Research on the Effect of Chemical Reduction-Stabilization Combined Remediation of Cr-contaminated Soil

Mao-guo AN; Qing-ling ZHAO; Xian-feng TAN; Yong-gang WANG; Qing-cai LI

doi:10.15898/j.cnki.11-2131/td.201806040068

Rock and Mineral Analysis > 2019 > 38(2): 204-211. > DOI: 10.15898/j.cnki.11-2131/td.201806040068

Mao-guo AN, Qing-ling ZHAO, Xian-feng TAN, Yong-gang WANG, Qing-cai LI. Research on the Effect of Chemical Reduction-Stabilization Combined Remediation of Cr-contaminated Soil[J]. Rock and Mineral Analysis, 2019, 38(2): 204-211. DOI: 10.15898/j.cnki.11-2131/td.201806040068

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Research on the Effect of Chemical Reduction-Stabilization Combined Remediation of Cr-contaminated Soil

1.
Lunan Geo-Engineering Exploration Institute of Shandong Province, Yanzhou 272100, China
2.
Technology Innovation Center of Integrated Management and Ecological Restoration for Mining Subsidence Area, Ministry of Natural Resources, Yanzhou 272100, China

More Information

Received Date: June 03, 2018
Revised Date: July 23, 2018
Accepted Date: August 09, 2018
Published Date: February 28, 2019

Abstract

HIGHLIGHTS
(1) A chemical reduction-stabilization combined method for remediation of Cr(Ⅵ) contaminated soil was adopted.

(2) The optimal operational condition and the parameters of the method were investigated.

ABSTRACT

BACKGROUNDCr(Ⅵ) is one of the 47 internationally recognized most dangerous wastes. Study on the remedy of Cr-contaminated soil is of great significance for risk control of contaminated soil.
OBJECTIVESTo build a reliable method for Cr-contaminated soil, and to screen the optimal remediation conditions. To propose a chemical reduction-stabilization combined method for remediation of Cr(Ⅵ) contaminated soil and screen the remediation conditions including choice of reductant, soil/liquid ratio and stabilizer.
METHODSSoil from a typical chromium contaminated site in Jinan is used as the research object, and the idea of 'chemical reduction + solidification stability' is suggested, which is aimed at the types of repair agent, dosage ratio, reaction time, reduction efficiency, repair cost and environmental effect. The optimal conditions for the repair process were determined and the remediation effects of contaminated soil were evaluated.
RESULTSThe results demonstrated that the optimal parameter for Cr(Ⅵ) treatment was using ferrous chloride as the reductant and treating for 2 days, controlling the addition amount of the reductant at 5 times of its stoichiometric need. Calcium magnesium phosphate was used as the stabilizer and its addition amount was controlled as 10%. After remediation, the bioavailable efficients of Cr in the soil reduced from 0.4398 to 0.0017. The results showed that contents of Cr(Ⅵ) in the treated soil were 0.315-0.501mg/kg, and 99.5% of Cr(Ⅵ) was reduced.
CONCLUSIONSThe remedied soil satisfies the risk screen number for residual land. This result could provide reference and theoretical basis for soil remediation and decision-making.
- chemical reduction,
- stabilization,
- Cr(Ⅵ),
- soil remediation,
- combined method

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