Preparation of Certified Reference Materials of Sillimanite for Chemical Composition Analysis

Chun-xue XU; Ya-ping WANG; Xu ZHANG; Bo DONG; De-zhong SUN; Zi-yi AN

doi:10.15898/j.cnki.11-2131/td.201608190123

Rock and Mineral Analysis > 2017 > 36(4): 396-404. > DOI: 10.15898/j.cnki.11-2131/td.201608190123

Chun-xue XU, Ya-ping WANG, Xu ZHANG, Bo DONG, De-zhong SUN, Zi-yi AN. Preparation of Certified Reference Materials of Sillimanite for Chemical Composition Analysis[J]. Rock and Mineral Analysis, 2017, 36(4): 396-404. DOI: 10.15898/j.cnki.11-2131/td.201608190123

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Preparation of Certified Reference Materials of Sillimanite for Chemical Composition Analysis

1.
National Research Center for Geoanalysis, Beijing 100037, China
2.
Institute of Geology and Mineral Resources Testing & Application of Heilongjiang Province, Harbin 150036, China

More Information

Received Date: August 18, 2016
Revised Date: February 06, 2017
Accepted Date: February 14, 2017
Published Date: March 31, 2017

Abstract

Highlights
· Three new sillimanite standard materials (CRMs) were reported and have been approved as the national standard materials.

· Certified values and uncertainties of 39 components, including major elements and trace elements were given in the three sillimanite CRMs. The measurable components can meet the needs of different users.

· The sillimanite CRMs tried to establish traceability of sillimanite analysis in ores.

ABSTRACT

With an increasing utilization of sillimanite, some reference materials of sillimanite for chemical composition have been developed in countries such as the UK, South Africa and Japan. In China, there is only one national secondary standard material for chemical compositon of sillimanite. It is difficult to meet the research needs of the country in terms of the concentration gradient range and the value index. For this study, two sillimanite ores were collected from Linkou county in Heilongjiang and Leijiang county in Henan, and one sillimanite concentrate was collected from Linkou county in Heilongjiang. According to national primary reference materials specifications, 3 sillimanite CRMs have been developed and approved as national standard reference materials (GBW07843, GBW07844, GBW07845). For the homogeneity test, the calculated F values in 3 sillimanite CRMs obtained by analysis of variance (ANOVA) were less than the critical F values at the 95% confidence level, with the exception of TFe₂O₃ and Cu in Y-1, and MnO in J-1, indicating no obvious differences between units and within units. The differences of TFe₂O₃ and Cu in Y-1 and MnO in J-1 between units and within units resulted from the error in the analytical methods. The results showed that 3 sillimanite CRMs had good homogeneity. The calculated test statistic b₁ of 3 sillimanite CRMs during the 14-month observation period was statistically insignificant, indicating that 3 sillimanite CRMs were stable. 10 qualified laboratories were selected to give certified values and uncertainties of 39 components, including major elements, trace elements and sillimanite phases in ores. The relative expanded uncertainties of 39 components range from 0.60% to 29.9%. The content of Al₂O₃ in sillimanite reference materials is 25.85%, 28.16%, 55.06% for GBW07843, GBW07844, and GBW07845, respectively. 3 sillimanite CRMs meet the monitoring requirements of chemical composition analysis for sillimanite samples in geology and environment fields.
- sillimanite,
- chemical composition analysis,
- phase analysis,
- reference material,
- certified value

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