Pollution and Distribution Characteristics of Pesticides in Groundwater in the Alluvial-Pluvial Fan of the Hutuo River, Haihe River Basin

Ze-yan LI; Fu-yang HUANG; Dan-dan LIU; Yan-jun LIU; Fei LIU

doi:10.15898/j.cnki.11-2131/td.201808030091

Rock and Mineral Analysis > 2019 > 38(2): 186-194. > DOI: 10.15898/j.cnki.11-2131/td.201808030091

Ze-yan LI, Fu-yang HUANG, Dan-dan LIU, Yan-jun LIU, Fei LIU. Pollution and Distribution Characteristics of Pesticides in Groundwater in the Alluvial-Pluvial Fan of the Hutuo River, Haihe River Basin[J]. Rock and Mineral Analysis, 2019, 38(2): 186-194. DOI: 10.15898/j.cnki.11-2131/td.201808030091

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Pollution and Distribution Characteristics of Pesticides in Groundwater in the Alluvial-Pluvial Fan of the Hutuo River, Haihe River Basin

1.
School of Water Resources and Environmental Engineering, China University of Geoscience(Beijing), Beijing 100083, China
2.
Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Baoding 071051, China
3.
Geological Museum of Heilongjiang Province, Harbin 150090, China

More Information

Received Date: August 02, 2018
Revised Date: December 16, 2018
Accepted Date: January 03, 2019
Published Date: February 28, 2019

Abstract

HIGHLIGHTS
(1) The concentration differences of organochlorine pesticides, organophosphorus pesticides and organic nitrogen pesticides were related to their application history and properties.

(2) The spatial distribution characteristics of pesticides were influenced mainly by the groundwater depth and lithology of the aerated zone.

(3) HCHs and DDTs in the area had two sources of the recent or historical utilization.

ABSTRACT

BACKGROUNDGroundwater is the primary drinking water source in the alluvial-pluvial fan of the Hutuo River. Pesticides application during agricultural planting leads to groundwater pollution. The pesticide pollution investigation work of this area in groundwater is relatively scarce.
OBJECTIVESTo study the pollution and distribution characteristics of pesticides in groundwater collected in the alluvial-pluvial fan of the Hutuo River.
METHODSGas Chromatography-Mass Spectrometry was used to analyze 75 pesticides in 30 groups of groundwater samples, and the results were investigated by statistical methods.
RESULTSThe results show that pesticides were detected in all 30 sampling sites. 40 of 75 pesticides were detected, which include organochlorine pesticides, organophosphorus pesticides, and organic nitrogen pesticides. The pesticides with the highest detection frequency were 3-hydroxycarburan (93.3%), dioxathion (90.0%) and chloroneb (90.0%). The pesticide with the maximum sum detection concentration of 30 samples was carbofuran (4860.6ng/L). The average detected concentrations of three pesticide types in the study area were 70.8ng/L for organochlorine pesticides, 392.7ng/L for organophosphorus pesticides, and 580.9ng/L for organic nitrogen pesti-cides, which is related to the application history and property of three pesticide types.
CONCLUSIONSOrganochlorine pesticides were banned in 1983 due to their high toxicity and hard degradation. At the beginning of the 21st century, relatively efficient and easily degradable organophosphorus pesticides and organic nitrogen pesticides developed rapidly. From the top to the middle of the alluvial fan, the concentration of the three pesticide types decreased gradually. The spatial distribution characteristics of pesticides were mainly influenced by the hydrogeological characteristics of the alluvial fan. HCHs in the area were from the recent using of lindan or industrial degradation of HCHs, DDTs were from the release of new DDT or historical ultilization. The research results provide basic data support for groundwater pesticides pollution monitoring and groundwater-related standard formulation in China.
- pesticides,
- groundwater,
- alluvial-pluvial fan of Hutuo River,
- hydrogeological characteristics,
- Gas Chromatography-Mass Spectrometry

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Pollution and Distribution Characteristics of Pesticides in Groundwater in the Alluvial-Pluvial Fan of the Hutuo River, Haihe River Basin

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