Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments

TIAN Qin; TONG Ling; AN Ziyi; XU Chunxue; SUN Huizhong; DIAO Jinling

doi:10.15898/j.cnki.11-2131/td.202110130149

Rock and Mineral Analysis > 2022 > 41(3): 511-520. > DOI: 10.15898/j.cnki.11-2131/td.202110130149

TIAN Qin, TONG Ling, AN Ziyi, XU Chunxue, SUN Huizhong, DIAO Jinling. Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments[J]. Rock and Mineral Analysis, 2022, 41(3): 511-520. DOI: 10.15898/j.cnki.11-2131/td.202110130149

Citation:

PDF (19785 KB)

Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments

TIAN Qin^{1, 2,},
TONG Ling^1, ,,
AN Ziyi^{1, 2},
XU Chunxue^{1, 2},
SUN Huizhong^{1, 2},
DIAO Jinling³

1.
National Research Center for Geoanalysis, Beijing 100037, China
2.
Key Laboratory of Eco-geochemistry, Ministry of Natural Resources, Beijing 100037, China
3.
China Agricultural University, Beijing 100193, China

More Information

Received Date: October 12, 2021
Revised Date: December 07, 2021
Accepted Date: January 27, 2022
Available Online: July 28, 2022

Abstract

HIGHLIGHTS
(1) The certified reference materials of sediments from different stream systems of rivers and lakes in China have been developed. This series of reference materials not only have three kinds of certified values: 16 PAHs, 3 OCPs and 3 PCBs, but also have a wide content range from ng/g to μg/g levels, which meet the needs of different analyses.

(2) Nine laboratories used three analytical methods for collaborative analysis, including high-precision isotope dilution mass spectrometry, which ensured the accuracy of the certified values.

(3) The method of certified values, accuracy and uncertainty have achieved the level of research and development of similar reference materials in the world.

ABSTRACT

BACKGROUND
Polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) have teratogenic, carcinogenic and mutagenic effects, which are priority pollutants. The formulation of pollution investigation and treatment measures depends on accurate analysis and test data, and certified reference materials (CRMs) are an important guarantee for data quality control. However, the existing relevant reference materials cannot meet the actual needs of pollution monitoring in China.
OBJECTIVES
To prepare four CRMs of sediments for analysis of PAHs, OCPs and PCBs, and to meet the needs of environmental monitoring and scientific research for the monitoring of priority pollutants in China.
METHODS
In this study, according to the specifications of certified reference materials (JJF 1006—1994, JJF1343—2012 and JJF 1646—2017), 4 CRMs of PAHs, OCPs and PCBs in different sediments (GBW07352-GBW07355) have been developed for Chinese environmental monitoring and scientific research. In the development process, in order to solve the technical difficulties of the stability of organic compound reference materials, the effects of ⁶⁰Co sterilization and temperature on the stability of organic compounds were investigated. In view of the complex characteristics of the sediment sample matrix, different extraction and purification technologies were adopted to reduce or eliminate the influence of the complex matrix on the extraction solution and reduce the matrix effect of instrument measurement. Nine laboratories' collaborative analysis was carried out by using traditional methods including high performance liquid chromatography (HPLC), gas chromatography-electron capture detector (GC-ECD), gas chromatography-mass spectrometry (GC-MS) and new techniques of gas chromatography-isotope dilution mass spectrometry (GC-IDMS).
RESULTS
The sediment candidates have good homogeneity and stability. The certified values and expanded uncertainty for 16 PAHs, 3 OCPs and 3 PCBs are given, and the concentrations range from 9.0ng/g to 5.7μg/g, which meets the requirements of quality assurance and quality control for analysis of PAHs, OCPs and PCBs.
CONCLUSIONS
This series of reference materials has been approved as a national first-class reference material, numbered from GBW07352 to GBW07355. This series of CRMs can be used in analytical method validation, laboratory quality control, laboratory analysis ability assessment.

FullText(HTML)

References (28)

References

[1]	Yang J, Qadeer A, Liu M, et al. Occurrence, source and partition of PAHs, PCBs and OCPs in the multiphase system of an urban lake, Shanghai[J]. Applied Geochemistry, 2019, 106: 17-25. doi: 10.1016/j.apgeochem.2019.04.023
[2]	张文博, 刘宾绪, 江涛, 等. 环渤海渔港沉积物多环芳烃的污染特征和生态风险评价[J]. 环境化学, 2022, 41(2): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX202202015.htm Zhang W B, Liu B X, Jiang T. et al. Pollution characteristics and ecological risk assessment of polycyclic aromatic hydrocarbons in sediments from fishing ports along the coast of Bohai Sea[J]. Environmental Chemistry, 2022, 41(2): 1-11. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX202202015.htm
[3]	李玉芳, 潘萌, 顾涛, 等. 北京哺乳期女性及婴幼儿多环芳烃暴露风险变化特征[J]. 岩矿测试, 2020, 39(4): 578-586. doi: 10.15898/j.cnki.11-2131/td.201912040167 Li Y F, Pan M, Gu T, et al. Exposure of mother and infants to polycyclic aromatic hydrocarbons during lactation, Beijing[J]. Rock and Mineral Analysis, 2020, 39(4): 578-586. doi: 10.15898/j.cnki.11-2131/td.201912040167
[4]	Hou J, Yin W J, Li P, et al. Joint effect of polycyclic aromatic hydrocarbons and phthalates exposure on telomere length and lung function[J]. Journal of Hazardous Materials, 2020, 386: 121663. doi: 10.1016/j.jhazmat.2019.121663
[5]	Ye X Q, Pan W Y, Li C M, et al. Exposure to polycyclic aromatic hydrocarbons and risk for premature ovarian failure and reproductive hormones imbalance[J]. Journal of Environmental Sciences, 2020, 91: 1-9. doi: 10.1016/j.jes.2019.12.015
[6]	Donat-Vargas C, Åkesson A, Berglund M, et al. Dietary exposure to polychlorinated biphenyls and risk of breast, endometrial and ovarian cancer in a prospective cohort[J]. British Journal of Cancer, 2016, 115: 1113-1121. doi: 10.1038/bjc.2016.282
[7]	Abbassy M A, Khalifa M A, Nassar A M K, et al. Analysis of organochlorine pesticides residues in fish from Edko Lake (North of Egypt) using eco-friendly method and their health implications for humans[J]. Toxicology Research, 2021, 37: 495-503. doi: 10.1007/s43188-020-00085-8
[8]	Yin S J, Sun Y, Yu J H, et al. Prenatal exposure to organochlorine pesticides is associated with increased risk for neural tube defects[J]. Science of the Total Environment, 2021, 770: 145284. doi: 10.1016/j.scitotenv.2021.145284
[9]	赵亚静, 邹立, 牛增元, 等. 液相色谱-高分辨质谱技术在沉积物和颗粒物中有机污染物分析的研究进展[J]. 分析测试学报, 2021, 40(9): 1396-1408. https://www.cnki.com.cn/Article/CJFDTOTAL-TEST202109020.htm Zhao Y J, Zou L, Niu Z Y, et al. Advances in the analysis of organic contaminants in sediments and particulate matters by liquid chromatography-high resolution mass spectrometry[J]. Journal of Instrumental Analysis, 2021, 40(9): 1396-1408. https://www.cnki.com.cn/Article/CJFDTOTAL-TEST202109020.htm
[10]	刘烨, 王玉洁, 汪福顺, 等. 多环芳烃在新安江河流-水库体系表层沉积物中的分布、来源及生态风险评估[J]. 上海大学学报(自然科学版), 2020, 26(1): 113-122. https://www.cnki.com.cn/Article/CJFDTOTAL-SDXZ202001011.htm Liu Y, Wang Y J, Wang F S, et al. Occurrence, sources and ecological risk assessment of polycyclic aromatic hydrocarbons in surface sediments from Xin'anjiang river-reservoir system[J]. Journal of Shanghai University (Natural Science Edition), 2020, 26(1): 113-122. https://www.cnki.com.cn/Article/CJFDTOTAL-SDXZ202001011.htm
[11]	许妍, 陈佳枫, 徐磊, 等. 白洋淀表层沉积物中有机氯农药和全多氯联苯的分布特征及风险评估[J]. 湖泊科学, 2020, 32(3): 654-664. https://www.cnki.com.cn/Article/CJFDTOTAL-FLKX202003006.htm Xu Y, Chen J F, Xu L, et al. Distribution and risk assessment of organochlorine pesticides and polychlori-nated biphenyls in surficial sediments from Lake Baiyangdian[J]. Lake Science, 2020, 32(3): 654-664. https://www.cnki.com.cn/Article/CJFDTOTAL-FLKX202003006.htm
[12]	范晨子, 刘永兵, 赵文博, 等. 云南安宁水系沉积污染物分布特征与风险评价[J]. 岩矿测试, 2021, 40(4): 570-582. doi: 10.15898/j.cnki.11-2131/td.202103080035 Fan C Z, Liu Y B, Zhao W B, et al. Pollution distribution characteristics and ecological risk assessment of heavy metals and polycyclic aromatic hydrocarbons in the river sediments in Anning, Yunnan Province[J]. Rock and Mineral Analysis, 2021, 40(4): 570-582. doi: 10.15898/j.cnki.11-2131/td.202103080035
[13]	Li H X, Jiang W W, Pan Y L, et al. Occurrence and partition of organochlorine pesticides (OCPs) in water, sediment, and organisms from the eastern sea area of Shandong Peninsula, Yellow Sea, China[J]. Marine Pollution Bulletin, 2021, 162: 111906. doi: 10.1016/j.marpolbul.2020.111906
[14]	Wang P, Shang H T, Li H H, et al. PBDEs, PCBs and PCDD/Fs in the sediments from seven major river basins in China: Occurrence, congener profile and spatial tendency[J]. Chemosphere, 2016, 144: 13-20. doi: 10.1016/j.chemosphere.2015.08.045
[15]	雷沛, 潘科, 张洪, 等. 水体沉积物中16种优控PAHs的快速萃取[J]. 环境化学, 2019, 38(3): 494-502. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX201903006.htm Lei P, Pan K, Zhang H, et al. A device for the rapid extraction of 16 priority PAHs in aquatic sediments[J]. Environmental Chemistry, 2019, 38(3): 494-502. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX201903006.htm
[16]	Itoh N, Aoyagi Y, Takatsu A, et al. Certified reference material for quantification of polycyclic aromatic hydrocarbons in sediment from the National Metrology Institute of Japan[J]. Analytical and Bioanalytical Chemistry, 2009, 393: 2039-2049. doi: 10.1007/s00216-009-2675-2
[17]	SRM (1941b) organics in marine sediment[R]. Gaithersburg: National Institute of Standards and Technology (NIST), 2015.
[18]	SRM (1944) certificate of analysis. New York/New Jersey waterway sediment[R]. Gaithersburg: National Institute of Standards and Technology (NIST), 2017.
[19]	Wise S A, Poster D L, Schantz M M, et al. Two new marine sediment standard reference materials (SRMs) for the determination of organic-contaminants[J]. Analytical and Bioanalytical Chemistry, 2004, 378: 1251-1264. doi: 10.1007/s00216-003-2431-y
[20]	Wegener J W M, Cofino W P, Maier E A, et al. The preparation, testing andvertification of two freshwater sediment reference materials for polycyclic aromatic hydrocarbons and polychlorinated biphenyls: BCR CRM535 and CRM536[J]. Trends in Analytical Chemistry, 1999, 18(1): 14-25. doi: 10.1016/S0165-9936(98)00087-9
[21]	Wegener J W M, Maier E A, Kramer G N, et al. The certification of the contents (mass fractions) of polycyclic aromatic hydrocarbons: Pyrene, benz[a]anthracene, benzo[a] pyrene, benzo[e]pyrene, benzo[b]fluoranthene and indeno[1, 2, 3-cd]pyrenein freshwater harbour sediment CRM 535, EUR 17795EN[R]. Commission of the European Communities: Community Bureau of Reference, 1997.
[22]	LGC 6188. Statement of measurement. River sediment-PAHs (Latest Amendment)[R]. Laboratory of the Government Chemist (LGC), 2020.
[23]	Tolosa1 I, Cassi1 R, Huertas D. A new marine sediment certified reference material (CRM) for the determination of persistent organic contaminants: IAEA-459[J]. Environmental Science and Pollution Research, 2019, 26: 7347-7355. doi: 10.1007/s11356-018-1895-4
[24]	田芹, 吴淑琪, 佟玲, 等. 中国典型类型土壤中有机氯农药和多氯联苯成分分析标准物质研制[J]. 岩矿测试, 2015, 34(2): 238-244. doi: 10.15898/j.cnki.11-2131/td.2015.02.015 Tian Q, Wu S Q, Tong L, et al. Preparation of certified reference materials of organochlorine pesticides and polychlorinatedbipenyl in Chinese typical soils[J]. Rock and Mineral Analysis, 2015, 34(2): 238-244. doi: 10.15898/j.cnki.11-2131/td.2015.02.015
[25]	全国标准物质管理委员会. 标准物质目录[M]. 北京: 中国质检出版社, 中国标准出版社, 2017. National Administrative Committee for Certified Reference Materials. List of standard substances[M]. Beijing: Quality Inspection of China Press, Standards Press of China, 2017.
[26]	房丽萍, 吴忠祥, 王伟, 等. 河流沉积物多环芳烃标准样品的制备与定值[J]. 岩矿测试, 2013, 32(5): 767-774. doi: 10.3969/j.issn.0254-5357.2013.05.015 Fang L P, Wu Z X, Wang W, et al. Preparation and certification of river sediment reference material for polycyclic aromatic hydrocarbons[J]. Rock and Mineral Analysis, 2013, 32(5): 767-774. doi: 10.3969/j.issn.0254-5357.2013.05.015
[27]	全国标准物质管理委员会. 标准物质的研制管理与应用[M]. 北京: 中国计量出版社, 2010. National Administrative Committee for Certified Reference Materials. Preparation, management and application of reference materials[M]. Beijing: China Metrology Publishing House, 2010.
[28]	全国标准物质管理委员会. 标准物质定值原则和统计学原理[M]. 北京: 中国质检出版社, 2011. National Administrative Committee for Certified Reference Materials. Reference material general and statistical principles for certification[M]. Beijing: Quality Inspection of China Press, 2011.

Supplements (0)

Cited By

Cited by

Periodical cited type(4)

1.	侯将，肖传晶，姚阔为. 快速检测技术在水环境污染物检测中的应用研究进展. 实验室检测. 2024(07): 30-33 .
2.	高启宇. SPE-UFLC-MS法测定医药废水中8种四环素类抗生素. 化学工程师. 2024(08): 30-34 .
3.	赵静，侯静云，高超，包虹艳. 无机及分析化学实验的综合应用教学研究. 保山学院学报. 2024(05): 103-108 .
4.	王宝丽，张逸君，张宇航，陈艳. 生物炭基材料及其在电化学传感领域的应用. 岩矿测试. 2024(06): 967-981 . 本站查看

Other cited types(2)

Get Citation

PDF

XML

Article views (268) PDF downloads (29) Cited by(6)

Turn off MathJax

Article Contents

ABSTRACT

References

Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments

ABSTRACT

References

Cited by

Periodical cited type(4)

Other cited types(2)

Catalog

Export File

Citation

Format

Content