Determination of 18 Minor Elements in the Structural Superimposed Halo Samples from Gold Deposits by Wavelength Dispersive X-ray Fluorescence Spectrometry with Pressed-powder Pellets

Feng-feng XIU; Yong FAN; Jun-yu LI; Yi-jie ZHU

doi:10.15898/j.cnki.11-2131/td.201704170061

Rock and Mineral Analysis > 2018 > 37(5): 526-532. > DOI: 10.15898/j.cnki.11-2131/td.201704170061

Feng-feng XIU, Yong FAN, Jun-yu LI, Yi-jie ZHU. Determination of 18 Minor Elements in the Structural Superimposed Halo Samples from Gold Deposits by Wavelength Dispersive X-ray Fluorescence Spectrometry with Pressed-powder Pellets[J]. Rock and Mineral Analysis, 2018, 37(5): 526-532. DOI: 10.15898/j.cnki.11-2131/td.201704170061

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Determination of 18 Minor Elements in the Structural Superimposed Halo Samples from Gold Deposits by Wavelength Dispersive X-ray Fluorescence Spectrometry with Pressed-powder Pellets

Geophysical Exploration Academy of China Metallurgical Geology Bureau, Baoding 071051, China

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Received Date: April 16, 2017
Revised Date: December 06, 2017
Accepted Date: March 20, 2018
Published Date: August 31, 2018

Abstract

HIGHLIGHTS
(1) There is little report on the application of Wavelength Dispersive X-ray Fluorescence Spectrometry (XRF) in structural superimposed halo samples.

(2) The suitable spectral lines and accuracy of analytical results can be selected and improved through the study of sample angle scanning.

(3) The method can rapidly and accurately determine the contents of all elements in structural superimposed halo samples of gold deposits.

ABSTRACT

BACKGROUNDElements As, Sb, Bi, Ag, Sn, W, Mo, Cu, Pb, Zn, Co, Cr, Ni, Ti, V, Mn, Sr and Ba in structural superimposed halo samples of gold deposits were of significance to the multi-phases and multi-stage mineralization of the gold deposits. This kind of sample is collected in the gold mine. The content of each element is very different and the distribution is uneven, from the ppm level to a few percent.
OBJECTIVESTo overcome the problems of conventional detection methods, such as difficult to eliminate inter-element interference and serious memory effects.
METHODSThe contents of 18 elements in structural superimposed haloes of gold ore were studied by pressed-powder pellets Wavelength Dispersive XRF.
RESULTSBy studying the angle scanning chart, the analysis line with least interference and high intensity is selected, and the segregation effect is eliminated by fully mixing the sample. The detection limits of this method are 0.14-2.23 μg/g, and the precision (RSD, n=12) is less than 4%.
CONCLUSIONSThe method can rapidly and accurately determine the contents of all elements in structural superimposed halo samples of gold deposits.

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References (25)

References

李惠, 张国义, 禹斌.金矿区深部盲矿预测的构造叠加晕模型及找矿效果[M].北京:地质出版社, 2006:27.

Li H, Zhang G Y, Yu B.Structural Superposition Halo Model and Ore Finding Effect in the Prediction of Deep Blind Ore Deposits in Gold Deposits[M].Beijing:Geological Publishing House, 2006:27.

李惠, 禹斌, 李德亮.构造叠加晕找盲矿法及找矿效果[M].北京:地质出版社, 2008:14-20.

Li H, Yu B, Li D L.Blind Ore Prospecting Method with Structural Superposition Halo and Its Ore Finding Effect[M].Beijing:Geological Publishing House, 2008:14-20.

李惠, 禹斌, 李德亮, 等.构造叠加晕法预测盲矿的关键技术[J].物探与化探, 2014, 38(2):189-193. http://d.old.wanfangdata.com.cn/Periodical/wtyht201402001

Li H, Yu B, Li D L, et al.The key technology of predicting blind ore by structural superposition halo method[J].Geophysical and Geochemical Exploration, 2014, 38(2):189-193. http://d.old.wanfangdata.com.cn/Periodical/wtyht201402001

李惠, 禹斌, 李德亮, 等.成矿区带构造叠加晕找矿预测新方法[J].物探与化探, 2013, 37(2):189-193. http://d.old.wanfangdata.com.cn/Conference/7610910

Li H, Yu B, Li D L, et al.A new prognostic method using structure superimposed halo in regional metallogenic belt[J].Geophysical and Geochemical Exploration, 2013, 37(2):189-193. http://d.old.wanfangdata.com.cn/Conference/7610910

Galina V P, Tatyana S A, Alexander I F, et al.Analytical approaches for determination of bromine in sediment core samples by X-ray fluorescence spectrometry[J].Talanta, 2016, 160:375-380. doi: 10.1016/j.talanta.2016.07.059

吉昂.X射线荧光光谱三十年[J].岩矿测试, 2012, 31(3):383-398. doi: 10.3969/j.issn.0254-5357.2012.03.002

Ji A.Development of X-ray fluorescence spectrometry in the 30 years[J].Rock and Mineral Analysis, 2012, 31(3):383-398. doi: 10.3969/j.issn.0254-5357.2012.03.002

夏鹏超, 李明礼, 王祝, 等.粉末压片制样波长色散X射线荧光谱法测定斑岩型钼铜矿中主次量元素钼铜铅锌砷硫[J].岩矿测试, 2012, 31(3):468-472. doi: 10.3969/j.issn.0254-5357.2012.03.016

Xia P C, Li M L, Wang Z, et al.Determination of major and minor elements of Mo, Cu, Pb, Zn, As, Ni and S in the porphyry type lindgrenite by wavelength dispersive X-ray fluorescence spectrometry with pressed-powder pellets[J].Rock and Mineral Analysis, 2012, 31(3):468-472. doi: 10.3969/j.issn.0254-5357.2012.03.016

刘江斌, 段九存, 党亮.X射线荧光光谱法同时测定铝土矿中主次组分及3种痕量元素[J].理化检验(化学分册), 2011, 47(10):1211-1216. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK201103991166

Liu J B, Duan J C, Dang L.X-ray spectrometry determination of major, minor components and 3 trace elements in bauxites[J].Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2011, 47(10):1211-1216. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK201103991166

李清彩, 赵庆令.粉末压片制样波长色散X射线荧光谱法测定钼矿石中9种元素[J].岩矿测试, 2014, 33(6):839-843. http://www.ykcs.ac.cn/article/id/ykcs_20110421

Li Q C, Zhao Q L.Determination of 9 elements in molybdenum ore by wavelength dispersive X-ray fluorescence spectrometry with powder pelleting preparation[J].Rock and Mineral Analysis, 2014, 33(6):839-843. http://www.ykcs.ac.cn/article/id/ykcs_20110421

李小莉, 张勤.粉末压片-X射线荧光谱法测定土壤, 水系沉积物和岩石样品中15种稀土元素[J].治金分析, 2013, 33(7):35-40.

Li X L, Zhang Q.Determination of fifteen rare earth elements in soil, stream sediment and rock samples by X-ray fluorescence spectrometry with pressed powder pellet[J].Metallurgical Analysis, 2013, 33(7):35-40.

郑荣华, 刘建坤.粉末压片-X射线荧光谱法测定矿石中钨, 锡[J].理化检验(化学分册), 2013, 49(1):66-68.

Zhen R H, Liu J K.Determination of tungsten and tin in ores with preparation of disc sample from its powder by pressing by X-ray fluorescence spectrometry[J].Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2013, 49(1):66-68.

段家华, 马林泽, 张李斌.压片制样-X射线荧光光谱法测定高磷钢渣组分[J].冶金分析, 2013, 33(5):36-40. doi: 10.3969/j.issn.1000-7571.2013.05.008

Duan J H, Ma L Z, Zhang L B.Determination of components in high-phosphorus steel slag X-ray fluorescence spectrometry with tabletting sample preparation[J].Metallurgical Analysis, 2013, 33(5):36-40. doi: 10.3969/j.issn.1000-7571.2013.05.008

李强, 张学华.粉末压片-X射线荧光光谱法快速分析多金属结核和富钴结壳中22种组分[J].冶金分析, 2014, 34(1):28-33. http://d.old.wanfangdata.com.cn/Periodical/yjfx201401005

Li Q, Zhang X H.Rapid determination of twenty-two components in polymetallic nodule and cobalt-rich crusts by X-ray fluorescence spectrometry with pressed powder pellet[J].Metallurgical Analysis, 2014, 34(1):28-33. http://d.old.wanfangdata.com.cn/Periodical/yjfx201401005

陈静.X射线荧光光谱法测定地质样品中铌和钽的探讨[J].冶金分析, 2015, 35(10):24-29. http://d.old.wanfangdata.com.cn/Periodical/yjfx201510005

Chen J.Discussion on the determination of niobium and tantalum in geological samples by X-ray fluorescence spectrometry[J].Metallurgical Analysis, 2015, 35(10):24-29. http://d.old.wanfangdata.com.cn/Periodical/yjfx201510005

李先和, 万双, 刘子健, 等.X射线荧光光谱法测定铜精矿中10种元素[J].冶金分析, 2016, 36(6):55-59. http://d.old.wanfangdata.com.cn/Periodical/yjfx201606011

Li X H, Wan S, Liu Z J, et al.Determination of ten elements in copper concentrate by X-ray fluorescence spectrometry[J].Metallurgical Analysis, 2016, 36(6):55-59. http://d.old.wanfangdata.com.cn/Periodical/yjfx201606011

唐梦奇, 黎香荣, 罗明贵, 等.X射线荧光光谱法测定锌精矿中主次量成分[J].冶金分析, 2012, 32(7):55-58. doi: 10.3969/j.issn.1000-7571.2012.07.012

Tang M Q, Li X R, Luo M G, et al.Determination of major and minor components in zinc concentrates by X-ray fluorescence spectrometry[J].Metallurgical Analysis, 2012, 32(7):55-58. doi: 10.3969/j.issn.1000-7571.2012.07.012

曾江萍, 张莉娟, 李小莉, 等.超细粉末压片-X射线荧光光谱法测定磷矿石中12种组分[J].冶金分析, 2015, 35(7):37-43. http://d.old.wanfangdata.com.cn/Periodical/yjfx201507007

Zeng J P, Zhang L J, Li X L, et al.Determination of twelve components in phosphate ore by X-ray fluorescence spectrometry with ultra-fine powder tabletting[J].Metallurgical Analysis, 2015, 35(7):37-43. http://d.old.wanfangdata.com.cn/Periodical/yjfx201507007

夏传波, 姜云, 郑建业, 等.X射线荧光光谱法测定地质样品中氯的含量[J].理化检验(化学分册), 2017, 53(7):775-779. http://d.old.wanfangdata.com.cn/Periodical/lhjy-hx201707006

Xia C B, Jiang Y, Zheng J Y, et al.X-ray fluorescence spectrometric determination of Chlorine in Geological Samples[J].Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2017, 53(7):775-779. http://d.old.wanfangdata.com.cn/Periodical/lhjy-hx201707006

卜兆杰, 蒋春宏, 陶泽秀, 等.粉末压片制样-X射线荧光光谱法测定稀土镁中间合金中镁锰硅钛钙铁[J].冶金分析, 2018, 38(3):61-64. http://d.old.wanfangdata.com.cn/Periodical/yjfx201803012

Bu Z J, Jiang C H, Tao Z X, et al.Determination of magnesium, manganese, silicon, titanium, calcium, iron in rare earth-magnesium intermediate alloy by X-ray fluorescence spectrometry with pressed powder pellet[J].Metallurgical Analysis, 2018, 38(3):61-64.. http://d.old.wanfangdata.com.cn/Periodical/yjfx201803012

朱纪夏, 李庆美.X射线荧光光谱法快速测定铁中硅锰硫磷钛[J].理化检验(化学分册), 2004, 40(4):233-236. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=lhjy-hx200404021

Zhu J X, Li Q M.Fast X-ray fluorescence spectrometric determination of parathion manganese titanium in pig iron[J].Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2004, 40(4):233-236. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=lhjy-hx200404021

吕善胜, 徐金龙, 曲强.理论系数法和经验系数法结合相结合校正——X射线荧光光谱法测定铁矿石中14种组分[J].冶金分析, 2016, 36(4):46-51. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yjfx201604011

Lü S S, Xu J L, Qu Q.Determination of fourteen components in iron ore by X-ray fluorescence spectrometry with theoretical α coefficient and empirical coefficient method correction[J].Metallurgical Analysis, 2016, 36(4):46-51. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yjfx201604011

孙晓飞, 文孟喜, 杨丹丹.康普顿散射结合经验系数法校正X射线荧光光谱法测定石灰石和白云石中的应用[J].冶金分析, 2016, 36(1):11-17. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yjfx201601003

Sun X F, Wen M X, Yang D D.Application of Compton scatter and empirical coefficient correction in X-ray fluorescence spectrometric determination of limestone and dolomite[J].Metallurgical Analysis, 2016, 36(1):11-17. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yjfx201601003

苏梦晓, 陆安军.电感耦合等离子体原子发射光谱法、X射线荧光光谱法和摄谱法测定地球化学样品中铜、铅、锌、镍的比较[J].冶金分析, 2015, 35(5):48-53. http://d.old.wanfangdata.com.cn/Periodical/yjfx201505009

Su M X, Lu A J.Comparison of inductively coupled plasma atomic emission spectrometry and spectrographic method for the determination of copper, lead, zinc, and nickel in geochemical samples[J].Metallurgical Analysis, 2015, 35(5):48-53. http://d.old.wanfangdata.com.cn/Periodical/yjfx201505009

卢艳蓉, 尹明兰, 杨龙莲.碱熔融氢化物发生-原子荧光光谱法测定铁矿石中铋[J].冶金分析, 2014, 34(12):57-61. http://d.old.wanfangdata.com.cn/Periodical/yjfx201412012

Lu Y R, Yin M L, Yang L L.Determination of bismuth in iron ore by alkali fusion hydride generation-atomic fluorescence spectrometry[J].Metallurgical Analysis, 2014, 34(12):57-61. http://d.old.wanfangdata.com.cn/Periodical/yjfx201412012

袁水海, 尹昌慧, 元志线, 等.氢化物发生-原子荧光光谱法同时测定锡矿石中砷和锑[J].冶金分析, 2016, 36(3):39-43. http://d.old.wanfangdata.com.cn/Periodical/yjfx201603009

Yuan S H, Yin C H, Yuan Z X, et al.Determination of arsenic and antimony in tin ore by hydride generation-atomic fluorescence spectrometry[J]. Metallurgical Analysis, 2016, 36(3):39-43. http://d.old.wanfangdata.com.cn/Periodical/yjfx201603009

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Determination of 18 Minor Elements in the Structural Superimposed Halo Samples from Gold Deposits by Wavelength Dispersive X-ray Fluorescence Spectrometry with Pressed-powder Pellets

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