• Core Journal of China
  • DOAJ
  • Scopus
  • Chinese Scientific and Technical Papers and Citations (CSTPC)
  • Chinese Science Citation Database (CSCD)
Zhan-chang LEI, Si-qin-tu HAN, Chang-ju JIANG, Hui-zhen LIANG. Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion[J]. Rock and Mineral Analysis, 2019, 38(3): 326-332. DOI: 10.15898/j.cnki.11-2131/td.201812030127
Citation: Zhan-chang LEI, Si-qin-tu HAN, Chang-ju JIANG, Hui-zhen LIANG. Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion[J]. Rock and Mineral Analysis, 2019, 38(3): 326-332. DOI: 10.15898/j.cnki.11-2131/td.201812030127

Determination of Tin in Primary Ores by Inductively Coupled Plasma-Mass Spectrometry with Sodium Peroxide Alkali Fusion

More Information
  • Received Date: December 02, 2018
  • Revised Date: March 08, 2019
  • Accepted Date: April 08, 2019
  • Published Date: April 30, 2019
  • HIGHLIGHTS
    (1) The content of tin in primary ores was determined by alkali fusion with sodium peroxide.
    (2) The interference of the matrix was overcome by multiple dilution and the application of an internal standard.
    (3) Alkali fusion by sodium peroxide and tartaric acid-hydrochloric acid acidification can avoid incomplete digestion of ore, loss of elements and easy hydrolysis of tin.
    BACKGROUNDThe main types of primary tin ore occur in skarn, porphyry, cassiterite silicate vein, cassiterite sulfide vein, quartz vein and greisen tin deposits. Tin ores are generally insoluble in hydrochloric acid, nitric acid and aqua regia, and tin ores cannot be dissolved completely when treated with sulfuric acid or hydrofluoric acid. Traditional measurement methods such as phenylfluorone-cetyltrimethyl ammonium bromide spectrophotometry and iodometry have disadvantages, such as the serious interference of the associated elements in the sample, poor stability, high detection limit and low analysis efficiency.
    OBJECTIVESTo establish a method for the determination of tin in primary ore by Inductively Coupled Plasma-Mass Spectrometry.
    METHODSThe sample was melted and decomposed by sodium oxide, and leached by hot water, followed by tartaric acid and hydrochloric acid acidification. 103Rh was used as the internal standard element to correct instrument signal drift, and the matrix effect was overcome by high-dilution factors.
    RESULTSThe detection limit of the method was 0.1μg/g for tin, the precision was less than 5%, the minimum detection concentration was 0.4μg/g, and the measurement range was 12.5-12700μg/g.
    CONCLUSIONSThe method has simple pretreatment and operation. The analysis efficiency and data quality are an improvement over traditional methods.

  • 张颖, 宫嘉辰.铝片还原-碘量法测定银锡二元合金中锡[J].有色矿冶, 2017, 33(3):59-61. doi: 10.3969/j.issn.1007-967X.2017.03.014

    Zhang Y, Gong J C.Determination of tin silver tin binary alloy by aluminum sheet reduction-iodometry[J].Non-Ferrous Mining and Metallurgy, 2017, 33(3):59-61. doi: 10.3969/j.issn.1007-967X.2017.03.014
    何小虎, 周素莲, 韦莉, 等.碘量法测定铟锡氧化物靶材废料中锡[J].冶金分析, 2013, 33(9):65-69. http://d.old.wanfangdata.com.cn/Periodical/yjfx201309014

    He X H, Zhou S L, Wei L, et al.Determination of tin in indium tin oxide target waste by iodometry[J].Metallurgical Analysis, 2013, 33(9):65-69. http://d.old.wanfangdata.com.cn/Periodical/yjfx201309014
    叶家瑜.区域地球化学勘查样品分析方法[M].北京:地质出版社, 2004.

    Ye J Y.Sample Analysis Method for Regional Geochemical Exploration[M].Beijing:Geological Publishing House, 2004.
    胡永玫.碘量法测定掺锑二氧化锡粉中锡[J].冶金分析, 2018, 38(11):66-70. http://d.old.wanfangdata.com.cn/Periodical/yjfx201811013

    Hu Y M.Determination of tin in antimony-doped tin oxide powder by iodometry[J].Metallurgical Analysis, 2018, 38(11):66-70. http://d.old.wanfangdata.com.cn/Periodical/yjfx201811013
    苏洋, 刘红英.苯芴酮-溴化十六烷基三甲基铵分光光度法测定钛铁中锡[J].冶金分析, 2015, 35(4):65-76. http://d.old.wanfangdata.com.cn/Periodical/yjfx201504013

    Su Y, Liu H Y.Determination of tin in ferrotitanium by phenylfluorone-cetyl trimethyi ammonium bromide spectrophotometry[J].Metallurgical Analysis, 2015, 35(4):65-76. http://d.old.wanfangdata.com.cn/Periodical/yjfx201504013
    谭仪文.苯芴酮-溴代十六烷基三甲胺分光光度法测定析出铅中的锡[J].中国有色冶金, 2005, 4(2):23-25. doi: 10.3969/j.issn.1672-6103.2005.02.006

    Tan Y W.Determining tin in deposited lead by benzfluorenone-bromo-hexadecyl-trimethylamine spectrophotometry[J].China Nonferrous Metallurgy, 2005, 4(2):23-25. doi: 10.3969/j.issn.1672-6103.2005.02.006
    姚建贞, 郝志红, 唐瑞玲, 等.固体发射光谱法测定地球化学样品中的高含量锡[J].光谱学与光谱分析, 2013, 33(11):3124-3127. doi: 10.3964/j.issn.1000-0593(2013)11-3124-04

    Yao J Z, Hao Z H, Tang R L, et al.Determination of high content of tin in geochemical samples by solid emission spectrometry[J].Spectroscopy and Spectral Analysis, 2013, 33(11):3124-3127. doi: 10.3964/j.issn.1000-0593(2013)11-3124-04
    刘江斌, 武永芝.原子发射光谱法快速测定矿石中锡[J].冶金分析, 2013, 33(3):65-68. doi: 10.3969/j.issn.1000-7571.2013.03.012

    Liu J B, Wu Y Z.Rapid determination of tin in ore by atomic emission spectrometry[J].Metallurgical Analysis, 2013, 33(3):65-68. doi: 10.3969/j.issn.1000-7571.2013.03.012
    辛文芳, 李伟, 乌晓蒙.发射光谱法测多目标区域地球化学调查中银、硼、锡三元素的分析总结[J].地质与资源, 2016, 25(4):401-403. doi: 10.3969/j.issn.1671-1947.2016.04.016

    Xin W F, Li W, Wu X M.Determination of silver, boron and tin from multi-purpose regional geochemical survey by emission spectrometry[J].Geology and Resources, 2016, 25(4):401-403. doi: 10.3969/j.issn.1671-1947.2016.04.016
    胡长春, 王沿方, 陈作王.电感耦合等离子体原子发射光谱法测定锡铅合金中的锡[J].化学分析计量, 2018, 27(5):72-75. doi: 10.3969/j.issn.1008-6145.2018.05.017

    Hu C C, Wang Y F, Chen Z W.Determination of tin in tin-lead alloy by inductively coupled plasma atomic emission spectrometry[J].Chemical Analysis and Meterage, 2018, 27(5):72-75. doi: 10.3969/j.issn.1008-6145.2018.05.017
    李超, 刘英波, 韩豫萍, 等.发射光谱法测定地球化学物料中的微量银锡硼[J].云南冶金, 2018, 47(3):84-88. http://d.old.wanfangdata.com.cn/Periodical/ynyj201803014

    Li C, Liu Y B, Han Y P, et al.The determination of trace amount silver, tin, boron in geochemical materials by emission spectrography[J].Yunnan Metallurgy, 2018, 47(3):84-88. http://d.old.wanfangdata.com.cn/Periodical/ynyj201803014
    Roncevic S, Nemet I, Svedruzic L P, et al.Chemical vapour generation for tin determination in high-content calcium matrix by inductively coupled plasma atomic emission spectrometry[J].Croatica Chemica Acta, 2014, 87(1):17-22. doi: 10.5562/cca2259
    Afonso D D, Baytak S, Arslan Z.Simultaneous generation of hydrides of bismuth, lead and tin in the presence of ferricyanide and application to determination in biominerals by ICP-AES[J].Journal of Analytical Atomic Spectrometry, 2010, 25(5):726-729. doi: 10.1039/b920280c
    Uemoto M, Nagaoka M, Fujinuma H.Interlaboratory testing for the determination of trace amounts of tin and lead in magnesium and magnesium alloys by inductively coupled plasma atomic emission spectrometry[J].Analytical Sciences, 2009, 25(5):717-721. doi: 10.2116/analsci.25.717
    陈安明.电感耦合等离子体原子发射光谱法测定碳钢及生铁中痕量砷锑铋锡铅[J].冶金分析, 2007, 27(3):68-70. doi: 10.3969/j.issn.1000-7571.2007.03.016

    Chen A M.Determination of trace As, Sb, Bi, Sn and Pb in steel and pig iron by inductively coupled plasma-atomic emission spectrometry[J].Metallurgical Analysis, 2007, 27(3):68-70. doi: 10.3969/j.issn.1000-7571.2007.03.016
    Seco-Gesto E M, Moreda-Pineiro A, Bermejo-Barrera A, et al.Multi-element determination in raft mussels by fast microwave-assisted acid leaching and inductively coupled plasma-optical emission spectrometry[J].Talanta, 2007, 72(3):1178-1185. doi: 10.1016/j.talanta.2007.01.009
    陈波, 胡兰, 陈园园, 等.地质样品中总锡测定方法的研究进展[J].理化检验(化学分册), 2017, 53(2):236-241. http://d.old.wanfangdata.com.cn/Periodical/lhjy-hx201702026

    Chen B, Hu L, Chen Y Y, et al.Recent progress of research on methods for determination of total tin in geological samples[J].Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2017, 53(2):236-241. http://d.old.wanfangdata.com.cn/Periodical/lhjy-hx201702026
    郝原芳, 刘新, 宋丽华, 等.电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡[J].岩矿测试, 2016, 35(4):378-383. doi: 10.15898/j.cnki.11-2131/td.2016.04.007

    Hao Y F, Liu X, Song L H, et al.Determination of trace cadmium and tin in lead alloys by inductively coupled plasma-mass spectrometry[J].Rock and Mineral Analysis, 2016, 35(4):378-383. doi: 10.15898/j.cnki.11-2131/td.2016.04.007
    罗艳, 杨侨.碱熔、分离沉淀-电感耦合等离子体质谱法快速测定地球化学样品中的锡[J].分析试验室, 2017, 36(7):827-830. http://www.cnki.com.cn/Article/CJFDTOTAL-FXSY201707020.htm

    Luo Y, Yang Q.Alkaline fusion, separate precipitation-inductively coupled plasma spectrometry and rapid measurement of tin from planet chemical samples[J].Chinese Journal of Analysis Laboratory, 2017, 36(7):827-830. http://www.cnki.com.cn/Article/CJFDTOTAL-FXSY201707020.htm
    侯艳霞, 刘庆彬, 胡净宇, 等.电感耦合等离子体质谱法测定锡粉基体的记忆效应研究[J].冶金分析, 2015, 35(12):1-4. http://d.old.wanfangdata.com.cn/Periodical/yjfx201512001

    Hou Y X, Liu Q B, Hu J Y, et al.Study on memory effect of tin powder matrix by inductively coupled plasma mass spectrometry[J].Metallurgical Analysis, 2015, 35(12):1-4. http://d.old.wanfangdata.com.cn/Periodical/yjfx201512001
    王铁, 亢德华, 于媛君.电感耦合等离子体质谱法测定锰铁中痕量铅锡锑[J].冶金分析, 2013, 33(5):13-16. http://d.old.wanfangdata.com.cn/Periodical/yjfx201305003

    Wang T, Kang D H, Yu Y J.Determination of trace lead, tin and antimony in ferromanganese by inductively coupled plasma mass spectrometry[J].Metallurgical Analysis, 2013, 33(5):13-16. http://d.old.wanfangdata.com.cn/Periodical/yjfx201305003
    Hosick T J, Ingamells R L, Machemer S D.Determina-tion of tin in soil by continuous hydride generation and inductively coupled plasma mass spectrometry[J].Analytica Chimica Acta, 2002, 456(2):263-269. doi: 10.1016/S0003-2670(02)00049-1
    Brügmann G, Berger D, Pernicka E.Determination of the tin stable isotopic composition in tin-bearing metals and minerals by MC-ICP-MS[J].Geostandards and Geoanalytical Research, 2017, 41(3):437-448. doi: 10.1111/ggr.2017.41.issue-3
    Latkoczy C, Prohaska T, Stingeder G, et al.Simultaneous multi-element analysis of trace elements in soil samples by means of high-resolution inductively coupled plasma sector field mass spectrometry (SF-ICP-MS)[J].Fresenius Journal of Analytical Chemistry, 2000, 368(2-3):256-262. doi: 10.1007/s002160000432
    Duan H, Gong Z, Yang S.Online photochemical vapour generation of inorganic tin for inductively coupled plasma mass spectrometric detection[J].Journal of Analytical Atomic Spectrometry, 2015, 30(2):410-416. doi: 10.1039/C4JA00249K
    黄超冠, 蒙义舒, 郭焕花, 等.过氧化钠碱熔-电感耦合等离子体发射光谱法测定钛铝合金中的铬铁钼硅[J].岩矿测试, 2018, 37(1):30-35. doi: 10.15898/j.cnki.11-2131/td.201704240065

    Huang C G, Meng Y S, Guo H H, et al.Determination of chromium, iron, molybdenum and silicon in Ti-Al alloy by inductively coupled plasma-optical emission spectrometry with sodium peroxide alkali fusion[J].Rock and Mineral Analysis, 2018, 37(1):30-35. doi: 10.15898/j.cnki.11-2131/td.201704240065
    王凤祥.电感耦合等离子体原子发射光谱法测定锡矿石中锡[J].冶金分析, 2017, 37(11):59-63. http://d.old.wanfangdata.com.cn/Periodical/yjfx201711011

    Wang F X.Determination of tin in tin ore by inductively coupled plasma atomic emission spectrometry[J].Metallurgical Analysis, 2017, 37(11):59-63. http://d.old.wanfangdata.com.cn/Periodical/yjfx201711011
    黎卫亮, 程秀花, 李忠煜, 等.碱熔共沉淀-电感耦合等离子体质谱法测定橄榄岩中的稀土元素[J].岩矿测试, 2017, 36(5):468-473. doi: 10.15898/j.cnki.11-2131/td.201607130099

    Li W L, Cheng X H, Li Z Y, et al.Determination of rare earth elements in peridotite by inductively coupled plasma-mass spectrometry after alkali fusion and Mg(OH)2 and Fe(OH)3 coprecipitation[J].Rock and Mineral Analysis, 2017, 36(5):468-473. doi: 10.15898/j.cnki.11-2131/td.201607130099
    刘艳花, 孙湘莉.莫桑比克某重砂矿选冶流程样品中钛和铬的联合测定[J].冶金分析, 2017, 37(7):37-44. http://d.old.wanfangdata.com.cn/Periodical/yjfx201707007

    Liu Y H, Sun X L.Combined determination of titanium and chromium in the samples from the flotation-metallurgy process of heavy placer in Mozambique[J].Metallurgical Analysis, 2017, 37(7):37-44. http://d.old.wanfangdata.com.cn/Periodical/yjfx201707007
    王小强, 夏辉, 秦九红, 等.过氧化钠碱熔-电感耦合等离子体发射光谱法测定多金属矿中的锡钨钛等主次量成分[J].岩矿测试, 2017, 36(1):52-58. doi: 10.15898/j.cnki.11-2131/td.2017.01.008

    Wang X Q, Xia H, Qin J H, et al.Determination of Sn, W, Ti and other elements in polymetallic ore by inductively coupled plasma-optical emission spectrometry with sodium peroxide fusion[J].Rock and Mineral Analysis, 2017, 36(1):52-58. doi: 10.15898/j.cnki.11-2131/td.2017.01.008
    李冰, 杨红霞.电感耦合等离子体质谱原理和应用[M].北京:地质出版社, 2005.

    Li B, Yang H X.Principle and Application of Inductively Coupled Plasma-Mass Spectrometry[M].Beijing:Geological Publishing House, 2005.
    杨惠玲, 夏辉, 杜天军, 等.电感耦合等离子体发射光谱法同时测定锡矿石中锡钨钼铜铅锌[J].岩矿测试, 2013, 32(6):887-892. http://www.ykcs.ac.cn/article/id/12fc9719-0e4a-4249-be27-2e067212525c

    Yang H L, Xia H, Du T J, et al.Simultaneous determination of Sn, W, Mo, Cu, Pb and Zn in tin ores by inductively coupled plasma-atomic emission spectrometry[J].Rock and Mineral Analysis, 2013, 32(6):887-892. http://www.ykcs.ac.cn/article/id/12fc9719-0e4a-4249-be27-2e067212525c
    张雪梅, 张勤.发射光谱法测定勘查地球化学样品中银硼锡钼铅[J].岩矿测试, 2006, 25(4):323-326. http://www.ykcs.ac.cn/article/id/ykcs_200604107

    Zhang X M, Zhang Q.Determination of silver, boron, tin, molybdenum and lead in geochemical exploration samples by emission spectrometry[J].Rock and Mineral Analysis, 2006, 25(4):323-326. http://www.ykcs.ac.cn/article/id/ykcs_200604107
    杨小莉, 杨小丽, 李小丹, 等.敞开酸溶-电感耦合等离子体质谱法同时测定钨矿石和锡矿石中14种微量元素[J].岩矿测试, 2014, 33(3):321-326. http://www.ykcs.ac.cn/article/id/956360be-9a54-4e0a-8ef1-0f9f0be45e32

    Yang X L, Yang X L, Li X D, et al.Simultaneous determination of 14 trace elements in and tin ore with open acid digestion by inductively coupled plasma-mass spectrometry[J].Rock and Mineral Analysis, 2014, 33(3):321-326. http://www.ykcs.ac.cn/article/id/956360be-9a54-4e0a-8ef1-0f9f0be45e32
  • Related Articles

    [1]YUAN Jing, LI Yingchun, TAN Guili, HUANG Haibo, ZHANG Hua, LIU Jiao. Some Difficulties and Status in the Application of X-Ray Spectrometry in Geological Analysis: A Review[J]. Rock and Mineral Analysis, 2025, 44(2): 161-173. DOI: 10.15898/j.ykcs.202403150052
    [2]Jing CHEN, Zhi-jun GAO, Chong-ke CHEN, Yan-xia LIU, Ming-wei ZHANG. Application Skills on Determination of Geological Sample by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2015, 34(1): 91-98. DOI: 10.15898/j.cnki.11-2131/td.2015.01.012
    [3]Zhao-shui YU, Qin ZHANG, Xiao-li LI, Shou-zhong FAN, Yan-shan PAN, Guo-hui LI. Determination of 23 Elements in Biological Samples by Wavelength Dispersion X-ray Fluorescence Spectrometry with High Pressure Pressed Powder Pellet Preparation[J]. Rock and Mineral Analysis, 2014, 33(6): 844-848.
    [4]MA Tian-fang, LI Xiao-li, CHEN Yong-jun, DENG Zhen-pin, LI Guo-hui. Interchangeable Analysis of Method on the X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2011, 30(4): 486-490.
    [5]CHEN Yongjun, WANG Yaping, XU Chunxue, ZHENG Miaozi, WANG Suming. Preparation of Synthetic Standard Reference Materials for X-ray Fluorescence Spectrometric Analysis[J]. Rock and Mineral Analysis, 2009, 28(5): 462-466.
    [6]Determination of Mo,Pb,Fe and Cu in Molybdenum Ores by Energy-dispersive X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(3): 235-236.
    [7]Determination of Multi-elements in Iron Ores by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(3): 229-231.
    [8]Simultaneous Determination of Major, Minor and Trace Components in Limestone Samples by X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(2): 149-150.
    [9]Determination of Major and Minor Components in Sea Sediment Samples by Fused Bead-X-ray Fluorescence Spectrometry[J]. Rock and Mineral Analysis, 2008, 27(1): 74-76.
    [10]A Semi-quantitative Method Improved for Rare-earth Element Analysis by XRF without Standards[J]. Rock and Mineral Analysis, 2003, (1): 37-39.
  • Cited by

    Periodical cited type(31)

    1. 梁亚丽,吴领军,杨珍,孙银生,阿丽莉,贺攀红. 四酸消解-电感耦合等离子体质谱法测定砂岩型铀矿中铀钍及稀土元素. 冶金分析. 2025(01): 68-75 .
    2. 刘维一,熊正烨,郭竞渊,廖小婷,余果. 雷州半岛东部近岸水体溴质量浓度空间分布及其影响因素. 激光与光电子学进展. 2024(05): 89-97 .
    3. 李晓敬,胡艳巧,张金明,冉卓,赵良成,金倩. 微波消解-电感耦合等离子体质谱法测定石墨矿中16种稀土元素. 冶金分析. 2024(08): 18-26 .
    4. 黄平安,王夏青,唐湘玲,王玉堂,李玮,罗增,吕飞亚. X射线荧光光谱岩心扫描影响因素及校正方法的研究进展. 物探与化探. 2023(03): 726-738 .
    5. 李小莉,王毅民,邓赛文,王祎亚,李松,白金峰. 中国X射线荧光光谱分析的地学应用60年. 光谱学与光谱分析. 2023(10): 2989-2998 .
    6. 董龙腾,王生进,刘才云. 电感耦合等离子体质谱标准物质换算法测定地质样品中15种稀土元素. 化学分析计量. 2022(02): 53-57 .
    7. 王晨希. X射线荧光光谱法测定农田底泥中8种元素. 化学分析计量. 2022(02): 40-44 .
    8. 刘闫,姚明星,张丽萍,樊蕾,张宏丽,王甜甜. 电感耦合等离子体质谱法测定锆钛矿中16种稀土元素分量及其总量. 冶金分析. 2022(03): 19-25 .
    9. 胡瑶瑶,王浩铮,侯玉杨,宋皓然. 基于电子探针面扫描定量化的石英闪长岩微区成分分析. 岩矿测试. 2022(02): 260-271 . 本站查看
    10. 秦燕华,刘巍,刘姜瑾,练文柳,罗嘉,韩星,任建新. 基于EDXRF光谱法的滤棒中痕量砷和铅的快速检测. 烟草科技. 2022(07): 40-46 .
    11. 周凯红,张立锋,李佳. 电感耦合等离子体质谱法测定白云鄂博矿石中15种稀土元素总量及其分量. 冶金分析. 2022(08): 87-95 .
    12. 曾江萍,王家松,朱悦,张楠,王娜,吴良英,魏双. 敞开酸溶-电感耦合等离子体质谱法测定铀矿石中15种稀土元素. 岩矿测试. 2022(05): 789-797 . 本站查看
    13. 王娜,王家松,曾江萍,李强,吴磊,陈枫. 重铬酸钾和高锰酸钾电位落差法测定砂岩型铀矿氧化还原电位的探讨. 岩矿测试. 2022(05): 806-814 . 本站查看
    14. 玉永珊. 稀土元素分析测试方法在地质学上的应用. 世界有色金属. 2022(15): 166-168 .
    15. 张玉芹,彭艳,韦时宏,朱健. 高压密闭消解-电感耦合等离子体质谱法测定地质样品中稀土元素. 实验室研究与探索. 2021(03): 29-32 .
    16. 李艳. 熔融制样X射线荧光光谱法测定矿石中五氧化二钒的含量. 福建分析测试. 2021(01): 54-58 .
    17. 刘春,高励珍,张翼明,刘晓杰. 电感耦合等离子体发射光谱法测定镨钕钆合金中稀土杂质量. 金属功能材料. 2021(04): 59-63 .
    18. 苗煦,王礼胜. 湖南临武黑色石英岩质玉矿物组成特征及成因初探. 岩矿测试. 2021(04): 522-531 . 本站查看
    19. 曾江萍,王家松,王娜,郑智慷,王力强,张楠. 敞开酸溶—电感耦合等离子体质谱法测定锑矿石中的稀土元素. 华北地质. 2021(04): 80-84 .
    20. 尹昌慧,袁永海,杨锋. 阳离子交换树脂富集-电感耦合等离子体质谱法测定铜精矿中14种稀土元素. 理化检验(化学分册). 2020(05): 532-535 .
    21. 王毅民,邓赛文,王祎亚,李松. X射线荧光光谱在矿石分析中的应用评介——总论. 冶金分析. 2020(10): 32-49 .
    22. 张绵绵,高晓哲. 塑胶跑道面层中铅、镉、铬、汞的测定X射线荧光光谱法. 中国石油和化工标准与质量. 2020(16): 71-72+76 .
    23. 王祎亚,高新华,王毅民,邓赛文,李松. 地质材料稀土元素的X射线荧光分析文献评介. 光谱学与光谱分析. 2020(11): 3341-3352 .
    24. 袁静,刘建坤,郑荣华,沈加林. 高能偏振能量色散X射线荧光光谱仪特性研究及地质样品中主微量元素分析. 岩矿测试. 2020(06): 816-827 . 本站查看
    25. 李迎春,张磊,周伟,尚文郁. 熔融制样-波长色散和能量色散X射线荧光光谱仪应用于硅酸盐类矿物及疑难样品分析. 岩矿测试. 2020(06): 828-838 . 本站查看
    26. 赵毅华. 熔融制样-X射线荧光光谱法测定镜铁矿中主次成分. 分析测试技术与仪器. 2019(01): 33-38 .
    27. 阿丽莉,张盼盼,贺攀红,杨珍,梁亚丽,杨有泽. X射线荧光光谱法测定地质样品中的硫和氟. 中国无机分析化学. 2019(02): 50-53 .
    28. 王啸,李田义,姜菲. ICP-MS测定高硅矿物中铌、钽及稀土. 稀土. 2019(03): 109-114 .
    29. 阿丽莉,贺攀红,张盼盼. 粉末压片-X射线荧光光谱法测定地质样品中镧铈镨钕钐. 冶金分析. 2019(09): 39-45 .
    30. 田衎,郭伟臣,杨永,岳亚萍,张覃,赵亚娴. 波长色散X射线荧光光谱法测定土壤和水系沉积物中13种重金属元素. 冶金分析. 2019(10): 30-36 .
    31. 董学林,何海洋,储溱,仇秀梅,唐兴敏. 碱熔沉淀分离-电感耦合等离子体质谱法测定伴生重晶石稀土矿中的稀土元素. 岩矿测试. 2019(06): 620-630 . 本站查看

    Other cited types(3)

Catalog

    Article views (1865) PDF downloads (85) Cited by(34)

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return