 1mg/g. X-ray fluorescence spectrometry (XRF), which is commonly used to measure Ti content in silicic rocks (usually more than 0.1%), cannot meet the requirements of accurate measurement of trace Ti in carbonate rocks. This paper reports on the attempts to test Ti in carbonate rock by inductively coupled plasma-mass spectrometry (ICP-MS), discusses and analyzes the interference of 5 test isotopes of Ti (46Ti, 47Ti, 48Ti, 49Ti, 50Ti) in carbonate solution matrix, and determines the suitable test isotope 48Ti. Then the ICP-MS method for the determination of trace Ti in carbonate rock is proposed. According to the method, the concentration of Ti in 5 first-class national standard materials was tested and corrected. The measured values were consistent with the certified values, and the relative standard deviation (RSD,
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