Rapid Determination of Soil Cation Exchange Capacity by Automatic Kjeldahl Analyzer after Oscillating Exchange and Suction Filtration

Yi-fei MA; Ni ZHANG; Zeng WEI; Wen-xu GAO; Kui WANG

doi:10.15898/j.cnki.11-2131/td.201712110191

Rock and Mineral Analysis > 2019 > 38(1): 129-135. > DOI: 10.15898/j.cnki.11-2131/td.201712110191

Yi-fei MA, Ni ZHANG, Zeng WEI, Wen-xu GAO, Kui WANG. Rapid Determination of Soil Cation Exchange Capacity by Automatic Kjeldahl Analyzer after Oscillating Exchange and Suction Filtration[J]. Rock and Mineral Analysis, 2019, 38(1): 129-135. DOI: 10.15898/j.cnki.11-2131/td.201712110191

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Rapid Determination of Soil Cation Exchange Capacity by Automatic Kjeldahl Analyzer after Oscillating Exchange and Suction Filtration

1.
Xi'an Northwest Geological Institute for Nonferrous Metals Co., LTD., Xi'an 710054, China
2.
Institute of Analytical Science, Northwest University; Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry, Xi'an 710069, China

More Information

Received Date: December 11, 2017
Revised Date: April 25, 2018
Accepted Date: July 05, 2018
Published Date: December 31, 2018

Abstract

HIGHLIGHTS
(1) Sufficient cation exchange between the sample and ammonium acetate solution can be completed by oscillating for 25min.

(2) Extra ammonium ions can be removed quickly by vacuum filtration.

(3) The analysis of one batch sample (100 pieces) takes only 12 hours.

ABSTRACT

BACKGROUNDThe industry criteria of determination of soil cation exchange capacity (CEC) (LY/T1243-1999)uses centrifugal separation combined with manual distillation and titration, which is complex and time consuming.
OBJECTIVESDetermination of soil cation exchange capacity by automatic Kjeldahl analyzer after oscillating exchange and vacuum filtration.
METHODSThe acidic and neutral soils were treated with ammonium acetate, the calcareous soil was treated with ammonium chloride-ammonium acetate, and the cations were quickly exchanged and cleaned by shaking and by using suction filtration equipment, and adsorbed by a fully automatic Kjeldahl analyzer. The ammonium ion was measured to calculate the CEC value.
RESULTSThe experimental results show that, under the optimized oscillation and distillation, concentration of titration acid and ratio of indicator conditions, the analysis of one batch sample (100 pieces) only takes 12 hours. Compared with traditional methods, the detection time is shortened by nearly 80%. The results of national standard materials determined by the proposed method are in accordance with the certified values, the relative standard deviation is less than 1.5% (n=5).
CONCLUSIONSThe method eliminates multiple centrifugation operations, solves the problem of low component loss and CEC measurement value deviations, and improves detection efficiency and accuracy. This method has a lower cost than the forestry standard method, and has high operability and is suitable for analysis of large-scale soil samples such as environmental quality assessment and regional soil sampling surveys.
- oscillation,
- leaching,
- fully automatic Kjeldahl analyzer,
- ammonium acetate,
- ammonium chloride-ammonium acetate,
- soil,
- cation exchange capacity

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References (19)

References

黄尚书, 叶川, 钟义军, 等.不同土地利用方式对红壤坡地土壤阳离子交换量及交换性盐基离子的影响[J].土壤与作物, 2016, 5(2):72-77. http://d.old.wanfangdata.com.cn/Periodical/tryzw201602002

Huang S S, Ye C, Zhong Y J, et al.Soil cation exchange capacity and exchangeable base cations as affected by land use pattern in sloping farmland of red soil[J].Soils and Crops, 2016, 5(2):72-77. http://d.old.wanfangdata.com.cn/Periodical/tryzw201602002

胡清菁, 张超兰, 靳振江, 等.铅锌矿尾砂重金属污染物对不同土地利用类型土壤性质影响的典范对应分析[J].岩矿测试, 2014, 33(5):714-722. doi: 10.3969/j.issn.0254-5357.2014.05.016

Hu Q J, Zhang C L, Jin Z J, et al.Canonical correspondence analysis for soil properties and heavy metal pollution from Pb-Zn mine tailings in different land use types[J].Rock and Mineral Analysis, 2014, 33(5):714-722. doi: 10.3969/j.issn.0254-5357.2014.05.016

Fang K, Kou D, Wang G Q, et al.Decreased soil cation exchange capacity across northern China's grasslands over the last three decade[J].Journal of Geophysical Research-Biogeosciences, 2017, 122(11):3088-3097. doi: 10.1002/jgrg.v122.11

Aranda V, Oyonarte C.Characteristics of organic matter in soil surface horizons derived from calcareous and metamorphic rocks and different vegetation types from the mediterranean high-mountains in SE Spain[J].Soil Biology, 2006(42):247-258. https://www.sciencedirect.com/science/article/abs/pii/S1164556306000185

Dawid J, Dorota K.A comparison of methods for the de-termination of cation exchange capacity of soils[J].Ecological Chemistry & Engineering S, 2014, 21(3):487-498.

王文艳, 张丽萍, 刘俏.黄土高原小流域土壤阳离子交换量分布特征及影响因子[J].水土保持学报, 2012, 26(5):123-127. http://d.old.wanfangdata.com.cn/Periodical/trqsystbcxb201205025

Wang W Y, Zhang L P, Liu Q.Distribution and affecting factors of soil cation exchange capacity in watershed of the loess plateau[J].Journal of Soil and Water Conservation, 2012, 26(5):123-127. http://d.old.wanfangdata.com.cn/Periodical/trqsystbcxb201205025

沈纯怡, 邢伟银.快速检测土壤阳离子交换量的研究[J].中国土壤与肥料, 2016(5):144-147. http://d.old.wanfangdata.com.cn/Periodical/trfl201605029

Shen C Y, Xing W Y.Research on the rapid determination of cation exchange capacity in soil[J].Soil and Fertilizer Sciences in China, 2016(5):144-147. http://d.old.wanfangdata.com.cn/Periodical/trfl201605029

周圆, 卞世闻, 张宇.凯氏定氮仪测定土壤阳离子交换量的方法改进[J].环境科学导刊, 2015, 34(6):106-109. doi: 10.3969/j.issn.1673-9655.2015.06.027

Zhou Y, Bian S W, Zhang Y.Method improvement of detecting soil CEC by Kieldahl's azotometer[J].Environmental Science Survey, 2015, 34(6):106-109. doi: 10.3969/j.issn.1673-9655.2015.06.027

拉毛吉, 王玉功, 张榕.乙酸铵离心交换法和乙酸钙离心交换法测定土壤阳离子交换量[J].中国无机分析化学, 2017, 7(3):38-41. doi: 10.3969/j.issn.2095-1035.2017.03.010

La M J, Wang Y G, Zhang R.Determination of cation exchange capacity of soil by centrifugal exchange of ammonium and calcium acetates[J].Chinese Journal of Inorganic Analytical Chenistry, 2017, 7(3):38-41. doi: 10.3969/j.issn.2095-1035.2017.03.010

葛艳梅, 李亚.膨润土测定阳离子交换量缩合滴定和凯式蒸馏滴定方法的比对[J].当代化工, 2016, 45(7):1558-1559. doi: 10.3969/j.issn.1671-0460.2016.07.071

Ge Y M, Li Y.Delemination of cation exchange capacity of bentonite condensation titration and Kjeldahl distillation titration method comparison[J].Contemporary Chemical Industry, 2016, 45(7):1558-1559. doi: 10.3969/j.issn.1671-0460.2016.07.071

窦蓓蕾, 张沛, 田渭花.陕西地区土壤阳离子交换量(CEC)测定方法研究[J].安徽农学通报, 2015, 21(22):65-66. doi: 10.3969/j.issn.1007-7731.2015.22.029

Dou B L, Zhang P, Tian W H.The determination method of soil cationic exchange capacity in Shaanxi area[J].Anhui Agricultural Science Bulletin, 2015, 21(22):65-66. doi: 10.3969/j.issn.1007-7731.2015.22.029

张彦雄, 李丹, 张佐玉, 等.两种土壤阳离子交换量测定方法的比较[J].贵州林业科技, 2010, 38(2):45-49. http://d.old.wanfangdata.com.cn/Periodical/gzlykj201002011

Zhang Y X, Li D, Zhang Z Y, et al.A comparison study of two methods for measurement of soil cation exchange capacity[J].Guizhou Forestry Science and Technology, 2010, 38(2):45-49. http://d.old.wanfangdata.com.cn/Periodical/gzlykj201002011

Khorshidi M, Lu N.Determination of cation exchange capacity from soil water retention curve[J].Journal of Engineering Mechanics, 2017, 143(6):04017023. doi: 10.1061/(ASCE)EM.1943-7889.0001220

魏昌龙, 赵玉国, 李德成, 等.基于相似光谱匹配预测土壤有机质和阳离子交换量[J].农业工程学报, 2014, 30(1):81-88. doi: 10.3969/j.issn.1002-6819.2014.01.011

Wei C L, Zhao Y G, Li D C, et al.Prediction of soil organic matter and cation exchange capacity based on spectral similarity measuring[J].Transactions of the Chinese Society of Agricultural Engineering, 2014, 30(1):81-88. doi: 10.3969/j.issn.1002-6819.2014.01.011

方利民, 冯爱明, 林敏.可见/近红外光谱快速测定土壤中的有机碳含量和阳离子交换量[J].光谱学与光谱分析, 2010, 30(2):327-330. doi: 10.3964/j.issn.1000-0593(2010)02-0327-04

Fang L M, Feng A M, Lin M.Rapid prediction of total organic carbon content and CEC in soil using visible/near infrared spectroscopy[J].Spectroscopy and Spectral Analysis, 2010, 30(2):327-330. doi: 10.3964/j.issn.1000-0593(2010)02-0327-04

杨乐苏.ICP-AES直接测定土壤中多种交换性阳离子组成[J].广东林业科技, 2008, 24(6):20-23. doi: 10.3969/j.issn.1006-4427.2008.06.004

Yang L S.Directly determining the exchangeable cations in soil by ICP-AES[J].Guangdong Forestry Science and Technology, 2008, 24(6):20-23. doi: 10.3969/j.issn.1006-4427.2008.06.004

张玉革, 肖敏, 董怡华.乙酸铵浸提原子吸收光谱法同时测定土壤交换性盐基离子组成[J].光谱学与光谱分析, 2012, 32(8):2242-2245. doi: 10.3964/j.issn.1000-0593(2012)08-2242-04

Zhang Y G, Xiao M, Dong Y H.Determination of soil exchangeable base cations by using atomic absorption spectrophotometer and extraction with ammonium acetate[J].Spectroscopy and Spectral Analysis, 2012, 32(8):2242-2245. doi: 10.3964/j.issn.1000-0593(2012)08-2242-04

褚龙, 贺斌.土壤阳离子交换量的测定方法[J].黑龙江环境通报, 2009, 33(1):81-83. http://d.old.wanfangdata.com.cn/Periodical/hljhjtb200901034

Chu L, He B.Determining method of soil cation exchange capacity[J].Heilongjiang Environmental Journal, 2009, 33(1):81-83. http://d.old.wanfangdata.com.cn/Periodical/hljhjtb200901034

李荃.K9840自动凯氏定氮仪测定阳离子交换量[J].世界有色金属, 2017(17):284-285. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QKC20172017112900027125

Li Q.K9840 automatic Kjeldahl apparatus used to determine the cation exchange capacity[J].World Nonferrous Metals, 2017(17):284-285. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QKC20172017112900027125

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Rapid Determination of Soil Cation Exchange Capacity by Automatic Kjeldahl Analyzer after Oscillating Exchange and Suction Filtration

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Rapid Determination of Soil Cation Exchange Capacity by Automatic Kjeldahl Analyzer after Oscillating Exchange and Suction Filtration

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