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TANG Qingyu,CHEN Lu,TIAN Shihong,et al. A Study on Memory Effects in Lithium and Boron Isotope Analysis Using MC-ICP-MS[J]. Rock and Mineral Analysis,2024,43(2):201−212. DOI: 10.15898/j.ykcs.202310260167
Citation: TANG Qingyu,CHEN Lu,TIAN Shihong,et al. A Study on Memory Effects in Lithium and Boron Isotope Analysis Using MC-ICP-MS[J]. Rock and Mineral Analysis,2024,43(2):201−212. DOI: 10.15898/j.ykcs.202310260167

A Study on Memory Effects in Lithium and Boron Isotope Analysis Using MC-ICP-MS

  • Lithium (Li) and boron (B) isotopes are excellent tracers in geological processes. In order to study and eliminate the memory effects of lithium and boron element in isotopic measurements using MC-ICP-MS, different background rinsing protocols were designed with reference to previous research. The δ7Li and δ11B values of different types of reference materials were tested to evaluate the long-term reproducibility of the measurements using designated rinsing protocols for at least six months. The results show that using only 0.3% NaCl solution to clean the background for 60s can significantly reduce the lithium background signal and ensure the 7Li background signal is less than 5mV within 24h. The long-term external precision of δ7Li values for Alfa Li, an in-house standard, was 0.13‰ (2SD, n=73). Rinsing solutions, such as NAF and NH3·H2O could not significantly reduce the boron background of the instrument. However, the flexible blank subtracting method was used for precise determination of δ11B values. The long-term external precision of δ11B values for Alfa B was 0.19‰ (2SD, n=60). The average δ7Li and δ11B values of different types of reference materials were tested using these rinsing protocols, and the results were well consistent with reported data, supporting the applicability of the conclusions. The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202310260167.

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