A Review of Research Progress on Fractionation Characteristics and Acquisition Methods of Rare Earth Elements in Carbonate Minerals

WANG Yiru; WU Xiaotan; HE Jing; LI Chongying

doi:10.15898/j.cnki.11-2131/td.202204180081

Rock and Mineral Analysis > 2022 > 41(6): 935-946. > DOI: 10.15898/j.cnki.11-2131/td.202204180081

WANG Yiru, WU Xiaotan, HE Jing, LI Chongying. A Review of Research Progress on Fractionation Characteristics and Acquisition Methods of Rare Earth Elements in Carbonate Minerals[J]. Rock and Mineral Analysis, 2022, 41(6): 935-946. DOI: 10.15898/j.cnki.11-2131/td.202204180081

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A Review of Research Progress on Fractionation Characteristics and Acquisition Methods of Rare Earth Elements in Carbonate Minerals

School of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

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Received Date: April 17, 2022
Revised Date: May 29, 2022
Accepted Date: July 28, 2022
Available Online: December 13, 2022

Abstract

HIGHLIGHTS
(1) The fractionation characteristics of rare earth elements in paleo-surface water are affected by pH, salinity, dissolved oxygen and hydrothermal input of the water.

(2) The fractionation characteristics of rare earth elements of carbonate minerals can be used to trace the paleo-environmental information of the water where they precipitated.

(3) Non-carbonate minerals in carbonate rocks can affect the determination of the rare earth elements in carbonate minerals.

(4) An accurate method is absent for the determination of rare earth elements in carbonate minerals in carbonate rocks.

ABSTRACT

BACKGROUND
Authigenic carbonate minerals deposited from paleo-surface water can retain the fractionation characteristics of rare earth elements in water when deposited. The environmental conditions of the water at the time affect these characteristics. Therefore, these characteristics can be used as a reliable indicator for the paleo-environmental information of deposited water.
OBJECTIVES
Based on previous studies, the influence of pH, salinity, dissolved oxygen and hydrothermal input of paleo-surface water on the fractionation characteristics of rare earth elements are reviewed, and the methods of tracing the paleo-environment information and obtaining the characteristics information of rare earth elements in carbonate minerals are summarized.
METHODS
At present, laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and acid dissolution-inductively coupled plasma-mass spectrometry are the mainstream analytical methods used to obtain the fractionation characteristics of rare earth elements in carbonate minerals.
RESULTS
It is rare to find samples that only contain carbonate minerals, so samples are usually carbonate rocks exposed on the earth's surface. However, carbonate rocks have been inevitably mixed with terrigenous minerals (such as clay, quartz, feldspar) and authigenic non-carbonate minerals during their formation, which will disturb the original rare earth elements fractionation characteristics of the carbonate minerals. Unfortunately, neither method mentioned earlier was successful in avoiding this interference.
CONCLUSIONS
The future study on the fractionation characteristics of rare earth elements should first explore the methods to accurately obtain the fractionation characteristics of carbonate minerals in carbonate rocks.

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References (82)

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A Review of Research Progress on Fractionation Characteristics and Acquisition Methods of Rare Earth Elements in Carbonate Minerals

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