Determination of 15 Rare Earth Elements in Hetian Jade by Inductively Coupled Plasma-Mass Spectrometry with High-pressure Closed Digestion

ZHOU An-li; WU Zhi-yuan; NING Hai-long; WANG Dong; YANG Li; LÜ Xin-ming

doi:10.15898/j.cnki.11-2131/td.201907170106

Rock and Mineral Analysis > 2020 > 39(3): 451-458. > DOI: 10.15898/j.cnki.11-2131/td.201907170106

ZHOU An-li, WU Zhi-yuan, NING Hai-long, WANG Dong, YANG Li, LÜ Xin-ming. Determination of 15 Rare Earth Elements in Hetian Jade by Inductively Coupled Plasma-Mass Spectrometry with High-pressure Closed Digestion[J]. Rock and Mineral Analysis, 2020, 39(3): 451-458. DOI: 10.15898/j.cnki.11-2131/td.201907170106

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Determination of 15 Rare Earth Elements in Hetian Jade by Inductively Coupled Plasma-Mass Spectrometry with High-pressure Closed Digestion

1.
College of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China
2.
Alashankou Customs Technology Center, Alashankou 833418, China
3.
Altay Branch of Urumqi Customs Technical Center, Altay 836500, China

More Information

Received Date: July 16, 2019
Revised Date: September 03, 2019
Accepted Date: October 20, 2019
Published Date: April 30, 2020

Abstract

HIGHLIGHTS
(1) Two pretreatment methods were compared to evaluate the dissolution effect of nitric acid-hydrofluoric acid and lithium tetraborate-lithium metaborate alkaline fusion.

(2) The proposed method uses less acid and has higher dissolution efficiency.

(3) The REE pattern of Hetian jade was characterized by light REE enrichment.

ABSTRACT

BACKGROUNDThere are abundant rare earth elements in Hetian jade. The accurate determination of the content of rare earth elements is of great significance for revealing the source of ore-forming materials, the nature of ore-forming fluids and the genesis of the deposit.
OBJECTIVESTo compare the different acid systems in microware digestion and investigate the elimination test of polyatomic interferences, so as to develop a method for the determination of REE in Hetian jade by inductively coupled plasma-mass spectrometry (ICP-MS) with microwave digestion.
METHODSAfter comparing the efficiency of HNO₃-HF acid dissolution and Li₂B₄O₇-LiBO₂ fusion, the Hetian jade samples were digested by HNO₃-HF. Fifteen rare earth elements were determined by ICP-MS. ¹⁰³Rh and ⁴⁹In are used as internal isotopes to complement matrix effect and correct sensitivity drift, in order to reduce matrix effect.
RESULTSThe detection limits of the method were 0.0008-0.0091μg/L, whereas the recoveries were 101.0%-120.0%. The relative standard deviation was 0.55%-1.83%(n=11).
CONCLUSIONSThis method uses less acid and has a low blank value. It is applied to the analysis of Hetian jade in different regions. The distribution pattern of rare earth elements is characterized by right-inclined light rare earth enrichment, which provides constraints on the genesis of the jade deposit.
- Hetian jade,
- Trace elements,
- rare earth elements,
- inductively coupled plasma-mass spectrometry

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References (31)

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Determination of 15 Rare Earth Elements in Hetian Jade by Inductively Coupled Plasma-Mass Spectrometry with High-pressure Closed Digestion

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