A Comparative Study of Four Extractants on the Extraction of Available Selenium in Vegetable and Orchard Soils

XIE Wei; YANG Yao-dong; JIAN Gui-qin; LI Guo-cheng; ZHAO Xin-hua; HOU Jia-yu

doi:10.15898/j.cnki.11-2131/td.201905150063

Rock and Mineral Analysis > 2020 > 39(3): 434-441. > DOI: 10.15898/j.cnki.11-2131/td.201905150063

XIE Wei, YANG Yao-dong, JIAN Gui-qin, LI Guo-cheng, ZHAO Xin-hua, HOU Jia-yu. A Comparative Study of Four Extractants on the Extraction of Available Selenium in Vegetable and Orchard Soils[J]. Rock and Mineral Analysis, 2020, 39(3): 434-441. DOI: 10.15898/j.cnki.11-2131/td.201905150063

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A Comparative Study of Four Extractants on the Extraction of Available Selenium in Vegetable and Orchard Soils

1.
Tianjin Geological and Mineral Testing Center, Tianjin 300191, China
2.
Geological Center of Tianjin Planning and Natural Resources Bureau, Tianjin 300042, China

More Information

Received Date: May 14, 2019
Revised Date: September 29, 2019
Accepted Date: April 15, 2020
Published Date: April 30, 2020

Abstract

HIGHLIGHTS
(1) According to the correlation between available selenium and selenium species, the optimum extractant were determined.

((2) Potassium dihydrogen phosphate was the best extractants of available selenium in vegetable and orchard soils of Tianjin.

((3) The selection basis of effective selenium extractants was diversified.

ABSTRACT

BACKGROUNDAvailable selenium is an important index to evaluate the supply capacity of selenium from soil to plants. However, there is no national standard method to test available selenium in China. The selection of extractants is very important for the accurate determination of available selenium.
OBJECTIVESTo determine the optimum extractant based on the correlation between available selenium and selenium species.
METHODSFour extractants, sodium bicarbonate, potassium dihydrogen phosphate, nitric acid and hydrochloric acid, were selected to extract the available selenium from vegetable and orchard soils in Tianjin. Atomic fluorescence spectrometry was used to determine the content of various forms of selenium, and the minimum, 25 percentile, median, 75 percentile, maximum value of the effective selenium and water-soluble+ion-exchange+carbonate-combined selenium were used for comparative analysis and the difference.
RESULTSThe average content of available selenium extracted from vegetable soils by sodium bicarbonate and potassium dihydrogen phosphate was 0.039mg/kg, which was higher than that of nitric acid and hydrochloric acid. The contents of available selenium extracted from orchard soils by sodium bicarbonate, potassium dihydrogen phosphate, nitric acid and hydrochloric acid decreased in turn. The minimum, 25 percentile, median, 75 percentile, and maximum values of available selenium extracted by potassium dihydrogen phosphate in the two soils were closer to the content of sum of water-soluble, ion-exchange and carbonate combined selenium.
CONCLUSIONSPotassium dihydrogen phosphate with a concentration of 0.1mol/L was the optimum extractant of available Se for vegetable and orchard soils in Tianjin.
- soil,
- selenium,
- available form,
- speciation analysis,
- extractants,
- potassium dihydrogen phosphate,
- atomic fluorescence spectrometry

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References

戴慧敏, 宫传东, 董北, 等.东北平原土壤硒分布特征及影响因素[J].土壤学报, 2015, 52(6):1356-1364. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trxb201506015

Dai H M, Gong C D, Dong B, et al.Distribution of soil selenium in the northeast China plain and its influencing factors[J]. Acta Pedologica Sinica, 2015, 52(6):1356-1364. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trxb201506015

迟凤琴, 徐强, 匡恩俊, 等.黑龙江省土壤硒分布及其影响因素研究[J].土壤学报, 2016, 53(5):1262-1273. http://d.old.wanfangdata.com.cn/Periodical/trxb201605017

Chi F Q, Xu Q, Kuang E J, et al.Distribution of selenium and its influencing factors in soils of Heilongjiang Province, China[J]. Acta Pedologica Sinica, 2016, 53(5):1262-1273. http://d.old.wanfangdata.com.cn/Periodical/trxb201605017

秦冲, 施畅, 万秋月, 等.高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态[J].岩矿测试, 2018, 37(6):664-670. doi: 10.15898/j.cnki.11-2131/td.201803200024

Qin C, Shi C, Wan Q Y, et al.Speciation analysis of inorganic selenium in soil by high performance liquid chromatography-inductively coupled plasma-mass spectrometry[J]. Rock and Mineral Analysis, 2018, 37(6):664-670. doi: 10.15898/j.cnki.11-2131/td.201803200024

曹容浩.福建省龙海市表层土壤硒含量及影响因素研究[J].岩矿测试, 2017, 36(3):282-288. doi: 10.15898/j.cnki.11-2131/td.201606130084

Cao R H.Study on selenium content of surface soils in Longhai, Fujian and its influencing factors[J]. Rock and Mineral Analysis, 2017, 36(3):282-288. doi: 10.15898/j.cnki.11-2131/td.201606130084

李杰, 刘久臣, 汤奇峰, 等.川西高原地区水体中硒含量及分布特征研究[J].岩矿测试, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

Li J, Liu J C, Tang Q F, et al.Study of the contents and distribution of selenium in water samples from the western Sichuan plateau and the incidence of Kaschin beck disease[J]. Rock and Mineral Analysis, 2018, 37(2):183-192. doi: 10.15898/j.cnki.11-2131/td.201709250154

谢薇, 杨耀栋, 侯佳渝.天津某菜地土壤-蔬菜中硒与重金属含量特征及绿色富硒蔬菜筛选[J].环境化学, 2018, 37(12):2790-2799.

Xie W, Yang Y D, Hou J Y.Characteristics of selenium and heavy metals concentrations in soils and vegetables and screening of green selenium-enriched vegetables in a base of Tianjin[J]. Environmental Chemistry, 2018, 37(12):2790-2799.

宋晓珂, 王金贵, 李宗仁, 等.富硒土壤中有效硒浸提剂和浸提条件研究[J].中国农学通报, 2018, 34(3):152-157. http://d.old.wanfangdata.com.cn/Periodical/zgnxtb201803023

Song X K, Wang J G, Li Z R, et al.Extractants and extraction conditions of soil available selenium in selenium-enriched soil[J]. Chinese Agricultural Science Bulletin, 2018, 34(3):152-157. http://d.old.wanfangdata.com.cn/Periodical/zgnxtb201803023

Keskinen R, Ekholm P, Yli-Halla M, et al.Efficiency of different methods in extracting selenium form agricultural soils of Finland[J]. Geoderma, 2009, 153:87-93.

Peng Q, Wang D, Wang M K, et al.Prediction of sele-nium uptake by pak choi in several agricultural soils based on diffusive gradients in thin-films technique and single extraction[J]. Environmental Pollution, 2020, 256:1-10.

赵成义.酸性土壤有效态硒浸提方法的研究[J].干旱环境监测, 1991, 5(1):38-41.

Zhao C Y.Studies on the method of the extracted selenium from the acid soil[J]. Arid Environmental Monitoring, 1991, 5(1):38-41.

李辉勇, 刘鹏, 刘军鸽, 等.酸性水稻土有效硒提取剂的比较研究[J].生态环境, 2003, 12(1):12-14. http://d.old.wanfangdata.com.cn/Periodical/tryhj200301004

Li H Y, Liu P, Liu J G, et al.Comparative studies on available Se extractants for acid paddy soils[J]. Ecology and Environment, 2003, 12(1):12-14. http://d.old.wanfangdata.com.cn/Periodical/tryhj200301004

耿建梅, 王文斌, 罗丹, 等.不同浸提剂对海南稻田土壤有效硒浸提效果比较[J].土壤, 2010, 42(4):624-629. http://d.old.wanfangdata.com.cn/Periodical/tr201004021

Geng J M, Wang W B, Luo D, et al.Comparative studies on effects of several extractants on available selenium of paddy soils in Hainan[J]. Soils, 2010, 42(4):624-629. http://d.old.wanfangdata.com.cn/Periodical/tr201004021

汤志云, 肖灵, 张培新, 等.多目标生态地球化学调查土壤样品中砷硒锑有效态分析方法的商榷[J].岩矿测试, 2004, 23(3):173-178. http://www.ykcs.ac.cn/article/id/ykcs_20040347

Tang Z Y, Xiao L, Zhang P X, et al.Determination of available species of As, Se and Sb in soils by HG-AFS[J]. Rock and Mineral Analysis, 2004, 23(3):173-178. http://www.ykcs.ac.cn/article/id/ykcs_20040347

瞿建国, 徐伯兴, 龚书椿.上海不同地区土壤中硒的形态分布及其有效性研究[J].土壤学报, 1998, 35(3):398-403.

Qu J G, Xu B X, Gong S C.Study on speciation distribution and availability of selenium in different soils of Shanghai[J]. Acta Pedologica Sinica, 1998, 35(3):398-403.

吴雄平, 鲍俊丹, 伊田, 等.石灰性土壤有效硒浸提剂和浸提条件研究[J].农业环境科学学报, 2009, 28(5):931-936. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh200905012

Wu X P, Bao J D, Yi T, te al.Extractants and optimum extracting conditions of soil available selenium in calcareous soil[J]. Journal of Agro-Environment Science, 2009, 28(5):931-936. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh200905012

《岩石矿物分析》编委会.岩石矿物分析(第四版第四分册)[M].北京:地质出版社, 2011:906-908.

The editorial committee of < Rock and mineral analysis>. Rock and mineral analysis (The fourth edition:Vol.Ⅳ)[M]. Beijing:Geological Publishing House, 2011:906-908.

程素敏, 王娟, 张岩, 等.土壤样品中砷的形态分析方法研究[J].中国无机分析化学, 2016, 6(1):17-21. http://d.old.wanfangdata.com.cn/Periodical/zgwjfxhxwz201601005

Cheng S M, Wang J, Zhang Y, et al.Study on speciation analysis of arsenic in soil samples[J]. Chinese Journal of Inorganic Analytical Chemistry, 2016, 6(1):17-21. http://d.old.wanfangdata.com.cn/Periodical/zgwjfxhxwz201601005

王松山.土壤中硒形态和价态及生物有效性研究[D].陕西: 西北农林科技大学, 2012.

Wang S S.Fractionation and speciations of selenium in soil and its bioavailability[D]. Shaanxi: Northwest Agricultural and Forestry University, 2012.

王兆双.土壤有效硒提取方法比较及其生物有效性研究[D].武汉: 华中农业大学, 2014.

Wang Z S.Comparison of soil available selenium extraction methods and its bioavailability[D]. Wuhan: Huazhong Agricultural University, 2014.

黄春雷, 魏迎春, 简中华, 等.浙中典型富硒区土壤硒含量及形态特征[J].地球与环境, 2013, 41(2):155-159. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx201302010

Huang C L, Wei Y C, Jian Z H, et al.Study on selenium contents and combined forms of typical selenium-rich soil in the central part of Zhejiang Province[J]. Earth and Environment, 2013, 41(2):155-159. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx201302010

中国地质科学院地球物理地球化学勘查研究所.标准物质证书集[M]. 2010: 45-49.

Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences.Certificate set of reference materials[M]. 2010: 45-49.

刘军鸽, 刘鹏, 葛旦之, 等.淹水土壤有效硒提取剂的比较研究[J].湖南农业大学学报, 2000, 26(1):5-8. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hunannydx200001002

Liu J G, Liu P, Ge D Z, et al.Comparative studies of available Se extracts in flooding soil[J]. Journal of Hunan Agricultural University, 2000, 26(1):5-8. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hunannydx200001002

汤丽玲, 范辉, 马生明, 等.AB-DTPA通用提取剂法测定土壤地球化学样品元素有效性的可行性研究[J].物探化探计算技术, 2007, 29(增刊):238-242.

Tang L L, Fan H, Ma S M, et al.A feasibility study of determining elements in geochemical soil samples by using general extractant AB-DEPA[J]. Computing Techniques for Geophysical and Geochemical Exploration, 2007, 29(Supplement):238-242.

周越, 吴文良, 孟凡乔, 等.土壤中硒含量、形态及有效性分析[J].农业资源与环境学报, 2014, 31(6):527-532. http://d.old.wanfangdata.com.cn/Periodical/nyhjyfz201406007

Zhou Y, Wu W L, Meng F Q, et al.Review on the content, specification of selenium and its availability in soils[J]. Journal of Agricultural Resources and Environment, 2014, 31(6):527-532. http://d.old.wanfangdata.com.cn/Periodical/nyhjyfz201406007

Dean A M, Donald L S.Selenium speciation of soil/sedi-ment determined with sequential extractions and hydride generation atomic absorption spectrophotometry[J]. Environmental Science & Technology, 1997, 31:133-139.

梁东丽, 彭琴, 崔泽玮, 等.土壤中硒的形态转化及其对有效性的影响研究进展[J].生物技术进展, 2017, 7(5):374-380. http://d.old.wanfangdata.com.cn/Periodical/swjsjz201705005

Liang D L, Peng Q, Cui Z W, et al.Progress on selenium bioavailability and influential factors in soils[J]. Current Biotechnology, 2017, 7(5):374-380. http://d.old.wanfangdata.com.cn/Periodical/swjsjz201705005

梁若玉, 和娇, 史亚娟, 等.典型富硒农业基地土壤硒的生物有效性与剖面分布分析[J].环境化学, 2017, 36(7):1588-1595. http://d.old.wanfangdata.com.cn/Periodical/hjhx201707017

Liang R Y, He J, Shi Y J, et al.Bioavailability and profile distribution of selenium in soils of typical Se-enriched agricultural base[J]. Environmental Chemistry, 2017, 36(7):1588-1595. http://d.old.wanfangdata.com.cn/Periodical/hjhx201707017

王锐, 余涛, 杨忠芳, 等.富硒土壤硒生物有效性及影响因素研究[J].长江流域资源与环境, 2018, 27(7):1648-1654. http://d.old.wanfangdata.com.cn/Periodical/cjlyzyyhj201807024

Wang R, Yu T, Yang Z F, et al.Bioavailability of soil selenium and its influencing factors in selenium-enriched soil[J]. Resources and Environment in the Yangtze Basin, 2018, 27(7):1648-1654. http://d.old.wanfangdata.com.cn/Periodical/cjlyzyyhj201807024

赵妍, 宗良纲, 曹丹, 等.江苏省典型茶园土壤硒分布特性及其有效性研究[J].农业环境科学学报, 2011, 30(12):2467-2474. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh201112012

Zhao Y, Zong L G, Cao D, et al.Distribution and availability of selenium in typical tea garden of Jiangsu Province, China[J]. Journal of Agro-Environment Science, 2011, 30(12):2467-2474. http://d.old.wanfangdata.com.cn/Periodical/nyhjbh201112012

马迅, 宗良纲, 诸旭东, 等.江西丰城生态硒谷土壤硒有效性及其影响因素[J].安全与环境学报, 2017, 17(4):1588-1593. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201704071

Ma X, Zong L G, Zhu X D, et al.Effectiveness and influential factors of soil selenium in selenium valley, Fengcheng, Jiangxi[J]. Journal of Safety and Environment, 2017, 17(4):1588-1593. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201704071

Yu D S, Liang D L, Lei L M, et al.Selenium geochemical distribution in the environment and predicted human daily dietary intake in northeastern Qinghai, China[J]. Environmental Science and Pollution Research, 2015, 22:11224-11235. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=47eabc2cf6a032d9b5693661cfdcb7d8

王松山, 梁东丽, 魏威, 等.基于路径分析的土壤硒形态与土壤性质的关系[J].土壤学报, 2011, 48(4):823-830. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trxb201104019

Wang S S, Liang D L, Wei W, et al.Relationship between soil physic-chemical properties and selenium species based on path analysis[J]. Acta Pedologica Sinica, 2011, 48(4):823-830. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trxb201104019

Malisa E P.The behavior of selenium in geological proce-sses[J]. Environment Geochemistry and Health, 2001, 23:137-158.

姚欢, 宗良纲, 孟蝶, 等.增施磷肥对提高强酸性高硒茶园土壤硒有效性的效果[J].安全与环境学报, 2015, 15(4):287-292. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201504061

Yao H, Zong L G, Meng D, et al.Effect of enhancing availability of selenium by increasing phosphate fertilizer in highly acidic Se-rich soil in tea plantations[J]. Journal of Safety and Environment, 2015, 15(4):287-292. http://d.old.wanfangdata.com.cn/Periodical/aqyhjxb201504061

谢珊妮, 宗良纲, 张琪惠, 等.3种改良剂对强酸性高硒茶园土壤硒有效性调控效果与机理[J].茶叶科学, 2017, 37(3):299-307. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cykx201703010

Xie S N, Zong L G, Zhang Q H, et al.Effects of three amendments on selenium availability of highly acidic and Se-rich soil in tea garden and their relative mechanisms[J]. Journal of Tea Science, 2017, 37(3):299-307. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cykx201703010

赵婉彤.重庆市江津区土壤硒含量分布及影响因素[D].重庆: 西南大学, 2015.

Zhao W T.Study on the distribution and influencing factors of soil Se of Jiangjin district, Chongqing Municipality[D]. Chongqing: Southwest University, 2015.

郦逸根, 徐静, 李琰, 等.浙江富硒土壤中硒赋存形态特征[J].物探与化探, 2007, 31(2):95-98. http://d.old.wanfangdata.com.cn/Periodical/wtyht200702001

Li Y G, Xu J, Li Y, et al.The modes of occurrence of selenium in selenium-rich soil of Zhejiang Province[J]. Geophysical and Geochemical Exploration, 2007, 31(2):95-98. http://d.old.wanfangdata.com.cn/Periodical/wtyht200702001

罗倩.名山河流域不同土地利用方式土壤硒的形态及其有效性研究[D].成都: 四川农业大学, 2014.

Luo Q.Study on soil selenium species and availability of soil under different land uses in Mingshan River watershed[D]. Chengdu: Sichuan Agricultural University, 2014.

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A Comparative Study of Four Extractants on the Extraction of Available Selenium in Vegetable and Orchard Soils

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