Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing

GAO Zi-han; LI Li-wu; WANG Yu-hui; CAO Chun-hui; HE Jian

doi:10.15898/j.cnki.11-2131/td.201812190138

Rock and Mineral Analysis > 2019 > 38(5): 469-478. > DOI: 10.15898/j.cnki.11-2131/td.201812190138

GAO Zi-han, LI Li-wu, WANG Yu-hui, CAO Chun-hui, HE Jian. Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing[J]. Rock and Mineral Analysis, 2019, 38(5): 469-478. DOI: 10.15898/j.cnki.11-2131/td.201812190138

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Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing

GAO Zi-han^1,2,3,,
LI Li-wu^1,2, ,,
WANG Yu-hui^1,2,3,
CAO Chun-hui^1,2,
HE Jian^1,2

1.
Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China
2.
Key Laboratory of Petroleum Resources, Gansu Province/Key Laboratory of Petroleum Resources Research, Chinese Academy of Sciences, Lanzhou 730000, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

More Information

Received Date: December 18, 2018
Revised Date: May 13, 2019
Accepted Date: July 15, 2019
Published Date: August 31, 2019

Abstract

HIGHLIGHTS
(1) A double vacuum furnace tube with small volume and simple structure composed of quartz glass and metal parts was developed.

(2) An experimental method for heating degassing of rock and ore samples using the double vacuum furnace tube was established.

(3) The results of parallel comparative experiments show that the closure of the double vacuum furnace tube was better than that of the single quartz glass tube at high temperature.

ABSTRACT

BACKGROUNDThe analysis of gas chemical composition in rock and mineral can provide important information and constraints for the study of different geochemical processes of lithospheric mantle, redox environment in the earth, and water circulation in the deep earth. Heating rock and ore samples to remove gas is a common experimental method. A single quartz glass tube is used as the sample tube. Irregular voids in quartz glass structure make gas easy to diffuse and permeate at high temperature. The double vacuum furnace tubes consisting of molybdenum and tantalum crucibles are generally used for the analysis of rare gas isotope composition, but seldom used for the analysis of gas chemical composition. The device has a complex structure, is not easy to assemble and disassemble, and is easily damaged.
OBJECTIVESTo solve the problems contained in the sample-filling tube proposed in the background research.
METHODSA double vacuum sampling furnace tube composed of quartz glass and metal parts had been developed. The furnace tube had the characteristics of small size, easy assembly, disassembly and movement. Under the same experimental conditions, the result was compared with that of a single quartz glass tube.
RESULTSH₂ concentration measured by the double vacuum sampling tube was higher than that measured by the single quartz glass tube under the same experimental conditions, no matter which type of sample was heated to degas at 500℃ or 950℃.
CONCLUSIONSThe closure of the double vacuum furnace tube is better than that of the single quartz glass tube, which is conducive to obtain more real gas chemical composition in the sample.
- double vacuum furnace tube,
- single quartz glass tube,
- gas chromatography,
- gas-released from rock

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References (32)

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Development of a Double Vacuum Furnace Tube and Its Application in Gas Composition Determination during Rock Heating Degassing