Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion

Zhan-chang LEI; Si-qin-tu HAN; Chang-ju JIANG; Hui-zhen LIANG

doi:10.15898/j.cnki.11-2131/td.201812030127

Rock and Mineral Analysis > 2019 > 38(3): 326-332. > DOI: 10.15898/j.cnki.11-2131/td.201812030127

Zhan-chang LEI, Si-qin-tu HAN, Chang-ju JIANG, Hui-zhen LIANG. Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion[J]. Rock and Mineral Analysis, 2019, 38(3): 326-332. DOI: 10.15898/j.cnki.11-2131/td.201812030127

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Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion

Testing Center of Qinghai Nuclear Industry Geological Bureau, Xining 810016, China

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Received Date: December 02, 2018
Revised Date: March 08, 2019
Accepted Date: April 08, 2019
Published Date: April 30, 2019

Abstract

HIGHLIGHTS
(1) The content of tin in primary ores was determined by alkali fusion with sodium peroxide.

(2) The interference of the matrix was overcome by multiple dilution and the application of an internal standard.

(3) Alkali fusion by sodium peroxide and tartaric acid-hydrochloric acid acidification can avoid incomplete digestion of ore, loss of elements and easy hydrolysis of tin.

ABSTRACT

BACKGROUNDThe main types of primary tin ore occur in skarn, porphyry, cassiterite silicate vein, cassiterite sulfide vein, quartz vein and greisen tin deposits. Tin ores are generally insoluble in hydrochloric acid, nitric acid and aqua regia, and tin ores cannot be dissolved completely when treated with sulfuric acid or hydrofluoric acid. Traditional measurement methods such as phenylfluorone-cetyltrimethyl ammonium bromide spectrophotometry and iodometry have disadvantages, such as the serious interference of the associated elements in the sample, poor stability, high detection limit and low analysis efficiency.
OBJECTIVESTo establish a method for the determination of tin in primary ore by Inductively Coupled Plasma-Mass Spectrometry.
METHODSThe sample was melted and decomposed by sodium oxide, and leached by hot water, followed by tartaric acid and hydrochloric acid acidification. ¹⁰³Rh was used as the internal standard element to correct instrument signal drift, and the matrix effect was overcome by high-dilution factors.
RESULTSThe detection limit of the method was 0.1μg/g for tin, the precision was less than 5%, the minimum detection concentration was 0.4μg/g, and the measurement range was 12.5-12700μg/g.
CONCLUSIONSThe method has simple pretreatment and operation. The analysis efficiency and data quality are an improvement over traditional methods.
- tin ore,
- Inductively Coupled Plasma-Mass Spectrometry,
- sodium peroxide,
- tartaric acid-hydrochloric acid acidification

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