The Pore Structure Characterization of Shale Based on Scanning Electron Microscopy and JMicroVision
-
摘要: 孔隙发育特征是泥页岩储集能力评价的关键参数之一。扫描电镜观察法已普遍用于描述泥页岩的孔隙发育特征，但是目前文献中对泥页岩微孔隙类型划分比较混乱，孔隙结构特征参数的表征以定性描述为主，缺乏定量表征手段。本文选取了18个泥页岩样品为研究对象，通过氩离子抛光和高分辨率扫描电子显微镜图像观察，基于孔隙发育形态、位置及成因，对样品中不同孔隙进行类型划分；结合JMicroVision图像分析软件，应用泥页岩微孔隙描述技术和孔隙尺度分类统计技术，统计不同类型孔隙发育数量、孔径大小、面孔率、形状系数、概率熵等参数，对其分布特征进行评价。研究表明，晶（粒）间孔隙和有机孔隙比较发育，其次为晶（粒）内孔和晶间隙。不同类型孔隙其孔径分布以纳米级为主，不同类型孔隙分布较无序，其概率熵主要分布在0.5~0.7之间，对应的形状系数分布差异也较大。有机质孔隙的形状系数主要分布在0.6~0.7范围内，形状分布以椭圆形或近似圆形为主，晶（粒）间孔隙和晶（粒）内孔隙的形状系数主要分布在0.3~0.7，分析晶（粒）间孔隙和晶（粒）内孔隙形状系数分布特征主要是受原始孔隙形态、压实作用和溶蚀作用的影响。研究认为，SEM与JMicroVision相结合是定量研究不同类型微孔发育特征的有效手段，为研究微孔的形成和演化奠定了基础。
-
关键词:
- 孔隙类型划分 /
- 孔隙结构表征 /
- 扫描电镜观察 /
- JMicroVision /
- 泥页岩
要点(1) 采用氩离子抛光和高分辨率扫描电镜，对泥页岩微孔隙发育特征进行观察。
(2) 基于发育形态、位置及成因，微孔隙被划分为有机孔隙、基质孔隙和微裂缝。
(3) 结合JMicroVision图像分析软件，定量分析评价孔隙结构特征参数分布特征。
HIGHLIGHTS(1) The characteristics of shale pore by using Ar-ion milling and Scanning Electron Microscopy were observated.
(2) The pores based on the morphology, development location and genesis were classified.
(3) Combined with JMicroVision, the distribution characteristics of pores parameters in shale were quantitatively analyzed.
Abstract:BACKGROUNDThe pore characteristics of shale are one of the key parameters for evaluation of the shale reservoir capacity. Scanning Electron Microscopy (SEM) has been widely used to describe the pore characteristics of shale. However, the classification of micro-pore types in mud shale reservoirs in the literature was relatively diverse, and the quantitative characterization of pore based on SEM was relatively lacking.OBJECTIVESTo classify the pore types and quantitatively characterize these pores in shale.METHODS18 shale samples were selected as the research object in this study. Based on the form, position and origin of pores observed by argon ion polishing and Scanning Electron Microscopy, the types of different pores in the sample were classified. By using JMicroVision image analysis software, the pore characteristics including the number of pore types, pore size, face rate, shape coefficient, probability entropy and other parameters were quantitatively described.RESULTSThe inter-crystal (particle) pores and organic pores were the most developed, followed by intra-crystal (particle) pores and crystal gap inter-crystal (particle) pores. The sizes of pore were mainly nanometer. The probabilistic entropy of intra-crystal (particle) pores and organic pores were mainly distributed between 0.5 and 0.7, with a different shape coefficient distribution. The shape coefficients of organic pores were mainly distributed between 0.6 and 0.7, and their shape were mainly oval or nearly circular. The shape coefficient of intra-crystal (particle) pores and inter-crystal (particle) pores were mainly between 0.3 and 0.7, which were mainly affected by the original pore morphology, compaction and dissolution.CONCLUSIONSThe combination of SEM and JMicroVision is an effective means to quantitatively study the development characteristics of different types of micropores. This work has laid a foundation for the study of the genesis and evolution of micropores.
-
石英脉型黑钨矿是钨矿的一个工业类型，因其质量优于白钨矿而一直作为战略性资源加以保护性开采[1]。国内外的大型、超大型钨矿床均以白钨矿为主[2]，而黑钨矿属于紧缺资源，其重要性等同于离子吸附型稀土矿。当前，黑钨矿主要产于中国的南岭地区，以赣南、粤北最为常见，并可见与绿柱石共生现象[3-5]。虽然近年来在江西北部也发现了大湖塘、朱溪等世界级超大型钨矿床，但含钨的矿石矿物仍是以白钨矿为主；前人曾提出“南钨北扩、东钨西扩”新认识[6]，但黑钨矿能不能“跨过长江”，一直是个疑问。
2012年以来，在陈毓川院士、盛继福等专家的指导下，项目组对陕西镇安一带的钨矿床开展了调查研究，在钻孔岩心首次发现石英脉中存在中-细晶黑钨矿与柱状晶体绿柱石共生的现象(图 1、图 2)。
![]()
图 1 陕西镇安W-Be矿区中石英脉见绿柱石和黑钨矿共生a—金云母片岩中发育切层石英脉，石英脉中见黑钨矿与绿柱石共生，发育团块状黄铁矿；b—石英脉中见黑钨矿与绿柱石共生，发育铬云母及细网脉状褐铁矿。Figure 1. Pictures showing wolframite intergrowth with beryl in quartz vein in Zhen'an W-Be mine, Shannxi Province![]()
图 2 陕西镇安某地黑钨矿反射光显微镜下特征a—黑钨矿反射光下呈板状晶体，麻点发育，与绿柱石及石英共生；b—同一视域下斜交偏光下见黑钨矿发育接触双晶。Wf—黑钨矿；Qtz—石英；Brl—绿柱石。Figure 2. Micrographs showing wolframite intergrowth with beryl in quartz vein in Zhen'an W-Be mine, Shannxi Province这一发现意义重大在于：一是黑钨矿可以出现在秦巴地区。秦巴地区作为中国中央造山带的核心部位，也是秦祁昆成矿域的核心部位，但一直没找到黑钨矿[1, 7-8]，此次可能是首次发现；二是石英脉型黑钨矿可以出现在典型的造山带。虽然白钨矿在秦岭早有发现，但主要是矽卡岩型和斑岩型，独立地产于围岩地层和构造破碎带中的石英脉型黑钨矿尚未见报道；三是出现新的矿种组合，指出了新的找矿方向。以往的白钨矿主要与钼矿共伴生，此次发现的黑钨矿出现在白钨矿与铍矿共伴生的矿区，即除了W-Mo组合之外，还存在W-Be组合；四是石英脉型黑钨矿的发现，对深部找矿指明了新的方向。秦巴地区的钨矿目前正在进行勘查，但主要分布在远离岩体的地方，或者“找不到成矿母岩”，如镇安东阳矿区。
由于石英脉型黑钨矿与花岗岩类关系密切，花岗岩体的查找是寻找此类钨矿的首要目标。石英脉型黑钨矿的发现，不但证明“南钨北扩”已经扩展至秦岭地区，还有可能出现在中条山[9]、太行山等，而且对深部找矿也指出了新的方向。
-
![]()
图 1 泥页岩储层孔隙特征描述照片
a—石英粒内微孔；b—黏土矿物粒内孔; c—片状伊蒙混层晶间孔；d—霉球状黄铁矿晶间孔；e—晶间隙；f—长石粒内溶孔；g—黏土矿物粒间溶孔；h—出油孔；i—出气孔；j—气孔群；k—有机质收缩缝；l—微裂缝。
Figure 1. Characteristics of pores in shale gas reservoir
![]()
图 3 不同类型孔隙的(a)孔径、(b)概率熵、(c)形状系数分布频率
Figure 3. Distribution frequency diagrams of (a) pore diameters, (b)probability entropy, (c)shape factor of different pores
![]()
图 4 晶(粒)间孔隙发育数量与黏土矿物相对含量关系
Figure 4. Relationship between the number of inter- crystal (particle) pores and the content of clay
![]()
图 5 有机质孔隙形状系数与有机质成熟度关系
Figure 5. Relationship between pore shape coefficient of organic matter and Ro
表 1 泥页岩样品的基本特性
Table 1 Characteristics of the selected shale samples
样品编号 TOC(%) Ro(%) 有机质类型 矿物含量(%) 石英 长石 碳酸盐 黏土矿物 黄铁矿 其他 1 3.576 1.21 Ⅱ1 20 15 6 44 8 7 2 4.337 1.96 Ⅱ1 24 12 3 49 9 3 3 2.045 1.16 Ⅱ1 25 24 13 31 4 3 4 6.435 2.29 Ⅱ1 20 12 3 56 5 4 5 5.892 1.21 Ⅱ1 21 17 3 48 3 8 6 5.198 1.26 Ⅱ1 20 22 6 45 6 1 7 2.740 1.38 Ⅱ1 51 0 4 37 6 2 8 2.697 3.27 Ⅰ 5 8 44 43 0 0 9 0.784 1.10 Ⅰ 30 10 20 40 0 0 10 3.199 1.11 Ⅱ1 24 14 5 51 4 2 11 2.541 1.18 Ⅱ1 24 30 2 38 2 4 12 3.496 1.08 Ⅰ 30 12 3 53 2 0 13 6.531 1.16 Ⅱ1 26 25 0 45 2 2 14 6.811 2.85 Ⅱ1 27 35 0 32 6 0 15 6.009 3.11 Ⅰ 23 25 5 41 6 0 16 1.398 1.01 Ⅰ 36 16 38 23 2 3 17 1.096 0.99 Ⅰ 27 18 7 39 5 4 18 2.240 0.97 Ⅰ 27 26 12 27 6 2 
下载: 导出CSV
表 2 泥页岩储层孔隙分类
Table 2 Characteristics of pore classification of shale gas reservoir
孔隙类型 成因机制 分布特征 无机孔隙 原生孔隙 晶(粒)内孔(图 1-a, b) 矿物成岩作用过程中保留下来的微孔隙 常见于黏土矿物颗粒、石英、长石等晶体内，形状不规则 无机孔隙 原生孔隙 晶(粒)间孔(图 1-c, d) 矿物颗粒沉积或再生长过程中保留下来微孔隙 常见于黏土矿物颗粒及黄铁矿等晶体间 无机孔隙 原生孔隙 晶间隙(图 1-e) 矿物(尤其是黏土矿物)成岩转化过程中形成的间隙 发育于矿物晶体层间或颗粒边缘，多呈片状分布 无机孔隙 次生孔隙 晶(粒)内溶孔(图 1-f)，晶(粒)间溶孔(图 1-g) 不稳定矿物因发生溶蚀作用而形成 常见于黏土矿物、长石等晶体内(间)，性状不规则 有机质孔 有机质热成因孔 出油孔(图 1-h)，出气孔(图 1-i)，气孔群(图 1-j) 有机质不同演化阶段生烃、排烃过程中，油气聚积形成 出油孔、出气孔偶见于热演化程度较低的有机质中，气孔群常见于热演化程度较高的有机质中，呈分散的不规则分布 有机质孔 收缩孔(缝)(图 1-k) 有机质热演化(失水)过程中收缩形成 有机质与矿物结合边缘或内部 微裂缝 构造缝(图 1-l) 由局部构造作用所形成，主要与矿物的成岩作用、岩石脆性、地层压力以及构造活动(如断裂、褶皱等)相关 呈高角度裂缝切层发育
下载: 导出CSV
-
Mastalerz M, Schimmelmann A, Drobniak A, et al.Porosity of Devonian and Mississippian New Albany Shale across a maturation gradient:Insights from organic petrology, gas adsorption, and mercury intrusion[J].AAPG Bulletin, 2013, 97(10):1621-1643. doi: 10.1306/04011312194
王香增, 张金川, 曹金舟, 等.陆相页岩气资源评价初探:以延长直罗-下寺湾区中生界长7段为例[J].地学前缘, 2012, 19(2):192-197. http://d.old.wanfangdata.com.cn/Periodical/dxqy201202029 Wang X Z, Zhang J C, Cao J Z, et al.A preliminary discussion on evaluation of continental shale gas resources:A case study of Chang 7 of Mesozoic Yanchang Formation in Zhiluo-Xiasiwan of Yanchang[J].Earth Science Frontiers, 2012, 19(2):192-197. http://d.old.wanfangdata.com.cn/Periodical/dxqy201202029
吴松涛, 朱如凯, 崔京钢, 等.鄂尔多斯盆地长7湖相泥页岩孔隙演化特征[J].石油勘探与开发, 2015, 42(2):167-176. http://d.old.wanfangdata.com.cn/Periodical/syktykf201502005 Wu S T, Zhu R K, Cui J G, et al.Characteristics of lacustrine shale porosity evolution, Triassic Chang 7 Member, Ordos Basin, NW China[J].Petroleum Exploration and Development, 2015, 42(2):167-176. http://d.old.wanfangdata.com.cn/Periodical/syktykf201502005
李晋宁.泥页岩储层孔隙结构表征和连通方式研究[D].南京: 南京大学, 2017. http://cdmd.cnki.com.cn/Article/CDMD-10284-1017095378.htm Li J N.Study on Pore Structure Characteristics and Connectivity of Shale Reservoir[D].Nanjing: Nanjing University, 2017. http://cdmd.cnki.com.cn/Article/CDMD-10284-1017095378.htm
苑丹丹, 卢双舫, 陈方文, 等.渝东南地区彭页1井泥页岩微观孔隙结构特征[J].特种油气藏, 2016, 23(1):49-53. doi: 10.3969/j.issn.1006-6535.2016.01.011 Yuan D D, Lu S F, Chen F W, et al.Shale microscopic pore structure characterization in Well Pengye1 of Southeast Chongqing[J].Special Oil and Gas Reservoir, 2016, 23(1):49-53. doi: 10.3969/j.issn.1006-6535.2016.01.011
杨峰, 宁正福, 胡昌篷, 等.页岩储层微观孔隙结构特征[J].石油学报, 2013, 34(2):301-311. http://d.old.wanfangdata.com.cn/Periodical/syxb201302012 Yang F, Ning Z F, Hu C P, et al.Characterization of microscopic pore structures in shale reservoirs[J].Acta Petrolei Sinica, 2013, 34(2):301-311. http://d.old.wanfangdata.com.cn/Periodical/syxb201302012
王玉满, 董大忠, 杨桦, 等.川南下志留统龙马溪组页岩储集空间定量表征[J].中国科学(地球科学), 2014, 44(6):1348-1356. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201406024 Wang Y M, Dong D Z, Yang H, et al.Quantitative characterization of reservoir space in the Lower Silurian Longmaxi Shale, Southern Sichuan, China[J].Science China:Earth Sciences, 2014, 57:313-322. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201406024
王羽, 金婵, 汪丽华, 等.应用氩离子抛光-扫描电镜方法研究四川九老洞组页岩微观孔隙特征[J].岩矿测试, 2015, 34(3):278-285. doi: 10.15898/j.cnki.11-2131/td.2015.03.003 Wang Y, Jin C, Wang L H, et al.Characterization of pore structures of Jiulaodong Formation shale in the Sichuan Basin by SEM with Ar-ion milling[J].Rock and Mineral Analysis, 2015, 34(3):278-285. doi: 10.15898/j.cnki.11-2131/td.2015.03.003
俞雨溪, 罗晓容, 雷裕红, 等.陆相页岩孔隙结构特征研究——以鄂尔多斯盆地延长组页岩为例[J].天然气地球科学, 2016, 27(4):716-726. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017 Yu Y X, Luo X R, Lei Y H, et al.Characterization of lacustrine shale pore structure:An example from the Upper-Triassic Yanchang Formation, Ordos Basin[J].Naural Gas Geoscience, 2016, 27(4):716-726. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201604017
张林晔, 李钜源, 李政, 等.北美页岩油气研究进展及对中国陆相页岩油气勘探的思考[J].地球科学进展, 2014, 29(6):700-711. http://d.old.wanfangdata.com.cn/Periodical/dqkxjz201406006 Zhang L Y, Li J Y, Li Z, et al.Advance in shale oil/gas research in North America and considerations on exploration for continental shale oil/gas in China[J].Advances in Earth Science, 2014, 29(6):700-711. http://d.old.wanfangdata.com.cn/Periodical/dqkxjz201406006
Keller L M, Schuetz P, Erni R, et al.Characterization of multi-scale microstructural features in Opalinus clay[J].Microporous and Mesoporous Materials, 2012, 170(4):84-90. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=1b9b4752a8941edb4865cd28e2196d40
张磊磊, 陆正元, 王军, 等.渤海湾盆地沾化凹陷沙三下亚段页岩油层段微观孔隙结构[J].石油与天然气地质, 2016, 37(1):80-86. http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201601011 Zhang L L, Lu Z Y, Wang J, et al.Microscopic pore structure of shale oil reservoirs in the Lower 3rd Member of Shahejie Formation in Zhanhua Sag, Bohai Bay Basin[J].Oil & Gas Geology, 2016, 37(1):80-86. http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201601011
白名岗, 夏响华, 张聪, 等.场发射扫描电镜及PerGeos系统在安页1井龙马溪组页岩有机质孔隙研究中的联合应用[J].岩矿测试, 2018, 37(3):225-234. doi: 10.15898/j.cnki.11-2131/td.201803260030 Bai M G, Xia X H, Zhang C, et al.Study on shale organic porosity in the Longmaxi Formation, AnYe -1 Well using field emission-scanning electron microscopy and PerGeos system[J].Rock and Mineral Analysis, 2018, 37(3):225-234. doi: 10.15898/j.cnki.11-2131/td.201803260030
Jin L X, Mathur R, Rother G, et al.Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering[J].Chemical Geology, 2013, 256(2):50-63. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=0fca47e3231e521691e2604e2ca92965
Chen Q, Zhang J, Tang X, et al.Relationship between pore type and pore size of marine shale:An example from the Sinian-Cambrian Formation, Upper Yangtze region, South China[J].International Journal of Coal Geology, 2016, 158:13-28. doi: 10.1016/j.coal.2016.03.001
庞河清, 曾焱, 刘成川, 等.基于氮气吸附-核磁共振-氩离子抛光场发射扫描电镜研究川西须五段泥质岩储层孔隙结构[J].岩矿测试, 2017, 36(1):66-74. doi: 10.15898/j.cnki.11-2131/td.2017.01.010 Pang H Q, Zeng Y, Liu C C, et al.Investigation of pore structure of a argillaceous rocks reservoir in the 5th member of Xujiahe Formation in Western Sichuan, using NAM, NMR and AIP-FESEM[J].Rock and Mineral Analysis, 2017, 36(1):66-74. doi: 10.15898/j.cnki.11-2131/td.2017.01.010
帅琴, 黄瑞成, 高强, 等.页岩气实验测试技术现状与研究进展[J].岩矿测试, 2012, 31(6):931-938. doi: 10.3969/j.issn.0254-5357.2012.06.003 Shuai Q, Huang R C, Gao Q, et al.Research development of analytical techniques for shale gas[J].Rock and Mineral Analysis, 2012, 31(6):931-938. doi: 10.3969/j.issn.0254-5357.2012.06.003
焦堃.煤和泥页岩纳米孔隙的成因、演化机制与定量表征[D].南京: 南京大学, 2014. http://cdmd.cnki.com.cn/Article/CDMD-10284-1015313113.htm Jiao K.The Characterization, Genesis and Evolution of Nanopores in Coals[D].Nanjing: Nanjing University, 2014. http://cdmd.cnki.com.cn/Article/CDMD-10284-1015313113.htm
蒋祺, 康志宏, 黄文辉, 等.富含有机质泥页岩孔隙结构与储集空间类型分析[J].辽宁工程技术大学学报(自然科学版), 2016, 35(9):908-913. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=lngcjsdxxb201609003 Jiang Q, Kang Z H, Huang W H, et al.Analysis of the organic-rich shale pore structure of reservoir space[J].Journal of Liaoning Technical University (Natural Science), 2016, 35(9):908-913. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=lngcjsdxxb201609003
聂海宽, 张金川.页岩气储层类型和特征研究——以四川盆地及其周缘下古生界为例[J].石油实验地质, 2011, 33(3):219-225. doi: 10.3969/j.issn.1001-6112.2011.03.001 Nie H K, Zhang J C.Types and characteristics of shale gas reservoir:A case study of Lower Paleozoic in and around Sichuan Basin[J].Petroleum Geology & Experiment, 2011, 33(3):219-225. doi: 10.3969/j.issn.1001-6112.2011.03.001
Loucks R G, Reed R M, Ruppel S C, et al.Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrockpores[J].AAPG Bulletin, 2012, 96(6):1071-1098. doi: 10.1306/08171111061
于炳松.页岩气储层孔隙分类与表征[J].地学前缘, 2013, 20(4):211-220. http://d.old.wanfangdata.com.cn/Periodical/qgsj201715138 Yu B S.Classification and characterization of gas shale pore system[J].Earth Science Frontiers, 2013, 20(4):211-220. http://d.old.wanfangdata.com.cn/Periodical/qgsj201715138
曹茜, 周文, 陈文玲, 等.鄂尔多斯盆地南部延长组长7段陆相页岩气地层孔隙类型、尺度及成因分析[J].矿物岩石, 2015, 35(2):90-97. http://d.old.wanfangdata.com.cn/Periodical/kwys201502011 Cao Q, Zhou W, Chen W L, et al.Analysis of pore types, sizes and genesis in continental shale gas reservoir of Chang 7 of Yanchang Formation, Odros Basin[J].Mineral Petrology, 2015, 35(2):90-97. http://d.old.wanfangdata.com.cn/Periodical/kwys201502011
Cao Q, Zhou W, Deng H, et al.Classification and controlling factors of organic pores in continental shale gas reservoirs based on laboratory experimental results[J].Journal of Natural Gas Science and Engineering, 2015, 27:1381-1388. doi: 10.1016/j.jngse.2015.10.001
王香增, 范柏江, 张丽霞, 等.陆相页岩气的储集空间特征及赋存过程——以鄂尔多斯盆地陕北斜坡构造带延长探区延长组长7段为例[J].石油与天然气地质, 2015, 36(4):651-658. http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201504015 Wang X Z, Fan B J, Zhang L X, et al.Reservoir space characteristics and charging process of Lacustrine shale gas-A case study of the Chang 7 member in Yanchang Block in Shanbei slope of Ordos Basin[J].Oil & Gas Geology, 2015, 36(4):651-658. http://d.old.wanfangdata.com.cn/Periodical/syytrqdz201504015
于炳松.页岩气储层孔隙分类与表征[J].地学前缘, 2013, 20(4):211-220. http://d.old.wanfangdata.com.cn/Periodical/qgsj201715138 Yu B S.Classification and characterization of gas shale pore system[J].Earth Science Frontiers, 2013, 20(4):211-220. http://d.old.wanfangdata.com.cn/Periodical/qgsj201715138
张盼盼, 刘小平, 王雅杰, 等.页岩纳米孔隙研究新进展[J].地球科学进展, 2014, 29(11):1242-1249. doi: 10.11867/j.issn.1001-8166.2014.11.1242 Zhang P P, Liu X P, Wang Y J, et al.Research progress in shale nanopores[J].Advances in Earth Science, 2014, 29(11):1242-1249. doi: 10.11867/j.issn.1001-8166.2014.11.1242
焦淑静, 张慧, 薛东川, 等.泥页岩孔隙类型、形态特征及成因研究[J].电子显微学报, 2015, 34(5):422-427. http://d.old.wanfangdata.com.cn/Periodical/dzxwxb201505012 Jiao S J, Zhang H, Xue D C, et al.Study on morphological characteristics of micropores and microcracks in shale[J].Journal of Chinese Electron Microscopy Society, 2015, 34(5):422-427. http://d.old.wanfangdata.com.cn/Periodical/dzxwxb201505012
伍岳, 樊太亮, 蒋恕, 等.海相页岩储层微观孔隙体系表征技术及分类方案[J].地质科技情报, 2014, 33(4):92-97. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzkjqb201404015 Wu Y, Fan T L, Jiang S, et al.Characterizing techniques and classification methods for microscope pore system in marine shale reservoir[J].Geological Science and Technology Information, 2014, 33(4):92-97. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzkjqb201404015
Clarkson C R, Solano N, Bustin R M, et al.Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion[J].Fuel, 2013, 103:606-616. doi: 10.1016/j.fuel.2012.06.119
耳闯, 赵靖舟, 王芮, 等.鄂尔多斯盆地三叠系延长组页岩孔隙特征及发育机制[J].天然气地球科学, 2016, 27(7):1202-1214. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201607007 Er C, Zhao J Z, Wang R, et al.Characteristics and occurrence mechanism of organic-rich shale in the Triassic Yanchang Formation, Ordos Basin, China[J].Natural Gas Geoscience, 2016, 27(7):1202-1214. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=trqdqkx201607007
Pommer M, Milliken K.Pore types and pore-size distributions across thermal maturity, Eagle Ford Formation, Southern Texas[J].AAPG Bulletin, 2015, 99(9):1713-1744. doi: 10.1306/03051514151
姚军, 赵秀才.数字岩心及孔隙级渗流模拟理论[M].北京:石油工业出版社, 2010:125-128. Yao J, Zhao X C.Digital Core and Pore Level Percolation Simulation Theory[M].Beijing:Petroleum Industry Press, 2010:125-128.
-
期刊类型引用(13)
1. 郭东旭，史维鑫，回广骥，高卿楠，葛天助，刘晓，纪广轩，宋利强，刘军媛. 红外光谱技术在羌塘TK-1天然气水合物岩心录井中的应用. 矿产勘查. 2025(02): 337-349 . 
百度学术
2. 刘中戎，张启燕，刘晓，何志勇，范志伟，吴浩，葛天助. 北羌塘盆地东部上三叠统矿物成分特征分析及其地质意义. 矿产勘查. 2024(01): 13-23 . 百度学术
3. 张忠雪，代晶晶，王先广，胡正华，万新，彭勃，傅明海，赵龙贤. 赣北石门寺超大型钨矿床白云母短波红外特征及其勘查指示意义. 矿床地质. 2023(01): 116-127 . 百度学术
4. 成嘉伟，刘新星，张娟，王瑛雪，卢克轩，王猛. 基于红外光谱技术的西藏多不杂斑岩型Cu-Au矿床蚀变及矿化特征研究——以钻孔ZK3112为例. 地质与勘探. 2023(02): 259-270 . 百度学术
5. 马驰，王守敬. 我国矿物含量定量测定的研究进展. 冶金分析. 2023(06): 47-54 . 百度学术
6. 王猛，刘新星，李建康，周芳春，李鹏，张娟，成嘉伟，邱佳炜. 湘北仁里花岗伟晶岩型稀有金属矿床红外光谱特征研究及勘查应用. 岩石学报. 2023(07): 2101-2116 . 百度学术
7. 葛天助，安仰生，宋利强，刘晓，罗林涛，郭东旭. 基于红外光谱技术的区域矿物格架及地层划分研究——以北羌塘盆地玛曲地区侏罗统雀莫错组为例. 地质论评. 2023(05): 1939-1951 . 百度学术
8. 郭东旭，张弘，高卿楠，朱有峰，纪广轩. 钻孔岩心红外光谱-便携式XRF-磁化率测试在攀西太和钒钛磁铁矿床勘查中的应用. 岩矿测试. 2022(01): 43-53 . 本站查看
9. 张启燕，史维鑫，刘晓，回广骥，原春雨. 高光谱扫描在碳酸盐岩矿物组成分析中的应用. 岩矿测试. 2022(05): 815-825 . 本站查看
10. 张博，司庆红，苗培森，赵华雷，朱强，陈印，陈路路. 基于近红外岩心光谱扫描技术研究鄂尔多斯盆地彭阳铀矿床矿物分布特征. 岩矿测试. 2022(05): 733-743 . 本站查看
11. 郭东旭，刘晓，张海兰，张志国. 基于红外光谱技术研究云南普朗斑岩铜矿的蚀变和矿化特征. 岩矿测试. 2021(05): 698-709 . 本站查看
12. 张弘，高鹏鑫，高卿楠. 热红外反射光谱技术在石英含量评价中的应用. 岩矿测试. 2021(05): 710-719 . 本站查看
13. 冯晓曦，滕雪明. 豫西卢氏—内乡地区铜铀等战略性矿产成矿条件初探. 华北地质. 2021(04): 5-14 . 百度学术
其他类型引用(4)
计量
- 文章访问数: 2159
- HTML全文浏览量: 596
- PDF下载量: 63
- 被引次数: 17
京公网安备 11010202008159号