Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments

TIAN Qin; TONG Ling; AN Ziyi; XU Chunxue; SUN Huizhong; DIAO Jinling

doi:10.15898/j.cnki.11-2131/td.202110130149

Rock and Mineral Analysis > 2022 > 41(3): 511-520. > DOI: 10.15898/j.cnki.11-2131/td.202110130149

TIAN Qin, TONG Ling, AN Ziyi, XU Chunxue, SUN Huizhong, DIAO Jinling. Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments[J]. Rock and Mineral Analysis, 2022, 41(3): 511-520. DOI: 10.15898/j.cnki.11-2131/td.202110130149

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Development of Certified Reference Materials of Polycyclic Aromatic Hydrocarbons, Organochlorine Pesticides and Polychlorinated Biphenyls in Sediments

TIAN Qin^{1, 2,},
TONG Ling^1, ,,
AN Ziyi^{1, 2},
XU Chunxue^{1, 2},
SUN Huizhong^{1, 2},
DIAO Jinling³

1.
National Research Center for Geoanalysis, Beijing 100037, China
2.
Key Laboratory of Eco-geochemistry, Ministry of Natural Resources, Beijing 100037, China
3.
China Agricultural University, Beijing 100193, China

More Information

Received Date: October 12, 2021
Revised Date: December 07, 2021
Accepted Date: January 27, 2022
Available Online: July 28, 2022

Abstract

HIGHLIGHTS
(1) The certified reference materials of sediments from different stream systems of rivers and lakes in China have been developed. This series of reference materials not only have three kinds of certified values: 16 PAHs, 3 OCPs and 3 PCBs, but also have a wide content range from ng/g to μg/g levels, which meet the needs of different analyses.

(2) Nine laboratories used three analytical methods for collaborative analysis, including high-precision isotope dilution mass spectrometry, which ensured the accuracy of the certified values.

(3) The method of certified values, accuracy and uncertainty have achieved the level of research and development of similar reference materials in the world.

ABSTRACT

BACKGROUND
Polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) have teratogenic, carcinogenic and mutagenic effects, which are priority pollutants. The formulation of pollution investigation and treatment measures depends on accurate analysis and test data, and certified reference materials (CRMs) are an important guarantee for data quality control. However, the existing relevant reference materials cannot meet the actual needs of pollution monitoring in China.
OBJECTIVES
To prepare four CRMs of sediments for analysis of PAHs, OCPs and PCBs, and to meet the needs of environmental monitoring and scientific research for the monitoring of priority pollutants in China.
METHODS
In this study, according to the specifications of certified reference materials (JJF 1006—1994, JJF1343—2012 and JJF 1646—2017), 4 CRMs of PAHs, OCPs and PCBs in different sediments (GBW07352-GBW07355) have been developed for Chinese environmental monitoring and scientific research. In the development process, in order to solve the technical difficulties of the stability of organic compound reference materials, the effects of ⁶⁰Co sterilization and temperature on the stability of organic compounds were investigated. In view of the complex characteristics of the sediment sample matrix, different extraction and purification technologies were adopted to reduce or eliminate the influence of the complex matrix on the extraction solution and reduce the matrix effect of instrument measurement. Nine laboratories' collaborative analysis was carried out by using traditional methods including high performance liquid chromatography (HPLC), gas chromatography-electron capture detector (GC-ECD), gas chromatography-mass spectrometry (GC-MS) and new techniques of gas chromatography-isotope dilution mass spectrometry (GC-IDMS).
RESULTS
The sediment candidates have good homogeneity and stability. The certified values and expanded uncertainty for 16 PAHs, 3 OCPs and 3 PCBs are given, and the concentrations range from 9.0ng/g to 5.7μg/g, which meets the requirements of quality assurance and quality control for analysis of PAHs, OCPs and PCBs.
CONCLUSIONS
This series of reference materials has been approved as a national first-class reference material, numbered from GBW07352 to GBW07355. This series of CRMs can be used in analytical method validation, laboratory quality control, laboratory analysis ability assessment.

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