Hong-zhang DAI, Deng-hong WANG, Li-jun LIU, Fan HUANG, Cheng-hui WANG. Study on Emerald-level Beryl from the Zhen'an W-Be Polymetallic Deposit in Shaanxi Province by Electron Probe Microanalyzer and Micro X-ray Diffractometer[J]. Rock and Mineral Analysis, 2018, 37(3): 336-345. DOI: 10.15898/j.cnki.11-2131/td.201712140193
Citation: Hong-zhang DAI, Deng-hong WANG, Li-jun LIU, Fan HUANG, Cheng-hui WANG. Study on Emerald-level Beryl from the Zhen'an W-Be Polymetallic Deposit in Shaanxi Province by Electron Probe Microanalyzer and Micro X-ray Diffractometer[J]. Rock and Mineral Analysis, 2018, 37(3): 336-345. DOI: 10.15898/j.cnki.11-2131/td.201712140193

Study on Emerald-level Beryl from the Zhen'an W-Be Polymetallic Deposit in Shaanxi Province by Electron Probe Microanalyzer and Micro X-ray Diffractometer

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  • Received Date: December 13, 2017
  • Revised Date: January 24, 2018
  • Accepted Date: March 20, 2018
  • Published Date: April 30, 2018
  • HIGHLIGHTS
    (1) Electron Microprobe analysis and in-situ Micro X-ray Diffraction analysis were carried to study on chromatic mechanism and genetic mechanism of the newly discovered emerald in Zhen'an area, Shaanxi Province.
    (2) Vanadium is the main coloring element of the emerald and derived from carbonaceous slate, mica schist and dolomitic marble.
    (3) The emerald belongs to 'normal' beryl, and there are two kinds of isomorphous substitution mechanism including Al↔Me2+ and Be↔Li.
    BACKGROUND A new deposit type with a scheelite-beryl-molybdenite assemblage was first discovered in the Zhen'an area of Shaanxi Province.
    BAOBJECTIVES The research on chromatic mechanism and genetic mechanism of emerald was carried out.
    METHODS Combined with the geological survey, Electron Microprobe and in-situ Micro X-ray Diffractomer were used to conduct mineral research.
    RESULTS The emerald mainly occurs in the quartz (calcite) veins as euhedral crystal and is associated with scheelite. Both the core and rim of the emerald with high V2O3 contents of 0.64%-0.98% and 1.04%-1.42%, respectively, show an increased V2O3 trend from core to rim. Diffraction data show that the emerald is normal beryl and has two kinds of isomorphous substitution mechanism, Al↔Me2+ and Be↔Li. Vanadium is the main coloring element of emerald and was mainly derived from carbonaceous slate, mica schist, and dolomitic marble, whereas Be, Si and Al were derived from deep acidic igneous rocks.
    CONCLUSIONS The discovery provides basic geological data for the comprehensive development and utilization of tungsten and antimony mineral resources in the deposit, and indicates new prospecting directions for continued searching for rare metal deposits in the region and deep areas of the South Qinling.

  • 胡荣荣, 张世涛.祖母绿矿床研究现状[J].化工矿产地质, 2006, 28(4):234-240. http://mall.cnki.net/magazine/Article/HGKC200604009.htm

    Hu R R, Zhang S T.Current research situation of the world emerald deposits and the existing problems[J].Geology of Chemical Minerals, 2006, 28(4):234-240. http://mall.cnki.net/magazine/Article/HGKC200604009.htm
    胡荣荣, 张世涛.世界祖母绿矿床研究现状及存在问题[J].矿产与地质, 2007, 21(1):94-99. http://www.cnki.com.cn/Navi/A.htm

    Hu R R, Zhang S T.Status of worldwide emerald deposit research and some problems[J].Mineral Resources and Geology, 2007, 21(1):94-99. http://www.cnki.com.cn/Navi/A.htm
    Gavrilenko E, Pérez B C, Bolibar R C, et al.Emeralds from the Delbegetey deposit (Kazakhstan):Mineralogical characteristics and fluid-inclusion study[J].Mineralogical Magazine, 2006, 70(2):159-173. doi: 10.1180/0026461067020321
    Ottaway T L, Wicks F J, Bryndzia L T, et al.Formation of the Muzo hydrothermal emerald deposit in Colombia[J].Nature, 1994, 369:552-554. doi: 10.1038/369552a0
    Bragg W L, West J.The structure of beryl, Be3Al2Si6O18[J].Royal Society of London Proceedings, 1926, 111(759):691-714. doi: 10.1098/rspa.1926.0088
    刘琰, 邓军, 孙岱生, 等.四川虎牙雪宝顶W-Sn-Be矿床矿物学标型特征及流体对矿物形态的影响[J].地球科学——中国地质大学学报, 2007, 32(1):75-81. http://www.cnki.com.cn/Article/CJFD1997-KYDH701.007.htm

    Liu Y, Deng J, Sun D S, et al.Morphology and gensis typomorphism of minerals in W-Sn-Be deposit of Huya, Sichuan[J]. Earth Science-Journal of China University of Geosciences, 2007, 32(1):75-81. http://www.cnki.com.cn/Article/CJFD1997-KYDH701.007.htm
    阮青锋, 张良钜, 张昌龙, 等.绿柱石的成因与特征的研究[J].矿产与地质, 2008, 22(3):265-269. https://www.wenkuxiazai.com/doc/40021281d4d8d15abe234e07-2.html

    Ruan Q F, Zhang L J, Zhang C L, et al.Genesis and characteristics of beryl[J].Mineral Resources & Geology, 2008, 22(3):265-269. https://www.wenkuxiazai.com/doc/40021281d4d8d15abe234e07-2.html
    Garcí J M, Lastra A, Barriuso M T, et al.Origin of the different color of ruby and emerald[J].Physical Review B, 2005, 72(11):3104. http://www.mendeley.com/research/origin-different-color-ruby-emerald/
    钟倩, 廖宗廷, 周征宇, 等.水热法合成Paraíba色绿柱石的宝石学特征[J].宝石和宝石学杂志, 2016, 18(6):1-7. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bshbsxzz200201009

    Zhong Q, Liao Z T, Zhou Z Y, et al.Gemmological characteristics of hydrothermal synthetic paraíba-cloour beryl[J].Journal of Gems & Gemmology, 2016, 18(6):1-7. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bshbsxzz200201009
    申柯娅.天然祖母绿与合成祖母绿的成分及红外吸收光谱研究[J].岩矿测试, 2011, 30(2):233-237. http://www.ykcs.ac.cn/article/id/ce380698-cdb7-491c-8284-258a85a55ac4

    Shen K Y.Study on chemical compositions and infrared absorption spectra of natural and synthetic emeralds[J].Rock and Mineral Analysis, 2011, 30(2):233-237. http://www.ykcs.ac.cn/article/id/ce380698-cdb7-491c-8284-258a85a55ac4
    梁婷.云南祖母绿的呈色机理初探[J].宝石和宝石学杂志, 2001, 3(4):21-24. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bshbsxzz200104006

    Liang T.Study on coluration mechanism of emerald from Yunnan Province[J].Journal of Gems & Gemmology, 2001, 3(4):21-24. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bshbsxzz200104006
    梁婷.祖母绿的红外光谱特征研究[J].长安大学学报(地球科学版), 2003, 25(2):10-13. http://www.cnki.com.cn/Article/CJFDTOTAL-RGJT201503003.htm

    Liang T.The study on infrared absorption pectroscopic characteristics of emeralds[J].Journal of Chang'an University (Earth Science Edition), 2003, 25(2):10-13. http://www.cnki.com.cn/Article/CJFDTOTAL-RGJT201503003.htm
    张文兰, 王汝成, 蔡淑月.超轻元素Be元素的电子探针定量分析——以绿柱石为例[J].电子显微学报, 2006(增刊1):293-294. http://industry.wanfangdata.com.cn/dl/Detail/Conference?id=Conference_6347885

    Zhang W L, Wang R C, Cai S Y.Quantitative analysis of ultralight element Be by electron microprobe-Taking beryl as an example[J].Journal of Chinese Electron Microscopy Society, 2006(Supplement 1):293-294. http://industry.wanfangdata.com.cn/dl/Detail/Conference?id=Conference_6347885
    Liu J J, Zhai D G, Dai H Z, et al.Nanoscale character-ization of Au2Te grains from the Sandaowanzi gold deposit, Northeast China[J].The Canadian Mineralogist, 2017, 55(2):181-194. doi: 10.3749/canmin.1600077
    Uher P, Chudík P, Bačík P, et al.Beryl composition and evolution trends:An example from granitic pegmatites of the beryl-columbite subtype, Western Carpathians, Slovakia[J].Journal of Geosciences, 2010, 55(1):69-80. http://www.oalib.com/paper/2807022
    Wang R C, Che X D, Zhang W L, et al.Geochemical evolution and late re-equilibration of Na-Cs-rich beryl from the Koktokay #3 pegmatite (Altai, NW China)[J].European Journal of Mineralogy, 2009, 21(4):795-809. doi: 10.1127/0935-1221/2009/0021-1936
    Viana R R, Jordtevangelista H, Costa G M D, et al.Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais, Brazil[J].Physics and Chemistry of Minerals, 2002, 29(10):668-679. doi: 10.1007/s00269-002-0278-y
    Evensen J M.Beryllium in silicic magmas and the origin of beryl-bearing pegmatites[J].Reviews in Mineralogy & Geochemistry, 2002, 50(1):445-486. http://www.mendeley.com/research/beryllium-silicic-magmas-origin-berylbearing-pegmatites/
    Sabot B.Fluid inclusions in Ianapera emerald, Southern Madagasca[J].International Geology Review, 2005, 47(6):647-662. doi: 10.2747/0020-6814.47.6.647
    Moore T P. Emeralds of the World[M]//Mineralogical Record. 2003: 10-23, 25-33, 74-78.
    Groat L A, Giuliani G, Marshall D D, et al.Emerald deposits and occurrences:A review[J].Ore Geology Reviews, 2008, 34(1-2):87-112. doi: 10.1016/j.oregeorev.2007.09.003
    Groat L A, Marshall D D, Giuliani G, et al.Mineralogical and geochemical study of the Regal Ridge emerald showing, Southeastern Yukon[J].Canadian Mineralogist, 2002, 40(5):1313-1338. doi: 10.2113/gscanmin.40.5.1313
    Cheilletz A, Féraud G, Giuliani G, et al.Time-pressure and temperature constraints on the formation of Colombian emeralds:An 40Ar/39Ar laser microprobe and fluid inclusion study[J].Economic Geology, 1994, 89:361-380. doi: 10.2113/gsecongeo.89.2.361
    代鸿章, 王登红, 王成辉, 等.中央造山带秦巴地区发现石英脉型黑钨矿[J].岩矿测试, 2017, 36(5):559-560. doi: 10.15898/j.cnki.11-2131/td.201709040137

    Dai H Z, Wang D H, Wang C H, et al.New discovery of quartz vein-type of wolframite ores in the Qinling-Daba area, Central Orogenic Belt, China[J].Rock and Mineral Analysis, 2017, 36(5):559-560. doi: 10.15898/j.cnki.11-2131/td.201709040137
    许乃岑, 沈加林, 张静.X射线衍射-X射线荧光光谱-电子探针等分析测试技术在玄武岩矿物鉴定中的应用[J].岩矿测试, 2015, 34(1):75-81. doi: 10.15898/j.cnki.11-2131/td.2015.01.010

    Xu N C, Shen J L, Zhang J.Application of X-ray diffraction, X-ray fluorescence spectrometry and electron microprobe in the identification of basalt[J].Rock and Mineral Analysis, 2015, 34(1):75-81. doi: 10.15898/j.cnki.11-2131/td.2015.01.010
    刘永先, 范洪斌.云南祖母绿特征及开发利用初探[J].矿产综合利用, 1997(6):22-25. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199704007.htm

    Liu Y X, Fan H B.A preliminary study on the characteristics and exploitation and utilization of emeralds in Yunnan[J].Multipurpose Utilization of Mineral Resources, 1997(6):22-25. http://www.cnki.com.cn/Article/CJFDTOTAL-YNZD199704007.htm
    王濮, 潘兆橹, 翁玲宝, 等.统矿物学(中册)[M].北京:地质出版社, 1982:155-156.

    Wang P, Pan Z L, Weng L B, et al.Systematic Mineralogy (Volume 2)[M].Beijing:Geological Publishing House, 1982:155-156.
    Aurisicchio C, Fioravanti G, Grubessi O, et al.Reappra-isal of the crystal chemistry of beryl[J].American Minealogist, 1988, 73:826-837. http://rruff.info/doclib/hom/beryl.pdf
    黄文清, 倪培, 水汀, 等.云南麻栗坡祖母绿的矿物学特征研究[J].岩石矿物学杂志, 2015, 34(1):103-109. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yskwxzz201501009

    Huang W Q, Ni P, Shui T, et al.Mineralogical characteristics of emerald from Malipo, Yunnan Province[J].Acta Petrologica et Mineralogica, 2015, 34(1):103-109. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yskwxzz201501009
    任伟, 汪立今, 李甲平.电子探针和X射线衍射仪测定新疆祖母绿宝石[J].岩矿测试, 2010, 29(2):179-181. http://www.ykcs.ac.cn/article/id/5a9e1771-8bd3-42f9-b2fc-d5fe67a5c11f

    Ren W, Wang L J, Li J P. Detection of emerald from Xinjiang by electron probe microanalyzer and X-ray diffractometer[J].Rock and Mineral Analysis, 2010, 29(2):179-181. http://www.ykcs.ac.cn/article/id/5a9e1771-8bd3-42f9-b2fc-d5fe67a5c11f
    JCPDS. International Center for Diffraction Data[Z]. [PDF#09-0430], 1988.
    Schwartz D, Giuliani G.Emerald deposits:A review[J].Australian Gemmologist, 2001, 1:17-23. http://www.documentation.ird.fr/hor/fdi:010034445
    Vapnik Y, Moroz I, Roth M, et al.Formation of emeralds at pegmatite-ultramafic contacts based on fluid inclusions in Kianjavato emerald, Mananjary deposits, Madagascar[J].Mineralogical Magazine, 2006, 70:141-158. doi: 10.1180/0026461067020320
    汪立今, 彭雪峰, 李甲平, 等.新疆祖母绿(绿柱石)矿产出地质特征与找矿矿物学[J].矿物学报, 2011, 31(3):604-608. http://industry.wanfangdata.com.cn/dl/Magazine?magazineId=kwxb&yearIssue=2011_3

    Wang L J, Peng X F, Li J P, et al.A study on basic geological characteristics and mineralogy of ore prospecting in Xinjiang emerald (beryl) deposit[J].Acta Mineralogica Sinica, 2011, 31(3):604-608. http://industry.wanfangdata.com.cn/dl/Magazine?magazineId=kwxb&yearIssue=2011_3
    Dai H Z, Wang D H, Wang C H, et al.Re-Os isotopic dating of a W-Be polymetallic deposit in the Southern Qinling Region, China[J].Acta Geologica Sinica (English Edition), 2018, 92(1):414-415. doi: 10.1111/acgs.2018.92.issue-1
    刘茜. 陕西镇安钨矿床特征及成因研究[D]. 北京: 中国地质大学(北京), 2013. http://cdmd.cnki.com.cn/Article/CDMD-11415-1013270343.htm

    Liu Q. The Characterisitcs and Genesis of the Zhen'an W Deposit, Shannxi Province, China[D]. Beijing: China University of Geoscinces (Beijing), 2013. http://cdmd.cnki.com.cn/Article/CDMD-11415-1013270343.htm
    盛继福, 王登红.中国矿产地质志·钨矿卷[M].北京:地质出版社(待出版), 2018.

    Sheng J F, Wang D H.China's Mineral Geology (Tungsten Ore Volume)[M].Beijing:Geological Publishing House, 2018(in press).
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