Determination of Tin, Lead and Zinc in a Tin-Lead-Zinc Deposit in Xianghualing Mining Area, Hunan Province by Inductively Coupled Plasma-Optical Emission Spectrometry with Alkali Fusion

XIAO Xilian; XIA Jinlong; LI Xiaodan; LU Youyue; YANG Xiaoli; YANG Hongmei

doi:10.15898/j.cnki.11-2131/td.202107290087

Rock and Mineral Analysis > 2023 > 42(1): 125-135. > DOI: 10.15898/j.cnki.11-2131/td.202107290087

XIAO Xilian, XIA Jinlong, LI Xiaodan, LU Youyue, YANG Xiaoli, YANG Hongmei. Determination of Tin, Lead and Zinc in a Tin-Lead-Zinc Deposit in Xianghualing Mining Area, Hunan Province by Inductively Coupled Plasma-Optical Emission Spectrometry with Alkali Fusion[J]. Rock and Mineral Analysis, 2023, 42(1): 125-135. DOI: 10.15898/j.cnki.11-2131/td.202107290087

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Determination of Tin, Lead and Zinc in a Tin-Lead-Zinc Deposit in Xianghualing Mining Area, Hunan Province by Inductively Coupled Plasma-Optical Emission Spectrometry with Alkali Fusion

XIAO Xilian^{1, 2,},
XIA Jinlong^{1, 2},
LI Xiaodan²,
LU Youyue^{1, 2},
YANG Xiaoli^{1, 2},
YANG Hongmei^{1, 2}

1.
Research Center for Petrogenesis and Mineralization of Granitoid Rocks, China Geological Survey, Wuhan 430205, China
2.
Wuhan Center of China Geological Survey, China Geological Survey (Central South China Innovation Center for Geosciences), Wuhan 430205, China

More Information

Received Date: July 28, 2021
Revised Date: December 02, 2021
Accepted Date: January 27, 2022
Available Online: December 13, 2022

Abstract

HIGHLIGHTS
(1) The high contents of tin, lead and zinc in samples of a tin-lead-zinc deposit in Xianghualing mining area, Hunan Province, prevent samples from being completely digested by conventional methods. Selecting 4.0g of sodium peroxide as the flux, melting at 750℃ for 20 minutes, extracting with 30mL of boiling water and acidifying with 20mL of hydrochloric acid ensures the complete decomposition of the sample.

(2) The order of the ability of three alkali fluxes to decompose minerals was anhydrous sodium carbonate, sodium hydroxide, and sodium peroxide with increased ability.

(3) The calibration series was prepared with blank alkali melt acidification solution as the medium, so that the calibration series matched the sample matrix and eliminated the influence of matrix interference.

(4) The method is suitable for ore samples of different types with concentrations of tin, lead and zinc greater than 0.1%.

ABSTRACT

BACKGROUND
The Xianghualing mining area in Hunan Province is an important part of the east-west tectonic-magmatic-metallogenic belt in the Nanling area.The ore-forming geological conditions in the mining area are superior, and it is famous for its many types of deposits and complex types of minerals.The tin-lead-zinc deposit in the Xianghualing mining area is a very important polymetallic deposit in the Nanling metallogenic belt.The ore types are mainly cassiterite sulfide tin ore, tin-lead-zinc ore and sulfide lead-zinc ore.Tin, lead and zinc are very important nonferrous metal elements.The abundance and variation characteristics of these three elements can reflect the regional metallogenic conditions, indicate the existence of deposits or mineralization, and are the important basis for studying the metallogenic model, deepening the understanding of the genesis of the deposit, and identifying the metallogenic control factors.Therefore, it is very necessary to accurately determine the content of tin, lead and zinc in the tin, lead and zinc deposits in the Xianghualing mining area, and it is important to study the regional metallogenic conditions The geological characteristics of the deposit, the occurrence state of elements, mineral processing and comprehensive utilization of non-ferrous metal minerals are of great significance.However, the average grades of tin, lead and zinc in the deposit are percentage contents and tin itself is a refractory element.Conventional open acid dissolution or closed acid dissolution in the dissolution of high content of tin, lead and zinc in the ore will have the disadvantages of incomplete digestion and easy precipitation of the solution, resulting in serious low determination results.However, alkali fusion is more capable of decomposing minerals than acid dissolution.As long as the appropriate alkali fusion reagent, temperature and time are optimized, some high content of inorganic elements, even insoluble elements, can be completely decomposed, which is an ideal method of mineral decomposition pretreatment.
OBJECTIVES
To rapidly and accurately determine the concentrations of tin, lead and zinc in high contents of tin, lead and zinc samples of a tin-lead-zinc deposit in the Xianghualing mining area, Hunan Province.
METHODS
Inductively coupled plasma-optical emission spectrometry (ICP-OES) with alkali fusion was used to determine the levels of tin, lead and zinc.The selection of alkali fusion reagent, reagent dosage, alkali fusion temperature and time as well as the plasma excitation conditions, element spectral lines, button background position and other instrumental determination conditions were optimized.The effects of three kinds of fluxes: sodium hydroxide, anhydrous sodium carbonate and sodium peroxide were compared.
RESULTS
The measured value of tin was greatly affected by the alkali flux.Under the flux of sodium hydroxide or anhydrous sodium carbonate, the measured value of tin was low, while the measured value of tin was consistent with the standard value under the flux of sodium peroxide.Based on the comparison of the effects of various fluxes on the analysis results, sodium peroxide was selected as the flux, melting at a constant temperature of 750℃ for 20 minutes, and acidification with 20mL of hydrochloric acid after 30mL of boiling water extraction to ensure the complete decomposition of the sample.The calibration series was prepared with blank alkali melt solution as the medium, so that the calibration series matched the sample matrix and eliminated the influence of matrix interference.The national first-class geochemical reference materials were used for method quality evaluation, and the results showed that the absolute value of the logarithmic difference between the measured value and the certified value of the reference material was less than 0.04.The detection limits of the method for tin, lead and zinc were 13.60μg/g, 36.45μg/g and 53.83μg/g, respectively.The precision of the method was better than 8%.The determination range of the calibration curve was between 0 to 100μg/mL.
CONCLUSIONS
Due to the use of alkali fusion method and blank alkali fusion solution as the standard preparation medium, this method is suitable for the determination of high contents of tin, lead and zinc in cassiterite-sulfide type tin ores, tin-lead-zinc ores, and sulfide type lead-zinc ores, and it has good application prospects.At present, this method has been successfully applied to the analysis of actual samples in the Xianghualing mining area, Hunan Province, with satisfactory results.
- alkali fusion,
- inductively coupled plasma-optical emission spectrometry,
- Xianghualing,
- tin-lead-zinc deposits,
- tin,
- lead,
- zinc

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References (35)

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Determination of Tin, Lead and Zinc in a Tin-Lead-Zinc Deposit in Xianghualing Mining Area, Hunan Province by Inductively Coupled Plasma-Optical Emission Spectrometry with Alkali Fusion

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