Citation: | LIU Zhenchao,LI Zhixiong,LU Qianshu,et al. Improvement of the Method for Determining Total Nitrogen in Water Quality Using Alkaline Potassium Persulfate Ultraviolet Spectrophotometry[J]. Rock and Mineral Analysis,2024,43(1):114−123. DOI: 10.15898/j.ykcs.202302280028 |
Alkaline potassium persulfate (K2S2O8) ultraviolet (UV) spectrophotometry is the routine method to analyze total nitrogen (TN) in water and is important for studying pollutants in water and the geochemical cycling of TN. However, several analytical conditions can influence the accuracy of the results. (1) The blank, purity, and storage time of K2S2O8. For example, a blank UV of K2S2O8 exceeding 0.030 can lead to a significant underestimation of results. (2) The digestion method of bundling colorimetric tubes in high temperature and high pressure is time-consuming. (3) Improper sample storage conditions can lower measurement results. To improve the accuracy and efficiency of TN measurement in water samples, this study compared the storage times of different K2S2O8, different digestion methods, and sample storage methods. The results show that the domestic premium-grade alkaline K2S2O8 should be stored for <30 days (blank UV<0.03). The insertion digestion method is much more efficient (124°C, 20min). Acidification extends samples’ shelf life from 1 day to 7 days. Therefore, choosing domestic premium-grade K2S2O8 and using the modified insertion method for sample digestion results in lower detection limits, higher digestion efficiency, minimal risk of contamination and misplacement, and improved accuracy of TN measurement in water quality analysis.