Simultaneous Determination of Trace Arsenic, Copper, Lead, Zinc, Nickel and Vanadium in Soils by Hydride Generation-Inductively Coupled Plasma-Optical Emission Spectrometry

HE Pan-hong; YANG Zhen; GONG Zhi-xiang

doi:10.15898/j.cnki.11-2131/td.201904160048

Rock and Mineral Analysis > 2020 > 39(2): 235-242. > DOI: 10.15898/j.cnki.11-2131/td.201904160048

HE Pan-hong, YANG Zhen, GONG Zhi-xiang. Simultaneous Determination of Trace Arsenic, Copper, Lead, Zinc, Nickel and Vanadium in Soils by Hydride Generation-Inductively Coupled Plasma-Optical Emission Spectrometry[J]. Rock and Mineral Analysis, 2020, 39(2): 235-242. DOI: 10.15898/j.cnki.11-2131/td.201904160048

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Simultaneous Determination of Trace Arsenic, Copper, Lead, Zinc, Nickel and Vanadium in Soils by Hydride Generation-Inductively Coupled Plasma-Optical Emission Spectrometry

1.
Henan Province Nuclear Industry Geology Bureau, Zhengzhou 450044, China
2.
Henan Radionuclide Detection Center of Nuclear Industry, Zhengzhou 450044, China
3.
School of Chemistry, Biology and Material Science, East China University of Technology, Fuzhou 344000, China

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Received Date: April 15, 2019
Revised Date: August 13, 2019
Accepted Date: October 20, 2019
Published Date: February 29, 2020

Abstract

HIGHLIGHTS
(1) Injection device for ICP-OES was improved to have the functions of introducing atomization gas, hydrogeneration reaction gas, and liquid discharge.

(2) The influence of coexisting ions and the interference of La and Dy on the determination of As were studied.

(3) HG and ICP-OES can be operated simultaneously for the simultaneous determination of As and multiple metal elements.

(4) The method provided a novel approach for the simultaneous determination of easy hydrogenation elements and multiple metal elements.

ABSTRACT

BACKGROUNDHydride generation-atomic fluorescence spectrometry (HG-AFS) is widely used for the determination of arsenic in soil. Inductively coupled plasma-optical emission spectrometry (ICP-OES) is widely used in the simultaneous determination of multiple elements, but the detection limit of arsenic is slightly higher. The combination of hydride generation technology and ICP-OES has been widely studied, which can greatly reduce the detection limit of arsenic and yield the simultaneous determination of arsenic, antimony, bismuth, mercury and other elements. However, the combination technology can only be used to determine easy hydrogenation elements but it cannot simultaneously determine easy hydrogenation elements and difficult hydrogenation elements.
OBJECTIVESTo obtain the simultaneous determination of arsenic and various metal elements in samples by one dissolved sample and one apparatus.
METHODSThe soil samples were dissolved by hydrofluoric acid, nitric acid, perchloric acid and hydrochloric acid, followed by the addition of thiourea ascorbic acid solution to reduce arsenic to +3, by using 10% hydrochloric acid as the dissolving medium. The elements were determined by double flow method at the same time.
RESULTSFor the coexisting ions in the solution, La and Dy higher than 1.0mg/L had interference on the determination of arsenic. These elements had no effect on the determination of arsenic, when K, Na, Ca, Mg, and Fe concentrations were lower than 50.0mg/L, Pb, Mo, Zn, Cu, Ba, Ti, Mn, Ni, Sr, V, when Cr concentrations were lower than 20.0mg/L, and Co, Ag, U, Cd, Li, Au concentrations were lower than 10.0mg/L.
CONCLUSIONSThis method improves the sensitivity of arsenic and has the advantages of multi-element simultaneous determination. It can simultaneously determine trace arsenic and difficult hydrogenation elements such as copper, lead, zinc, nickel, and vanadium. The relative standard deviation (RSD) of the method is less than 5%. This method is confirmed by soil standard materials and is proved to be reliable and suitable for the simultaneous determination of trace arsenic and other elements.
- soil,
- arsenic,
- metal elements,
- simultaneous determination,
- hydride-generation determination,
- inductively coupled plasma-optical emission spectrometry

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Simultaneous Determination of Trace Arsenic, Copper, Lead, Zinc, Nickel and Vanadium in Soils by Hydride Generation-Inductively Coupled Plasma-Optical Emission Spectrometry

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