An Amino-functionalized Covalent Organic Framework Coating for Highly Efficient Solid Phase Microextraction of Trace Phenols in Water

TAO Hui; HUANG Lijin; OUYANG Lei; SHUAI Qin

doi:10.15898/j.cnki.11-2131/td.202204190084

Rock and Mineral Analysis > 2022 > 41(6): 1040-1049. > DOI: 10.15898/j.cnki.11-2131/td.202204190084

TAO Hui, HUANG Lijin, OUYANG Lei, SHUAI Qin. An Amino-functionalized Covalent Organic Framework Coating for Highly Efficient Solid Phase Microextraction of Trace Phenols in Water[J]. Rock and Mineral Analysis, 2022, 41(6): 1040-1049. DOI: 10.15898/j.cnki.11-2131/td.202204190084

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An Amino-functionalized Covalent Organic Framework Coating for Highly Efficient Solid Phase Microextraction of Trace Phenols in Water

Faculty of Materials and Chemistry, China University of Geosciences (Wuhan), Wuhan 430074, China

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Received Date: April 18, 2022
Revised Date: June 08, 2022
Accepted Date: June 24, 2022
Available Online: December 13, 2022

Abstract

HIGHLIGHTS
(1) Amino modified covalent organic framework materials were synthesized by one step solvent-free synthetic strategy using the reducing gas produced by high temperature decomposition of surfactant PF127.

(2) Amino functional groups can improve the extraction performance of materials toward phenolic compounds, whereas the nitro functional group is not conducive to the extraction of phenolic compounds.

(3) The high-sensitivity determination of phenolic compounds in water was realized using amino functionalized covalent organic frameworks as solid phase microextraction coating combined with GC-MS.

ABSTRACT

BACKGROUND
Phenolic compounds, as ubiquitous pollutants, should be effectively separated by sample pretreatment technology prior to analysis because of the low concentration, strong polarity and complex sample matrix. Solid phase microextraction (SPME) is a solvent-free pretreatment technology integrating sampling, enrichment and injection. Combined with gas chromatography-mass spectrometry (GC-MS), it can achieve the rapid enrichment and detection of trace organic compounds in a complex matrix.
OBJECTIVES
To develop a sensitive, simple, and environmentally friendly method for the determination of trace phenols.
METHODS
An amino functionalized covalent organic framework (TpPa-NH₂) was synthesized by a solvent-free method in one step. SPME was used as the coating, four kinds of phenolic compounds were used as target analytes, and a new method for the detection of phenolic compounds was established by headspace extraction mode combined with GC-MS.
RESULTS
The extraction performance of TpPa-NH₂ was 3-5 times that of TpPa-1. Under the optimum conditions, the established analysis method for four phenols had wide linear ranges (10-5.0×10⁴ng/L), high linear correlation coefficients (0.996-0.999), and low detection limits (1.30-5.35ng/L). Both the intra-fiber repeatability (RSD from 2.2%-9.2%) and inter-fiber reproducibility (RSD from 4.2%-8.9%) were satisfactory, and the coating can be reused more than 90 times.
CONCLUSIONS
The introduction of an amino group can effectively improve the extraction performance of TpPa for phenolic compounds. The established method establishes the sensitive, convenient and green detection of phenolic compounds in actual samples, demonstrating a good application prospect.
- phenolic compounds,
- solid phase microextraction,
- gas chromatography-mass spectrometry,
- covalent organic framework,
- functionalization

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References (39)

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